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Rare Metals
Published in: Rare Metals 7/2023

03-05-2018

Approaches to electrodeposit molybdenum from ionic liquid

Authors: Xiao-Tian Hu, Jian-Gang Qian, Ying Yin, Xin Li, Tie-Jun Li, Jing Li

Published in: Rare Metals | Issue 7/2023

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Abstract

Molybdenum is a kind of refractory metal and can hardly be deposited in aqueous solution since it is more likely to form molybdenum oxide rather than elementary Mo, but molten salts and ionic liquid become alternative to obtain Mo layer. This paper shows an available process to obtain metallic state molybdenum deposit from ionic liquid. Mo layer was electrodeposited under constant current in ionic liquid 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4). Micromorphology of the electrodeposited Mo layer was observed by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Results show that elementary Mo layer was electrodeposited under constant current in ionic liquid BMIMBF4. Properties of the Mo layer are affected significantly by additive ethylene glycol (EG), deposition temperature and current density. By parallel tests taking into consideration of different technical factors, optimized process parameters are obtained as volume ratio of 2:1 in BMIMBF4 + EG system, deposition temperature of 150 °C and current density of 0.75 mA·cm−2.
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Metadata
Title
Approaches to electrodeposit molybdenum from ionic liquid
Authors
Xiao-Tian Hu
Jian-Gang Qian
Ying Yin
Xin Li
Tie-Jun Li
Jing Li
Publication date
03-05-2018
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 7/2023
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-018-1040-z

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