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Clean Technologies and Environmental Policy
Published in: Clean Technologies and Environmental Policy 4/2013

01-08-2013 | Original Paper

Acrylic acid–allylpolyethoxy carboxylate copolymer as an environmentally friendly calcium carbonate and iron(III) scale inhibitor

Authors: Jingyi Huang, Guangqing Liu, Yuming Zhou, Qingzhao Yao, Yong Yang, Lei Ling, Huchuan Wang, Ke Cao, Yahui Liu, Peixin Zhang, Wendao Wu, Wei Sun

Published in: Clean Technologies and Environmental Policy | Issue 4/2013

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Abstract

A novel environmentally friendly type of calcium carbonate and iron(III) scale inhibitor AQn was synthesized. The anti-scale property of the AQn copolymer toward CaCO3 and iron(III) in the artificial cooling water was studied through static scale inhibition tests. The observation shows that both calcium carbonate and iron(III) inhibition increase with increasing the degree of polymerization of AQn from 5 to 15, and the dosage of AQn plays an important role on calcium carbonate and iron(III) inhibition. The effect on formation of CaCO3 was investigated with combination of scanning electronic microscopy, transmission electron microscopy, X-ray powder diffraction analysis, and Fourier-transform infrared spectrometer, respectively. Inhibition mechanism is proposed that the interactions between calcium or iron ions and polyethylene glycol are the fundamental impetus to restrain the formation of the scale in cooling water systems.
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Metadata
Title
Acrylic acid–allylpolyethoxy carboxylate copolymer as an environmentally friendly calcium carbonate and iron(III) scale inhibitor
Authors
Jingyi Huang
Guangqing Liu
Yuming Zhou
Qingzhao Yao
Yong Yang
Lei Ling
Huchuan Wang
Ke Cao
Yahui Liu
Peixin Zhang
Wendao Wu
Wei Sun
Publication date
01-08-2013
Publisher
Springer Berlin Heidelberg
Published in
Clean Technologies and Environmental Policy / Issue 4/2013
Print ISSN: 1618-954X
Electronic ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-012-0540-z

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