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Published in: Journal of Coatings Technology and Research 2/2021

19-10-2020

Bio-inspired fabrication of superhydrophilic and underwater superoleophobic alumina membranes for highly efficient oil/water separation

Authors: Wenjin Zhou, Mingyang Zhou, Huapeng Zhang, Hongyan Tang

Published in: Journal of Coatings Technology and Research | Issue 2/2021

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Abstract

Inspired by fish scales, superhydrophilic and underwater superoleophobic alumina membranes were fabricated in this study. Dopamine deposited on the surface of alumina membranes through immersion over time, and then crosslinking reaction occurred with polyethyleneimine (PEI), which was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. It induced the modified layer coated on the membrane surface. Values of water contact angle of the modified alumina membranes were ~ 0° in air. Values of underwater oil contact angle reached 155°, which indicated it was superhydrophilic and underwater superoleophobic. More particles engendered with the increase in the reaction time with PEI, which induced the decrease in the pore sizes and permeation flux. All values of oil rejection were higher than 98.5%. No obvious deterioration of permeation flux could be found. The rejection hardly suffered a sharp decline over 800 min. It indicates that the modified layer can firmly stick to the alumina membranes. Therefore, the as-prepared alumina membrane is promising for practical oil/water separation.

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Metadata
Title
Bio-inspired fabrication of superhydrophilic and underwater superoleophobic alumina membranes for highly efficient oil/water separation
Authors
Wenjin Zhou
Mingyang Zhou
Huapeng Zhang
Hongyan Tang
Publication date
19-10-2020
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 2/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00406-4