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Journal of Polymer Research
Published in: Journal of Polymer Research 8/2016

01-08-2016

A reactive copolymer based on Glycidylmethacrylate and Maleic Anhydride: 1-synthesis, characterization and monomer reactivity ratios

Authors: Reza Hasanzadeh, Peyman Najafi Moghadam, Naeimeh Bahri-Laleh, Farshid Ziaee

Published in: Journal of Polymer Research | Issue 8/2016

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Abstract

Copolymers of Glycidylmethacrylate (GMA) and Maleic anhydride (MAn) in different molar ratios were synthesized by free radical copolymerization in tetrahydrofurane (THF) at 80 °C using benzoyl peroxide as initiator. The copolymers were characterized by 1H NMR, 13C NMR, FT-IR spectroscopic techniques, GPC, CHN, TGA analyses. The 1HNMR was used for the calculation of monomer composition in the copolymer. The crosslinking behavior of the copolymers was shown by DSC analysis. The amorphous structure was indicated by XRD, SEM and DSC analyses. The monomer reactivity ratios were determined by linear methods. The best rG– rM pair of values was selected by using Akaike Information Criterion. In all the cases, r G  × r M  < 1 and r G  > r M indicate that the resulting copolymer has a tendency toward alternation with an azeotropic point. Structural parameters were obtained by calculating the dyad monomer sequence fractions, mean sequence length and run number (RN = 68.34, f = 0.61, one GMA units triads).
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Appendix
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Metadata
Title
A reactive copolymer based on Glycidylmethacrylate and Maleic Anhydride: 1-synthesis, characterization and monomer reactivity ratios
Authors
Reza Hasanzadeh
Peyman Najafi Moghadam
Naeimeh Bahri-Laleh
Farshid Ziaee
Publication date
01-08-2016
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 8/2016
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-1048-8

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