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Published in: Journal of Coatings Technology and Research 5/2020

11-05-2020

Assessment of lignin as a carbon source in intumescent coatings containing polyaniline

Authors: A. F. Baldissera, M. R. Silveira, A. C. Dornelles, C. A. Ferreira

Published in: Journal of Coatings Technology and Research | Issue 5/2020

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Abstract

Lignin, a vegetable compound, is the second most abundant biorenewable and biodegradable polymer in nature. In this study, the addition of this compound to paints containing ammonium polyphosphate (APP) and expandable graphite as pigments was investigated to improve the fire protection performance of intumescent coatings. The combination of lignin with polyaniline (PANI) in the formulations was also evaluated, as previous studies have shown that PANI-based paints show promising results in intumescent coatings. For this purpose, the thermal protection of mild steel samples coated with these organic coatings was evaluated during a fire resistance test, with the sample exposed to a Bunsen torch. During the test, temperature data and thermography images for the steel surface were collected. The coatings were also evaluated by thermogravimetric analysis and microscale combustion calorimetry. It was found that all coatings formulated provided good fire protection to the steel substrate and the lignin could be a good option to replace nonrenewable sources in intumescent paints, since the sample coated with the paint containing 10 wt% lignin reached 230°C after 30 min of assay. In addition, when this compound was used in combination with PANI, the flame protection was even better. The best performance was observed for the paint formulated with combination of 10 wt% lignin and 10 wt% PANI-ES, whose metal substrate temperature was 170°C after 30 min of assay.

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Literature
1.
go back to reference Duquesne, S, Magnet, S, Jama, C, Delobel, R, “Thermoplastic Resins for Thin Film Intumescent Coatings—Towards a Better Understanding of Their Effect on Intumescence Efficiency.” Polym. Degrad. Stab., 88 63–69 (2005) CrossRef Duquesne, S, Magnet, S, Jama, C, Delobel, R, “Thermoplastic Resins for Thin Film Intumescent Coatings—Towards a Better Understanding of Their Effect on Intumescence Efficiency.” Polym. Degrad. Stab., 88 63–69 (2005) CrossRef
2.
go back to reference Jimenez, M, Duquesne, S, Bourbigot, S, “Intumescent Fire Protective Coating: Toward a Better Understanding of Their Mechanism of Action.” Thermochim. Acta, 449 16–26 (2006) CrossRef Jimenez, M, Duquesne, S, Bourbigot, S, “Intumescent Fire Protective Coating: Toward a Better Understanding of Their Mechanism of Action.” Thermochim. Acta, 449 16–26 (2006) CrossRef
3.
go back to reference Duquesne, S, Magnet, S, Jama, C, Delobel, R, “Intumescent Paints: Fire Protective Coatings for Metallic Substrates.” Surf. Coat. Technol., 180–181 302–307 (2004) CrossRef Duquesne, S, Magnet, S, Jama, C, Delobel, R, “Intumescent Paints: Fire Protective Coatings for Metallic Substrates.” Surf. Coat. Technol., 180–181 302–307 (2004) CrossRef
4.
go back to reference Mariappan, T, “Recent Developments of Intumescent Fire Protection Coatings for Structural Steel: A Review.” J. Fire Sci., 34 120–163 (2016) CrossRef Mariappan, T, “Recent Developments of Intumescent Fire Protection Coatings for Structural Steel: A Review.” J. Fire Sci., 34 120–163 (2016) CrossRef
5.
go back to reference Li, J, Wang, M, She, D, Zhao, Y, “Structural Functionalization of Industrial Softwood Kraft Lignin for Simple Dip-Coating of Urea as Highly Efficient Nitrogen Fertilizer.” Ind. Crops Prod., 109 255–265 (2017) CrossRef Li, J, Wang, M, She, D, Zhao, Y, “Structural Functionalization of Industrial Softwood Kraft Lignin for Simple Dip-Coating of Urea as Highly Efficient Nitrogen Fertilizer.” Ind. Crops Prod., 109 255–265 (2017) CrossRef
6.
go back to reference Khan, TA, Lee, J-H, Kim, H-J, “Lignin-Based Adhesives and Coatings.” Lignocellul. Future Bioecon., 153–206 (2019). Khan, TA, Lee, J-H, Kim, H-J, “Lignin-Based Adhesives and Coatings.” Lignocellul. Future Bioecon., 153–206 (2019).
7.
go back to reference Alongi, J, Han, Z, Bourbigot, S, “Intumescence: Tradition Versus Novelty. A Comprehensive Review.” Prog. Polym. Sci., 51 28–73 (2015) CrossRef Alongi, J, Han, Z, Bourbigot, S, “Intumescence: Tradition Versus Novelty. A Comprehensive Review.” Prog. Polym. Sci., 51 28–73 (2015) CrossRef
8.
go back to reference Sadeghifar, H, Sen, S, Patil, SV, Argyropoulos, DS, “Toward Carbon Fibers from Single Component Kraft Lignin Systems: Optimization of Chain Extension Chemistry.” ACS Sustain. Chem. Eng., 4 5230–5237 (2016) CrossRef Sadeghifar, H, Sen, S, Patil, SV, Argyropoulos, DS, “Toward Carbon Fibers from Single Component Kraft Lignin Systems: Optimization of Chain Extension Chemistry.” ACS Sustain. Chem. Eng., 4 5230–5237 (2016) CrossRef
9.
go back to reference Yan, R, Liu, Y, Liu, B, Zhang, Y, Zhao, Q, Sun, Z, Hu, W, Zhang, N, “Improved Performance of Dual-Cured Organosolv Lignin-Based Epoxy Acrylate Coatings.” Compos. Commun., 10 52–56 (2018) CrossRef Yan, R, Liu, Y, Liu, B, Zhang, Y, Zhao, Q, Sun, Z, Hu, W, Zhang, N, “Improved Performance of Dual-Cured Organosolv Lignin-Based Epoxy Acrylate Coatings.” Compos. Commun., 10 52–56 (2018) CrossRef
10.
go back to reference Shahabadi, SIS, Kong, J, Lu, X, “Aqueous-Only, Green Route to Self-Healable, UV-Resistant, and Electrically Conductive Polyurethane/Graphene/Lignin Nanocomposite Coatings.” ACS. Sustain. Chem. Eng., 5 3148–3157 (2017) CrossRef Shahabadi, SIS, Kong, J, Lu, X, “Aqueous-Only, Green Route to Self-Healable, UV-Resistant, and Electrically Conductive Polyurethane/Graphene/Lignin Nanocomposite Coatings.” ACS. Sustain. Chem. Eng., 5 3148–3157 (2017) CrossRef
11.
go back to reference Nie, SB, Hu, Y, Song, L, He, QL, Yang, DL, Chen, H, “Synergistic Effect Between a Char Forming Agent (CFA) and Microencapsulated Ammonium Polyphosphate on the Thermal and Flame Retardant Properties of Polypropylene.” Polym. Adv. Technol., 19 1077–1083 (2008) CrossRef Nie, SB, Hu, Y, Song, L, He, QL, Yang, DL, Chen, H, “Synergistic Effect Between a Char Forming Agent (CFA) and Microencapsulated Ammonium Polyphosphate on the Thermal and Flame Retardant Properties of Polypropylene.” Polym. Adv. Technol., 19 1077–1083 (2008) CrossRef
12.
go back to reference Baldissera, AF, Silveira, MRS, Beraldo, CH, Tocchetto, NS, Ferreira, CA, “Polymeric Organic Coatings Based on PANI-ES and PANI-ES/APP for Fire Protection.” J. Mater. Res. Technol., 8 2832–2845 (2019) CrossRef Baldissera, AF, Silveira, MRS, Beraldo, CH, Tocchetto, NS, Ferreira, CA, “Polymeric Organic Coatings Based on PANI-ES and PANI-ES/APP for Fire Protection.” J. Mater. Res. Technol., 8 2832–2845 (2019) CrossRef
13.
go back to reference Baldissera, AF, Silveira, MRS, Beraldo, CH, Tocchetto, NS, Ferreira, CA, “Evaluation of the Expandable Graphite/Polyaniline Combination in Intumescent Coatings.” Synth. Met., 256 116141 (2019) CrossRef Baldissera, AF, Silveira, MRS, Beraldo, CH, Tocchetto, NS, Ferreira, CA, “Evaluation of the Expandable Graphite/Polyaniline Combination in Intumescent Coatings.” Synth. Met., 256 116141 (2019) CrossRef
15.
go back to reference Baldissera, AF, Ferreira, CA, “Coatings Based on Electronic Conducting Polymers for Corrosion Protection of Metals.” Prog. Org. Coat., 75 241–247 (2012) CrossRef Baldissera, AF, Ferreira, CA, “Coatings Based on Electronic Conducting Polymers for Corrosion Protection of Metals.” Prog. Org. Coat., 75 241–247 (2012) CrossRef
16.
go back to reference American Society for Testing and Materials, Standard Test Method for Determining Flammability Characteristics of Plastics and Other Solid Materials Using Microscale Combustion Calorimetry, D7309 (2013) American Society for Testing and Materials, Standard Test Method for Determining Flammability Characteristics of Plastics and Other Solid Materials Using Microscale Combustion Calorimetry, D7309 (2013)
17.
go back to reference American Society for Testing and Materials, Standard Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers, D4541 (2017) American Society for Testing and Materials, Standard Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers, D4541 (2017)
18.
go back to reference Baldissera, AF, “Development of Unconventional Antifouling Paint for Protection of Vessels and Metal Structures.” Doctoral Thesis. Federal University of Rio Grande do Sul (2008) Baldissera, AF, “Development of Unconventional Antifouling Paint for Protection of Vessels and Metal Structures.” Doctoral Thesis. Federal University of Rio Grande do Sul (2008)
19.
go back to reference Stefanidis, SD, Kalogiannis, KG, Iliopoulou, EF, Michailof, CM, Pilavachi, PA, Lappas, AA, “A Study of Lignocellulosic Biomass Pyrolysis via the Pyrolysis of Cellulose, Hemicellulose and Lignin.” J. Anal. Appl. Pyrol., 105 143–150 (2014) CrossRef Stefanidis, SD, Kalogiannis, KG, Iliopoulou, EF, Michailof, CM, Pilavachi, PA, Lappas, AA, “A Study of Lignocellulosic Biomass Pyrolysis via the Pyrolysis of Cellulose, Hemicellulose and Lignin.” J. Anal. Appl. Pyrol., 105 143–150 (2014) CrossRef
20.
go back to reference Hou, S, Zhang, YJ, Jiang, P, “Synergistic Effects of Synthetic Phosphonium Sulfonates with Expandable Graphite on Flame Retardancy for EVA Rubber Blends.” Polym. Degrad. Stab., 153 155–164 (2018) CrossRef Hou, S, Zhang, YJ, Jiang, P, “Synergistic Effects of Synthetic Phosphonium Sulfonates with Expandable Graphite on Flame Retardancy for EVA Rubber Blends.” Polym. Degrad. Stab., 153 155–164 (2018) CrossRef
21.
go back to reference Dittanet, P, Pearson, RA, Kongkachuichay, P, “Thermo-Mechanical Behaviors and Moisture Absorption of Silica Nanoparticle Reinforcement in Epoxy Resins.” Int. J. Adhes. Adhes., 78 74–82 (2017) CrossRef Dittanet, P, Pearson, RA, Kongkachuichay, P, “Thermo-Mechanical Behaviors and Moisture Absorption of Silica Nanoparticle Reinforcement in Epoxy Resins.” Int. J. Adhes. Adhes., 78 74–82 (2017) CrossRef
22.
go back to reference Baldissera, AF, Souza, JF, Ferreira, CA, “Synthesis of Polyaniline/Clay Conducting Nanocomposites.” Synth. Met., 183 69–72 (2013) CrossRef Baldissera, AF, Souza, JF, Ferreira, CA, “Synthesis of Polyaniline/Clay Conducting Nanocomposites.” Synth. Met., 183 69–72 (2013) CrossRef
23.
go back to reference Chen, W, Wang, L, Liu, G, “Synthesis of Ammonium Polyphosphate with Crystalline Form V (APP-V) from Melamine Polyphosphate (MPP).” Polym. Degrad. Stab., 97 2567–2570 (2012) CrossRef Chen, W, Wang, L, Liu, G, “Synthesis of Ammonium Polyphosphate with Crystalline Form V (APP-V) from Melamine Polyphosphate (MPP).” Polym. Degrad. Stab., 97 2567–2570 (2012) CrossRef
24.
go back to reference Han, Z, Fina, A, Malucelli, G, “Thermal Shielding Performances of Nano-Structured Intumescent Coatings Containing Organo-Modified Layered Double Hydroxides.” Prog. Org. Coat., 78 504–510 (2015) CrossRef Han, Z, Fina, A, Malucelli, G, “Thermal Shielding Performances of Nano-Structured Intumescent Coatings Containing Organo-Modified Layered Double Hydroxides.” Prog. Org. Coat., 78 504–510 (2015) CrossRef
25.
go back to reference Nørgaard, KP, Dam-Johansen, K, Català, P, Kiil, S, “Investigation of Char Strength and Expansion Properties of an Intumescent Coating Exposed to Rapid Heating Rates.” Prog. Org. Coat., 76 1851–1857 (2013) CrossRef Nørgaard, KP, Dam-Johansen, K, Català, P, Kiil, S, “Investigation of Char Strength and Expansion Properties of an Intumescent Coating Exposed to Rapid Heating Rates.” Prog. Org. Coat., 76 1851–1857 (2013) CrossRef
26.
go back to reference Zhang, Y, Chen, X, Fang, Z, “Synergistic Effects of Expandable Graphite and Ammonium Polyphosphate with a New Carbon Source Derived from Biomass in Flame Retardant ABS.” J. Appl. Polym. Sci., 128 2424–2432 (2013) CrossRef Zhang, Y, Chen, X, Fang, Z, “Synergistic Effects of Expandable Graphite and Ammonium Polyphosphate with a New Carbon Source Derived from Biomass in Flame Retardant ABS.” J. Appl. Polym. Sci., 128 2424–2432 (2013) CrossRef
27.
go back to reference Dong, Y, Wang, G, Su, Q, “Influence of Degree of Polymerization of Ammonium Polyphosphate on Anti-Aging Property of Waterborne Fire Resistive Coatings.” Surf. Coat. Technol., 246 71–76 (2014) CrossRef Dong, Y, Wang, G, Su, Q, “Influence of Degree of Polymerization of Ammonium Polyphosphate on Anti-Aging Property of Waterborne Fire Resistive Coatings.” Surf. Coat. Technol., 246 71–76 (2014) CrossRef
28.
go back to reference Schartel, B, “Phosphorus-Based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development?” Materials (Basel), 3 4710–4745 (2010) CrossRef Schartel, B, “Phosphorus-Based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development?” Materials (Basel), 3 4710–4745 (2010) CrossRef
29.
go back to reference Wladyka-Przybylak, M, Kozlowski, R, “Thermal Characteristics of Different Intumescent Coatings.” Fire Mater., 23 33–43 (1999) CrossRef Wladyka-Przybylak, M, Kozlowski, R, “Thermal Characteristics of Different Intumescent Coatings.” Fire Mater., 23 33–43 (1999) CrossRef
30.
go back to reference Lyon, RE, Walters, RN, “Pyrolysis Combustion Flow Calorimetry.” J. Anal. Appl. Pyrol., 71 27–46 (2004) CrossRef Lyon, RE, Walters, RN, “Pyrolysis Combustion Flow Calorimetry.” J. Anal. Appl. Pyrol., 71 27–46 (2004) CrossRef
Metadata
Title
Assessment of lignin as a carbon source in intumescent coatings containing polyaniline
Authors
A. F. Baldissera
M. R. Silveira
A. C. Dornelles
C. A. Ferreira
Publication date
11-05-2020
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 5/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00348-x

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