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Physics of Metals and Metallography

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01-02-2024 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Capillary Phenomena during Interaction of Copper Melt with Dense and Porous MAX Phases with General Formula (Cr,Mn)₂AlC

Authors: S. N. Zhevnenko, M. V. Gorshenkov

Published in: Physics of Metals and Metallography | Issue 2/2024

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Abstract

In this study, we experimentally investigated the interaction of a pure copper melt with dense MAX phase (Cr,Mn)₂AlC obtained as a result of sintering by the spark plasma method and with a porous phase compacted by room temperature pressing. The porous phase (porosity 20%) absorbs a molten copper at temperatures above 1200°C. The absorption kinetics is measured using a high speed (HS) thermo-visioning camera and an HS video camera. The experiments are carried out under a vacuum pressure of 10^–3 Pa. Scanning electron microscopy studies, microanalyses by the method of X-ray spectroscopy, and X-ray diffraction studies have shown that chemical reactions of the MAX phase with a copper melt lead to the formation of a solution of aluminum and chromium in copper and the decomposition of the MAX phase to stable and/or metastable chromium carbides. The dense sintered sample reacts with the melt though the contact (wetting) angles are more than 100°. The difference between porous and dense samples is in the reaction kinetics. The obtained results are compared with the earlier conducted experiments on wetting of the Cr₂AlC MAX phase by a Cu melt (with 0.8 at % Cr). The conditions in the earlier described experiments and the results of determining changes in the chemical composition and the phase composition during capillary experiments indicate that a composite material with a submicrometer structure of chromium carbide impregnated with aluminum bronze can be obtained.

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M. Sokol, V. Natu, S. Kota, and M. W. Barsoum, “On the chemical diversity of the MAX phases,” Trends Chem. 1, 210–223 (2019). https://doi.org/10.1016/j.trechm.2019.02.016CrossRef

X. Lei and N. Lin, “Structure and synthesis of MAX phase materials: A brief review,” Crit. Rev. Solid State Mater. Sci. 47, 736–771 (2022). https://doi.org/10.1080/10408436.2021.1966384CrossRef

V. A. Gorshkov, P. A. Miloserdov, N. Yu. Khomenko, and O. M. Miloserdova, “Cast ceramic materials based on MAX phases in the Mn-Cr-Al-C system obtained by the self-propagating high-temperature synthesis method,” in Durability and Structural Materials Science (ZhivKoM-2020): Proc. 5th Int. Sci.-Tech. Conf. in Remote Format, Moscow, 2020 (Inst. Mashinovedeniya im. A.A. Blagonravova Ross. Akad. Nauk, Moscow, 2020), pp. 90–91 [in Russian].

M. Barsoum and T. El-Raghy, “The MAX phases: Unique new carbide and nitride materials,” Am. Scientist 89, 334–345 (2001). https://doi.org/10.1511/2001.28.334CrossRef

M. W. Barsoum and M. Radovic, “Elastic and mechanical properties of the MAX phases,” Annu. Rev. Mater. Res. 41, 195–227 (2011). https://doi.org/10.1146/annurev-matsci-062910-100448CrossRef

H. Li, S. Li, and Ya. Zhou, “Cyclic thermal shock behaviour of a Cr2AlC ceramic,” Mater. Sci. Eng., A 607, 525–529 (2014). https://doi.org/10.1016/j.msea.2014.04.041CrossRef

V. A. Gorshkov, P. A. Miloserdov, A. V. Karpov, A. S. Shchukin, and A. E. Sytschev, “Investigation of the composition and properties of a Cr₂AlC MAX phase-based material prepared by metallothermic SHS,” Phys. Met. Metallogr. 120, 471–475 (2019). https://doi.org/10.1134/s0031918x19050041CrossRef

B. Jun, S. Kim, J. Heo, C. M. Park, N. Her, M. Jang, Yi. Huang, J. Han, and Ye. Yoon, “Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications,” Nano Res. 12, 471–487 (2019). https://doi.org/10.1007/s12274-018-2225-3CrossRef

Yi. Wei, P. Zhang, R. A. Soomro, Q. Zhu, and B. Xu, “Advances in the synthesis of 2D MXenes,” Adv. Mater. 33, 2103148 (2021). https://doi.org/10.1002/adma.202103148CrossRef

10.

B. B. Panigrahi, M. Chu, Yo. Kim, S. Cho, and J. J. Gracio, “Reaction synthesis and pressureless sintering of Cr₂AlC Powder,” J. Am. Ceram. Soc. 93, 1530–1533 (2010). https://doi.org/10.1111/j.1551-2916.2009.03560.xCrossRef

11.

D. Xiao, J. Zhu, F. Wang, and Yi. Tang, “Synthesis of nano sized Cr₂AlC powders by molten salt method,” J. Nanosci. Nanotechnol. 15, 7341–7345 (2015). https://doi.org/10.1166/jnn.2015.10590CrossRefPubMed

12.

X. Duan, L. Shen, D. Jia, Yu. Zhou, S. Van Der Zwaag, and W. G. Sloof, “Synthesis of high-purity, isotropic or textured Cr₂AlC bulk ceramics by spark plasma sintering of pressure-less sintered powders,” J. Eur. Ceram. Soc. 35, 1393–1400 (2015). https://doi.org/10.1016/j.jeurceramsoc.2014.11.008CrossRef

13.

P. A. Miloserdov, V. A. Gorshkov, and V. I. Yukhvid, “High-temperature synthesis of cast Cr₂AlC at an inert gas overpressure,” Inorg. Mater. 49, 781–785 (2013). https://doi.org/10.1134/s002016851307011xCrossRef

14.

L.-O. Xiao, Sh.-B. Li, G. Song, and W. G. Sloof, “Synthesis and thermal stability of Cr₂AlC,” J. Eur. Ceram. Soc. 31, 1497–1502 (2011). https://doi.org/10.1016/j.jeurceramsoc.2011.01.009CrossRef

15.

A. Shamsipoor, M. Farvizi, M. Razavi, and A. Keyvani, “Influences of processing parameters on the microstructure and wear performance of Cr₂AlC MAX phase prepared by spark plasma sintering method,” J. Alloys Compd. 815, 152345 (2020). https://doi.org/10.1016/j.jallcom.2019.152345CrossRef

16.

E. Tabares, M. Kitzmantel, E. Neubauer, A. Jimenez-Morales, and S. A. Tsipas, “Sinterability, mechanical properties and wear behavior of Ti₃SiC₂ and Cr₂AlC MAX phases,” Ceramics 5, 55–74 (2022). https://doi.org/10.3390/ceramics5010006CrossRef

17.

A. Mockute, M. Dahlqvist, J. Emmerlich, L. Hultman, J. M. Schneider, P. O. Å. Persson, and J. Rosen, “Synthesis and ab initio calculations of nanolaminated (Cr,Mn)₂AlC compounds,” Phys. Rev. B 87, 094113 (2013). https://doi.org/10.1103/physrevb.87.094113CrossRef

18.

K. Sobolev, H. Pazniak, M. Farle, V. Rodionova, and U. Wiedwald, “Synthesis, phase purification and magnetic characterization of the (Cr_1 − x,Mn_x)₂AlC MAX-phase,” J. Mater. Chem. C 9, 16516–16522 (2021). https://doi.org/10.1039/d1tc03092bCrossRef

19.

M. Ramzan, S. Lebègue, and R. Ahuja, “Correlation effects in the electronic and structural properties of Cr₂AlC,” Phys. Status Solidi RRL 5, 122–124 (2011). https://doi.org/10.1002/pssr.201004508CrossRef

20.

S. N. Zhevnenko and M. V. Gorshenkov, “Wetting and spreading of Cu(Cr) melt over the Cr₂AlC MAX phase,” Mater. Lett. 324, 132711 (2022). https://doi.org/10.1016/j.matlet.2022.132711CrossRef

21.

S. N. Zhevnenko, M. V. Gorshenkov, and I. S. Petrov, “Effect of B on improving wetting and imbibition of sintered porous Ta by Cu melt,” J. Alloys Compd. 860, 157886 (2021). https://doi.org/10.1016/j.jallcom.2020.157886CrossRef

22.

K. Sobolev, A. Pazniak, O. Shylenko, V. Komanicky, A. Provino, P. Manfrinetti, D. Peddis, and V. Rodionova, “Complex optimization of arc melting synthesis for bulk Cr₂AlC MAX-phase,” Ceram. Int. 47, 7745–7752 (2021). https://doi.org/10.1016/j.ceramint.2020.11.119CrossRef

23.

K. Sobolev, M. Gorshenkov, P. Manfrinetti, D. Peddis, A. Pazniak, and V. Rodionova, “Synthesis of phase-pure highly-doped MAX-phase (Cr_1 – xMn_x)₂AlC,” Ceram. Int. 47, 21069–21076 (2021). https://doi.org/10.1016/j.ceramint.2021.04.109CrossRef

24.

S. K. Senotrusov and V. A. Perezhogina, “Method of determining the kinetics of infiltration of capillary-porous solids by melts,” Sov. Powder Metall. Met. Ceram. 25, 467–470 (1986). https://doi.org/10.1007/bf00792380CrossRef

25.

H. M. Lu and Q. Jiang, “Surface tension and its temperature coefficient for liquid metals,” J. Phys. Chem. B 109, 15463–15468 (2005). https://doi.org/10.1021/jp0516341CrossRefPubMed

26.

I. Katayama, K. Oura, F. Shoji, and T. Hanawa, “Evidence for solute segregation on Cu–Mn alloy surfaces studied by low-energy ion scattering,” Phys. Rev. B 38, 2188–2191 (1988). https://doi.org/10.1103/physrevb.38.2188CrossRef

27.

P. Yen and R. Datta, “Butler–Sugimoto monomolecular bilayer interface model: The effect of oxygen on the surface tension of a liquid metal and its wetting of a ceramic,” J. Colloid Interface Sci. 426, 314–323 (2014). https://doi.org/10.1016/j.jcis.2014.04.019CrossRefPubMed

Title: Capillary Phenomena during Interaction of Copper Melt with Dense and Porous MAX Phases with General Formula (Cr,Mn)2AlC
Authors: S. N. Zhevnenko
M. V. Gorshenkov
Publication date: 01-02-2024
Publisher: Pleiades Publishing
Published in: Physics of Metals and Metallography / Issue 2/2024
Print ISSN: 0031-918X
Electronic ISSN: 1555-6190
DOI: https://doi.org/10.1134/S0031918X23602640

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Abstract

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Springer Professional "Wirtschaft+Technik"

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Springer Professional "Technik"

Features of Decomposition and the Mechanical Properties of an Aging Shape Memory Ti49Ni51 Alloy Subjected to Heat Treatment

Peculiarities of Magnetization Processes of Cobalt-Based Amorphous Alloy Ribbons in the As-Quenched State

Transverse Magneto-Optical Kerr Effect Enhancement in Si–Ni Nanogratings by Mie and Surface Lattice Resonances

Stress-Dependent Magnetization Processes in Cobalt-Based Amorphous Microwires

Investigation of the Absorption Properties of Multilayer Composites Based on ABS Plastic with Boron Nitride

The Impact of Thermomechanical Treatment on Structure, Electrical Resistance and Hardness of Al–4% Cu–3% Mn Alloy Casted in an Electromagnetic Crystallizer