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Journal of Materials Science
Published in: Journal of Materials Science 19/2019

19-06-2019 | Polymers & biopolymers

Affinity and distribution of silver nanoparticles within plasma polymer matrices

Authors: A. Mansour, F. Poncin-Epaillard, D. Debarnot

Published in: Journal of Materials Science | Issue 19/2019

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Abstract

The affinity and repartition of silver nanoparticles in different plasma polymer matrices are studied according to the polymer functional groups. The polymer layers are synthesized by plasma polymerization of allyl alcohol (AAl), aniline (ANI), or heptadecafluoro-1-decene (HDFD). The matrix is then impregnated in a metallic salt solution and a reducing one. When plasma-polymerized (pp) ANI is used as matrix, a higher amount of silver nanoparticles (AgNPs) is introduced compared to the other two polymer matrices. Otherwise, with pp-AAl, smaller AgNPs with narrower size distribution are inserted. Finally, different plasma polymer/AgNPs interaction mechanisms are proposed according to the polymer functional groups. Moreover, the sensing behavior of pp-ANI, well known as sensitive layer toward ammonia, is markedly enhanced by the presence of AgNPs.
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Metadata
Title
Affinity and distribution of silver nanoparticles within plasma polymer matrices
Authors
A. Mansour
F. Poncin-Epaillard
D. Debarnot
Publication date
19-06-2019
Publisher
Springer US
Published in
Journal of Materials Science / Issue 19/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03772-6

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