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Journal of Coatings Technology and Research

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07-06-2021

A novel waterborne fluorinated polyurethane–acrylate film for ultraviolet blocking and antiprotein fouling

Authors: Jianhong Zheng, Qiongfang Nie, Hongrui Guan, Xiangmei Wu, Shining Zhang, Jinjing Wu, Zefeng Wang, Sihai Zhang

Published in: Journal of Coatings Technology and Research | Issue 5/2021

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Abstract

Waterborne polyurethane–acrylate (WPUA) as a surface protective coating has been widely used in industrial, architectural, and textile applications. To extend the application of WPUA in the biological field, a novel ultraviolet-fluorinated waterborne polyurethane–acrylate (UV-WFPUA) film, which contains 2, 4-dihydroxybenzophenone (DHBP) as the ultraviolet (UV) absorber and dodecafluoroheptyl methacrylate (DFMA) as the fluorine monomer, was prepared. The paper discussed the effect of UV absorber and fluorine monomer on the UV adsorption performance, thermo-stability, and physical and mechanical properties of the UV-WFPUA film. Furthermore, it explored the independent and cooperative effects of UV absorber and fluorine monomer in affecting the antiprotein fouling property on a quantitative level. Results show that the antiprotein fouling performance of UV-WFPUA film significantly weakened after adding 0.4 wt.% DHPB since the average protein concentration increased from 0.14 to 0.37 mg/mL. In contrast, after adding 9 wt.% DFMA, the average protein concentration dropped from 0.37 to 0.13 mg/mL, indicating the antiprotein fouling properties improved. Therefore, the addition of fluorine monomer will contribute to antiprotein fouling and eliminate the adhesion of UV absorber with proteins. The excellent antiprotein fouling, thermal, and optical properties endow the waterborne polyurethane–acrylate films with promising applications in corneal contact lenses or intraocular lenses.

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Title: A novel waterborne fluorinated polyurethane–acrylate film for ultraviolet blocking and antiprotein fouling
Authors: Jianhong Zheng
Qiongfang Nie
Hongrui Guan
Xiangmei Wu
Shining Zhang
Jinjing Wu
Zefeng Wang
Sihai Zhang
Publication date: 07-06-2021
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 5/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-021-00492-y

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