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01-07-2022 | Research paper

Adsorption of meso-tetra(3-pyridyl)porphyrin on InP/ZnS colloidal quantum dots

Authors: Timofey P. Martyanov, Sergey A. Tovstun, Sergey G. Vasil’ev, Elena G. Martyanova, Maxim G. Spirin, Alexey V. Kozlov, Lyubov S. Klimenko, Sergey B. Brichkin, Vladimir F. Razumov

Published in: Journal of Nanoparticle Research | Issue 7/2022

Abstract

Interaction between InP/ZnS core/shell colloidal quantum dots (QDs) and meso-tetra(3-pyridyl)porphyrin (TPyP) was investigated by fluorescence and NMR spectroscopy. Density functional theory (DFT) calculations were used to interpret the NMR data. Formation of the QD-TPyP associate leads to an increase in the fluorescence intensity of the dye and to quenching of the nanocrystal photoluminescence mainly due to Förster resonance energy transfer (FRET). It was shown that the dye adsorption kinetics does not depend on its concentration, which testifies to the limitation of the adsorption rate by the rate of ligand detachment from the QD surface. The NMR data for concentrated solution of QD and TPyP with a 2:1 molar ratio reveal two different types of QD-TPyP associates. With the help of DFT calculations, this can be explained by taking into account that a dye molecule can be coordinated to a QD with one or two pyridine moieties. Associates of the former type are about two times more abundant than those of the latter.

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previous article Synthetic 2D tellurium nanosheets with intense TE wave polarization absorption by employing the PVD method

next article Effect of shell thickness on optical properties of ZnSe/ZnS quantum dots under solar and laser excitation

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Title: Adsorption of meso-tetra(3-pyridyl)porphyrin on InP/ZnS colloidal quantum dots
Authors: Timofey P. Martyanov
Sergey A. Tovstun
Sergey G. Vasil’ev
Elena G. Martyanova
Maxim G. Spirin
Alexey V. Kozlov
Lyubov S. Klimenko
Sergey B. Brichkin
Vladimir F. Razumov
Publication date: 01-07-2022
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 7/2022
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-022-05513-4

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