Top

Cellulose

Published in:

09-02-2021 | Original Research

A novel biomass vitamin B6-based flame retardant for lyocell fibers

Authors: Xiaowei Su, Chunzu Cheng, Yunbo Zheng, Xiaohui Liu, Yuanlin Ren, Ju He, Shenggen Lin, Bowen Cheng

Published in: Cellulose | Issue 5/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

A biomass vitamin B6-based flame retardant, ammonium salt of pyridoxine phosphoric ester acid (ASPPEA) was synthesized and used for modification of lyocell fibers. FTIR, XPS and EDX analyses indicated that lyocell fibers had been successfully grafted with ASPPEA. The ASPPEA improved the char-forming ability, as evidenced by the increase of the char residue (51 wt%) of ASPPEA-treated lyocell fibers. The limiting oxygen index (LOI) value of ASPPEA-treated lyocell fabrics increased up to 48.3%. After 450 min washing, the LOI value remained 30.8%, thus demonstrating the flame retardant durability. The total heat release of ASPPEA-treated lyocell fabrics decreased by 82.5%. During the pyrolysis, the ASPPEA decomposed to produce acidic substances which promoted the dehydration and char formation of lyocell fibers, thus blocked the exchange of heat and flammable gas. This research proposes a novel application of vitamin B6 to impart lyocell fibers with flame retardancy.

previous article Comparative study on the physical entrapment of soy and mushroom proteins on the durability of bacterial cellulose bio‐leather

next article Development of antibacterial and UV protective cotton fabrics using plant food waste and alien invasive plant extracts as reducing agents for the in-situ synthesis of silver nanoparticles

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Alongi J, Carletto RA, Di Blasio A, Carosio F, Bosco F, Malucelli G (2013) DNA: a novel, green, natural flame retardant and suppressant for cotton. J Mater Chem A 1:4779–4785. https://doi.org/10.1039/c3ta00107eCrossRef

Alongi J, Carletto RA, Bosco F, Carosio F, Di Blasio A, Cuttica F, Antonucci V, Giordano M, Malucelli G (2014) Caseins and hydrophobins as novel green flame retardants for cotton fabrics. Polym Degrad Stab 99:111–117. https://doi.org/10.1016/j.polymdegradstab.2013.11.016CrossRef

Bai BC, Kim EA, Jeon YP, Lee CW, In SJ, Lee YS, Im JS (2014) Improved flame-retardant properties of lyocell fiber achieved by phosphorus compound. Mater Lett 135:226–228. https://doi.org/10.1016/j.matlet.2014.07.131CrossRef

Basak S, Wazed Ali S (2018) Fire resistant behaviour of cellulosic textile functionalized with wastage plant bio-molecules: a comparative scientific report. Int J Biol Macromol 114:169–180. https://doi.org/10.1016/j.ijbiomac.2018.03.109CrossRefPubMed

Basak S, Samanta KK, Chattopadhyay SK (2014) Fire retardant property of cotton fabric treated with herbal extract. J Text I 106:1338–1347. https://doi.org/10.1080/00405000.2014.995456CrossRef

Basak S, Saxena S, Chattopadhyay S, Narkar R, Mahangade R (2016) Banana pseudostem sap: a waste plant resource for making thermally stable cellulosic substrate. J Ind Text 46:1003–1023. https://doi.org/10.1177/1528083715591580CrossRef

Bosco F, Carletto RA, Alongi J, Marmo L, Di Blasio A, Malucelli G (2013) Thermal stability and flame resistance of cotton fabrics treated with whey proteins. Carbohydr Polym 94:372–377. https://doi.org/10.1016/j.carbpol.2012.12.075CrossRefPubMed

Carosio F, Di Blasio A, Alongi J, Malucelli G (2013) Green DNA-based flame retardant coatings assembled through layer by layer. Polymer 54:5148–5153. https://doi.org/10.1016/j.polymer.2013.07.029CrossRef

Carosio F, Fontaine G, Alongi J, Bourbigot S (2015) Starch-based layer by layer assembly: efficient and sustainable approach to cotton fire protection. ACS Appl Mater Interfaces 7:12158–12167. https://doi.org/10.1021/acsami.5b02507CrossRefPubMed

Chen X, Jiao C (2008) Thermal degradation characteristics of a novel flame retardant coating using TG-IR technique. Polym Degrad Stab 93:2222–2225. https://doi.org/10.1016/j.polymdegradstab.2008.09.005CrossRef

Combs GF, McClung JP (2017) Vitamin B6. Vitam. https://doi.org/10.1016/b978-0-12-802965-7.00014-9

Costes L, Laoutid F, Brohez S, Dubois P (2017) Bio-based flame retardants: when nature meets fire protection. Mat Sci Eng R 117:1–25. https://doi.org/10.1016/j.mser.2017.04.001CrossRef

Dong CH, He PS, Lu Z, Wang SG, Sui SY, Liu J, Zhang L, Zhu P (2017) Preparation and properties of cotton fabrics treated with a novel antimicrobial and flame retardant containing triazine and phosphorus components. J Therm Anal Calorim 131:1079–1087. https://doi.org/10.1007/s10973-017-6604-xCrossRef

Fitzpatrick TB (2011) Vitamin B6 in plants. Biosynt Vitam Plants Part B. https://doi.org/10.1016/b978-0-12-385853-5.00006-4

Horrocks AR (1996) Developments in flame retardants for heat and fire resistant textiles—the role of char formation and intumescence. Polym Degrad Stab 54:143–154. https://doi.org/10.1016/S0141-3910(96)00038-9CrossRef

Horrocks AR (2011) Flame retardant challenges for textiles and fibres: new chemistry versus innovatory solutions. Polym Degrad Stab 96:377–392. https://doi.org/10.1016/j.polymdegradstab.2010.03.036CrossRef

Huang S, Zhong L, Li SN, Liu MS, Zhang Z, Zhang FX, Zhang GX (2019) A novel monosodium-glutamate-based flame retardant containing phosphorus for cotton fabrics. Cellulose 26:2715–2728. https://doi.org/10.1007/s10570-018-02241-8CrossRef

Joshi HD, Joshi DH, Patel MG (2010) Dyeing and finishing of lyocell union fibers: an industrial study. Color Technol 126:194–200. https://doi.org/10.1111/j.1478-4408.2010.00248.xCrossRef

Kandola BK, Horrocks AR, Price D, Coleman GV (1996) Flame-retardant treatments of cellulose and their influence on the mechanism of cellulose pyrolysis. J Macromol Sci C 36(4):721–794. https://doi.org/10.1080/15321799608014859CrossRef

Li C, Wang YZ (2010) A review on flame retardant technology in China. Part I: development of flame retardants. Polym Adv Technol 21:1–26. https://doi.org/10.1002/pat.1550CrossRef

Li P, Wang B, Xu YJ, Jiang ZM, Dong CH, Liu Y, Zhu P (2019a) Ecofriendly flame-retardant cotton fabrics: preparation, flame retardancy, thermal degradation properties, and mechanism. ACS Sustain Chem Eng 7(23):19246–19256. https://doi.org/10.1021/acssuschemeng.9b05523CrossRef

Li SN, Zhong L, Huang S, Wang DF, Zhang FX, Zhang GX (2019b) A novel flame retardant with reactive ammonium phosphate groups and polymerizing ability for preparing durable flame retardant and stiff cotton fabric. Polym Degrad Stab 164:145–156. https://doi.org/10.1016/j.polymdegradstab.2019b.04.009CrossRef

Li P, Wang B, Liu YY, Xu YJ, Jiang ZM, Dong CH, Zhang L, Liu Y, Zhu P (2020) Fully bio-based coating from chitosan and phytate for fire-safety and antibacterial cotton fabrics. Carbohyd Polym 237:116173. https://doi.org/10.1016/j.carbpol.2020.116173CrossRef

Liu XH, Zhang QY, Cheng BW, Ren YL, Zhang YG, Ding C (2018a) Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. Cellulose 25:799–811. https://doi.org/10.1007/s10570-017-1550-0CrossRef

Liu XH, Zhang YG, Cheng BW, Ren YL, Zhang QY, Ding C, Peng B (2018b) Preparation of durable and flame retardant lyocell fibers by a one-pot chemical treatment. Cellulose 25:799–811. https://doi.org/10.1007/s10570-018-2005-yCrossRef

Liu Y, Wang QQ, Jiang ZM, Zhang CZ, Li ZF, Chen HQ, Zhu P (2018c) Effect of chitosan on the fire retardancy and thermal degradation properties of coated cotton fabrics with sodium phytate and APTES by LBL assembly. J Anal Appl Pyrol 135:289–298. https://doi.org/10.1016/j.jaap.2018c.08.024CrossRef

Liu XH, Ding C, Peng B, Ren YL, Cheng BW, Lin SG, He J, Su XW (2020a) Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers. Cellulose 27:3427–3442. https://doi.org/10.1007/s10570-019-02894-zCrossRef

Liu XH, Zhang QY, Peng B, Ren YL, Cheng BW, Su XW, He J, Lin SG (2020b) Flame retardant cellulosic fabrics via layer-by-layer self-assembly double coating with egg white protein and phytic acid. J Clean Prod 243:118641. https://doi.org/10.1016/j.jclepro.2019.118641CrossRef

Ortelli S, Malucelli G, Blosi M, Zanoni I, Luisa Costa A (2019) NanoTiO₂@DNA complex: a novel eco, durable, fire retardant design strategy for cotton textiles. J Colloid Interfaces Sci 546:174–183. https://doi.org/10.1016/j.jcis.2019.03.055CrossRef

Qu ZC, Wu K, Jiao EX, Chen WL, Hu ZR, Xu CG, Shi J, Wang S, Tan ZY (2020) Surface functionalization of few-layer black phosphorene and its flame retardancy in epoxy resin. Chem Eng J 382:122991. https://doi.org/10.1016/j.cej.2019.122991CrossRef

Ren YL, Zhang Y, Zhao JY, Wang XL, Zeng Q, Gu YT (2017) Phosphorus-doped organic–inorganic hybrid silicon coating for improving fire retardancy of polyacrylonitrile fabric. J Sol–Gel Sci Technol 82:280–288. https://doi.org/10.1007/s10971-016-4273-zCrossRef

Ren YL, Huo TG, Qin YW, Liu XH (2018) Preparation of flame retardant polyacrylonitrile fabric based on sol–gel and layer-by-layer assembly. Materials 11:483. https://doi.org/10.3390/ma11040483CrossRefPubMedCentral

Ren YL, Liu YS, Wang Y, Guo X, Liu XH (2020) Preparation of durable and flame retardant lyocell fabrics by using a biomass-based modifier derived from vitamin C. Cellulose. https://doi.org/10.1007/s10570-020-03218-2

Sahito IA, Sun KC, Arbab AA, Qadir MB, Jeong SH (2015) Integrating high electrical conductivity and photocatalytic activity in cotton fabric by cationizing for enriched coating of negatively charged graphene oxide. Carbohydr Polym 130:299–306. https://doi.org/10.1016/j.carbpol.2015.05.010CrossRefPubMed

Spontón M, Ronda JC, Galià M, Cádiz V (2009) Cone calorimetry studies of benzoxazine-epoxy systems flame retarded by chemically bonded phosphorus or silicon. Polym Degrad Stab 94:102–106. https://doi.org/10.1016/j.polymdegradstab.2008.10.005CrossRef

Wang X, Lu CQ, Chen CX (2014) Effect of chicken-feather protein-based flame retardant on flame retarding performance of cotton fabric. J Appl Polym Sci 131:40585. https://doi.org/10.1002/app.40584CrossRef

Wang D, Zhong L, Zhang C, Li SN, Tian PX, Zhang FX, Zhang GX (2018) Eco-friendly synthesis of a highly efficient phosphorus flame retardant based on xylitol and application on cotton fabric. Cellulose 26:2123–2138. https://doi.org/10.1007/s10570-018-2193-5CrossRef

Wang B, Li P, Xu YJ, Jiang ZM, Dong CH, Liu Y, Zhu P (2020a) Bio-based, nontoxic and flame-retardant cotton/alginate blended fibres as filling materials: thermal degradation properties, flammability and flame-retardant mechanism. Compos Part B Eng 194:108038. https://doi.org/10.1016/j.compositesb.2020a.108038CrossRef

Wang B, Xu YJ, Li P, Zhang FQ, Liu Y, Zhu P (2020b) Flame-retardant polyester/cotton blend with phosphorus/nitrogen/silicon-containing nano-coating by layer-by-layer assembly. Appl Surf Sci 509:145323. https://doi.org/10.1016/j.apsusc.2020b.145323CrossRef

Xu F, Zhong L, Zhang C, Wang P, Zhang FX, Zhang GX (2019) Novel high-efficiency casein-based P–N-containing flame retardants with multiple reactive groups for cotton fabrics. ACS Sustain Chem Eng 7:13999–14008. https://doi.org/10.1021/acssuschemeng.9b02474CrossRef

Yang JC, Liao W, Deng SB, Cao ZJ, Wang YZ (2016) Flame retardation of cellulose-rich fabrics via a simplified layer-by-layer assembly. Carbohydr Polym 151:434–440. https://doi.org/10.1016/j.carbpol.2016.05.087CrossRefPubMed

Zhang S, Horrocks R (2003) Substantive intumescent flame retardants for functional fibrous polymers. J Mater Sci 38: 2195–2198. https://doi.org/10.1023/A:1023784232290CrossRef

Title: A novel biomass vitamin B6-based flame retardant for lyocell fibers
Authors: Xiaowei Su
Chunzu Cheng
Yunbo Zheng
Xiaohui Liu
Yuanlin Ren
Ju He
Shenggen Lin
Bowen Cheng
Publication date: 09-02-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 5/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03681-5

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 5/2021

Finite element analysis of glucose diffusivity in cellulose nanofibril peripheral nerve conduits

Enhancing magnetic resonance imaging of bio-based nano-contrast via anchoring manganese on rod-shaped cellulose nanocrystals

Making security glazing from modified TEMPO oxidized nanofibers and poly vinylbutyral

Vacuum-filtration fabrication for diverse conductive transparent cellulose electronic devices

Synthesis of cellulose aerogels as promising carriers for drug delivery: a review

Oxidized regenerated celluloses to fabricate high fire safety for epoxy resin with super expansion char layer