Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Physics of Metals and Metallography
Published in:

01-10-2022 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Calorimetric Studies of Phase Transformations in Fe–Ni Alloys

Authors: L. A. Stashkova, N. V. Mushnikov, V. S. Gaviko, A. V. Protasov

Published in: Physics of Metals and Metallography | Issue 10/2022

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Differential scanning calorimetry (DSC) has been used to study the martensitic transformation in Fe100 – xNix alloys containing 3 to 25 at % Ni. The temperature dependence of the DCS signal exhibits δ-like peaks related to the α–γ transformation; for the alloys with x ≤ 10, an additional λ-like anomaly related to the magnetic phase transformation has been observed. The concentration dependence of the martensitic transformation temperature has been plotted, heat effects have been determined, and the activation energy of the transition has been calculated. It is shown that at Ni concentration of more than 15 at % concentration separation of the alloys occurs.
previous article The Structure and Fracture Pattern of a Сu–Ti–Al–Ni–Fe–C–B Composite after Abrasive Wear
next article The Growth of a Grain during the Annealing of Iron Deformed at 250°C by Shear under Pressure

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
L. Y. Tian, O. Eriksson, and L. Vitos, “Pressure effect on the order–disorder transformation in L10 FeNi,” Sci. Rep. 10, 1–7 (2020).CrossRef
2.
J. Chen, P. Li, and E. E. Lin, “A molecular dynamics study on the mechanical properties of Fe–Ni alloy nanowires and their temperature dependence,” RSC Adv. 10, 40084–40091 (2020).CrossRef
3.
N. Srakaew, P. Jantaratana, P. Nipakul, and C. Sirisathitkul, “Structural and magnetic properties of FexNi100 – x alloys synthesized using Al as a reducing metal,” J. Magn. Magn. Mater. 435, 201–205 (2017).CrossRef
4.
D. Fukui, N. Nakada, and S. Onaka, “Internal residual stress originated from Bain strain and its effect on hardness in Fe–Ni martensite,” Acta Mater. 196, 660–668 (2020).CrossRef
5.
A. I. Poteryaev, N. A. Skorikov, V. I. Anisimov, and M. A. Korotin, “Magnetic properties of Fe1 – xNix alloy from CPA + DMFT perspectives,” Phys. Rev. B 93, 1–7 (2016).CrossRef
6.
L. Y. Tian, O. Gutfleisch, O. Eriksson, and L. Vitos, “Alloying effect on the order–disorder transformation in tetragonal FeNi,” Sci. Rep. 11, 1–9 (2021).
7.
V. V. Sagaradze, N. V. Kataeva, V. A. Zavalishin, V. A. Shabashov, K. A. Kozlov, and M. F. Klyukina, “Conditions for the violation of concentrational homogeneity of Fe–Ni Invar alloys,” Phys. Met. Metallogr. 122 (10), 969–975 (2021).CrossRef
8.
M. P. Kashchenko, N. M. Kashchenko, and V. G. Chashchina, “Dynamic theory of the effect of a strong magnetic field on the martensitic transformation in steels with austenite grain sizes close to a critical value,” Phys. Met. Metallogr. 122 (1), 47–53 (2021).CrossRef
9.
I. V. Zolotarevskii, M. O. Shchetinina, and A. I. Zolotarevskii, “Martensitic transformation in Fe–Ni alloys with addition of chromium, manganese, and carbon in high magnetic fields,” Phys. Met. Metallogr. 122 (2), 127–133 (2021).CrossRef
10.
G. Cacciamani, A. Dinsdale, M. Palumbo, and A. Pasturel, “The Fe–Ni system: Thermodynamic modelling assisted by atomistic calculations,” Intermetallics 18, 1148–1162 (2010).CrossRef
11.
Y. Wang, K. Li, F. Soisson, and C. S. Becquart, “Combining DFT and CALPHAD for the development of on-lattice interaction models: The case of Fe–Ni system,” Phys. Rev. Mater. 4, 113801-1–13 (2020).
12.
I. Ohnuma, S. Shimenouchi, T. Omori, K. Ishida, and R. Kainuma, “Experimental determination and thermodynamic evaluation of low-temperature phase equilibria in the Fe–Ni binary system,” Calphad 67, 101677-1-9 (2019).CrossRef
13.
H. Okamoto, “Supplemental literature review of binary phase diagrams: Au–La, Ce–Pt, Co–Pt, Cr–S, Cu–Sb, Fe–Ni, Lu–Pd, Si–Te, Ta–V, and V–Zn,” J. Phase Equilib. Diffus. 40, 743–756 (2019).CrossRef
14.
M. Hansen and K. Anderko, Constitution of Binary Alloys (McGraw-Hill, 1958).CrossRef
15.
A. Chamberod, J. Laugier, and J. M. Penisson, “Electron irradiation effects on iron-nickel invar alloys,” J. Magn. Magn. Mater. 10, 139–144 (1979).CrossRef
16.
O. Kubaschewski, Iron Binary Phase Diagram (Springer, New York, 1982), pp. 73–78.
17.
T. B. Massalski, H. Okamoto, P. R. Subramanian, and L. Kacprzak, Binary Alloy Phase Diagrams, 2nd ed. (ASM International, Materials Park, 1990).
18.
L. J. Swartzendruber, V. P. Itkin, and C. B. Alcock, “The Fe–Ni (Iron–Nickel) system,” J. Phase Equilib. 12 (3), 288–312 (1991).CrossRef
19.
K. Honda and S. Miura, “On the determination of the heterogeneous field in the system Fe–Ni,” Sci. Rep. Tohoku Imp. Univ. 16, 745–753 (1927).
20.
E. A. Owen and A. H. Sully, “The equilibrium diagram of iron-nickel alloys,” Philos. Mag. 27, 634–636 (1939).CrossRef
21.
E. A. Owen and Y. H. Liu, “Further X-Ray study of the equilibrium diagram of the iron–nickel alloy,” J. Iron Steel Inst. 123, 132–136 (1949).
22.
F. N. Jones and W. I. Pumphrey, “Free energy and metastable states in the iron–nickel and iron–manganese systems,” J. Iron Steel Inst. 163, 121–131 (1949).
23.
L. Kaufman and C. Morris, “The martensitic transformation in the iron–nickel system,” JOM 8 (10), 1393–1401 (1956).CrossRef
24.
E. A. Wilson, “Gamma–alpha transformation in Fe, Fe–Ni and Fe–Cr alloys,” Metal Sci. 18 (10), 471–484 (1984).CrossRef
25.
D. A. Mirzayev, O. P. Morozov, and M. M. Shteynberg, “The γ → α transformation in iron and its alloys,” Phys. Met. Metallogr. 6, 99–105 (1973).
26.
K. B. Reuter, D. B. Williams, and J. I. Goldstein, “Determination of the Fe–Ni Phase Diagram below 400°C,” Metall. Trans. A 20 (4), 719–725 (1989).CrossRef
27.
A. T. Dinsdale, “SGTE data for pure elements,” Calphad 15 (4), 317–425 (1991).CrossRef
28.
G. Ghosh and G. B. Olson, “Computational thermodynamics and the kinetics of martensitic transformation,” J. Phase Equilib. 22 (3), 199–207 (2001).CrossRef
29.
E. Scheil and W. Normann, “Investigation of the thermodynamics of the α–γ transformation in iron–nickel alloy,” Arch. Eisenhuttenwes 30 (12), 751–754 (1959).
30.
L. V. Spivak and N. E. Shchepina, “Calorimetric effects in the structural and phase transitions of metals and alloys,” Phys. Met. Metallogr. 121 (10), 968–995 (2020).CrossRef
31.
N. V. Mushnikov, A. G. Popov, V. S. Gaviko, Protasov, N. M. Kleinerman, O. A. Golovnya, and S. P. Naumov, “Peculiarities of phase diagram of Fe–Ni system at Ni concentrations 0–20 at %,” Acta Mater. 240, 118330 (2022).CrossRef
32.
K. H. Illers, “Die ermittlung des schmelzpunktes von kristallinen polymeren mittels wärmeflusskalorimetrie (DSC),” Eur. Polym. J. 10, 911–916 (1974).CrossRef
33.
L. V. Spivak and N. E. Shchepina, “Polymorphic transformations in iron and zirconium,” Tech. Phys. 65 (7), 1100–1105 (2020).CrossRef
34.
H. E. Kissinger, “Reaction kinetics in differential thermal analysis,” Anal. Chem. 29 (11), 1702–1706 (1957).CrossRef
Metadata
Title
Calorimetric Studies of Phase Transformations in Fe–Ni Alloys
Authors
L. A. Stashkova
N. V. Mushnikov
V. S. Gaviko
A. V. Protasov
Publication date
01-10-2022
Publisher
Pleiades Publishing
Published in
Physics of Metals and Metallography / Issue 10/2022
Print ISSN: 0031-918X
Electronic ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X22600907

Other articles of this Issue 10/2022

Physics of Metals and Metallography 10/2022 Go to the issue

STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

The Effect of Thermomechanical Treatment on the Structure and Mechanical Properties of the Ti49.5Ni50.5 Shape-Memory Alloy

STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

The Formation of Segregations and Nanofaceting of Asymmetric Special Grain Boundaries in Al

ELECTRICAL AND MAGNETIC PROPERTIES

The Magnetotransport Properties of Spin Valves Based on Exchange-Coupled Dy Helimagnetic and Co90Fe10 Ferromagnetic Nanolayers

ELECTRICAL AND MAGNETIC PROPERTIES

The Dependence of the Magnetothermal Properties of ZnxMn1 – xFe2O4 Nanoparticles on the Magnetic Field Near Physiological Brezovich Limit

STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

The Structure and Fracture Pattern of a Сu–Ti–Al–Ni–Fe–C–B Composite after Abrasive Wear

STRENGTH AND PLASTICITY

The Effect of Prolonged Annealing on the Structural Stability of Nanoparticle-Hardened Low-Carbon 9% Cr–3% Co Steel