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Cellulose
Published in: Cellulose 14/2020

22-07-2020 | Original Research

Carboxymethyl cellulose/metal (Fe, Cu and Ni) nanocomposites as non-precious inhibitors of C-steel corrosion in HCl solutions: synthesis, characterization, electrochemical and surface morphology studies

Authors: Hany M. Abd El-Lateef, W. A. Albokheet, M. Gouda

Published in: Cellulose | Issue 14/2020

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Abstract

This study was aimed at improving the stability and protection capacity of carboxymethyl cellulose (CMC) by combining copper, iron and nickel nanoparticles (Cu NP, Fe Np and Ni NP) produced in situ through the deposition of various metal oxide nanoparticles into a CMC matrix. The fabricated CMC as well as CMC/Fe NP, CMC/Cu NP and CMC/Ni NP nanocomposites were characterized by field emission-scanning electron microscope (FE-SEM), Fourier transform-infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy, transmission electron microscope, selected area diffraction pattern and X-ray diffraction techniques. The investigations of electrochemical methods, such as electrochemical impedance spectroscopy and potentiodynamic polarization (PDP), reinforced by surface morphology studies (FE-SEM, and FT-IR) were organized to explore the prepared materials’ protection abilities on a carbon steel electrode in 2 N of HCl. The highest protection power for the CMC as well as CMC/Fe NP, CMC/Cu NP and CMC/Ni NP composites at 400 mg L−1 were 76.6, 94.9, 96.2 and 98.4%, respectively. FE-SEM/EDX and FT-IR examinations confirmed that the prepared nanocomposites could successfully block an aggressive attack with Cl− via chemical adsorption on the steel, in accordance with the adsorption model of Langmuir. PDP data indicated that the nanocomposites could deliver superior corrosion protection and exhibited mixed-type inhibitors.

Graphic abstract

previous article Comparative study on the mechanical and dielectric properties of aramid fibrid, mica and nanofibrillated cellulose based binary composites
next article Green approach for the fabrication of silver-oxidized cellulose nanocomposite with antibacterial properties

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Literature
Acharyulu N, Dubey R, Swaminadham V, Kollu P, Kalyani R, Pammi S (2014) Green synthesis of CuO nanoparticles using phyllanthus amarus leaf extract and their antibacterial activity against multidrug resistance bacteria. Int J Eng Res Technol 3:639–641
Al-Shihry SS, Sayed AR, El-lateef HMA (2020) Design and assessment of a novel poly (urethane-semicarbazides) containing thiadiazoles on the backbone of the polymers as inhibitors for steel pipelines corrosion in CO2-saturated oilfield water. J Mol Struct 1201:127223
Alvi F, Aslam N, Shaukat SF (2015) Corrosion inhibition study of zinc oxide-polyanilinenanocomposite for aluminum and steel. Am J Appl Chem 3:57–64
Ansari K, Quraishi M, Singh A, Ramkumar S, Obote IB (2016) Corrosion inhibition of N80 steel in 15% HCl by pyrazolone derivatives: electrochemical, surface and quantum chemical studies. RSC Adv 6:24130–24141
Arnott D, Hinton B, Ryan N (1989) Cationic-film-forming inhibitors for the protection of the AA 7075 aluminum alloy against corrosion in aqueous chloride solution. Corrosion 45:12–18
Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D (2005) Corrosion inhibition of mild steel by some Schiff base compounds in hydrochloric acid. Appl Surf Sci 239:154–164
Azzam E, Hegazy M, Kandil N, Badawi A, Sami R (2015) The performance of hydrophobic and hydrophilic moieties in synthesized thiol cationic surfactants on corrosion inhibition of carbon steel in HCl. Egypt J Pet 24:493–503
Banerjee S, Srivastava V, Singh M (2012) Chemically modified natural polysaccharide as green corrosion inhibitor for mild steel in acidic medium. Corros Sci 59:35–41
Bello M, Ochoa N, Balsamo V, Lopez-Carrasquero F, Coll S, Monsalve A, Gonzalez G (2010) Modified cassava starches as corrosion inhibitors of carbon steel: an electrochemical and morphological approach. Carbohydr Polym 82:561–568
Bentrah H, Rahali Y, Chala A (2014) Gum Arabic as an eco-friendly inhibitor for API 5L X42 pipeline steel in HCl medium. Corros Sci 82:426–431
Chatterjee AK, Sarkar RK, Chattopadhyay AP, Aich P, Chakraborty R, Basu T (2012) A simple robust method for synthesis of metallic copper nanoparticles of high antibacterial potency against E. coli. Nanotechnology 23:085103PubMed
Chellouli M et al (2016) Corrosion inhibition of iron in acidic solution by a green formulation derived from Nigella sativa L. Electrochim Acta 204:50–59
Chong AL, Mardel JI, MacFarlane DR, Forsyth M, Somers AE (2016) Synergistic corrosion inhibition of mild steel in aqueous chloride solutions by an imidazolinium carboxylate salt. ACS Sustain Chem Eng 4:1746–1755
Chouhan S, Bajpai A, Bajpai J, Katare R, Dhoble S (2017) Mechanical and UV absorption behavior of zinc oxide nanoparticles: reinforced poly (vinyl alcohol-g-acrylonitrile) nanocomposite films. Polym Bull 74:4119–4141
Dao V-D, Choi H-S (2018) Carbon-based sunlight absorbers in solar-driven steam generation devices. Global Chall 2:1700094
Dao V-D, Vu NH, Choic H-S (2020a) All day Limnobium laevigatum inspired nanogenerator self-driven via water evaporation. J Power Sources 448:227388
Dao V-D, Vu NH, Yun S (2020b) Recent advances and challenges for solar-driven water evaporation system toward applications. Nano Energy 68:104324
Diva TN, Zare K, Taleshi F, Yousefi M (2017) Synthesis, characterization, and application of nickel oxide/CNT nanocomposites to remove Pb2+ from aqueous solution. J Nanostruct Chem 7:273–281
El-Lateef HMA (2020) Corrosion inhibition characteristics of a novel salycilidene isatin hydrazine sodium sulfonate on carbon steel in HCl and a synergistic nickel ions additive: a combined experimental and theoretical perspective. Appl Surf Sci 501:144237
El-Lateef HMA, Abdallah ZA, Ahmed MSM (2019) Solvent-free synthesis and corrosion inhibition performance of Ethyl 2-(1, 2, 3, 6-tetrahydro-6-oxo-2-thioxopyrimidin-4-yl) ethanoate on carbon steel in pickling acids: experimental, quantum chemical and Monte Carlo simulation studies. J Mol Liq 296:111800
Emregül KC, Düzgün E, Atakol O (2006) The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media. Corros Sci 48:3243–3260
Fares MM, Maayta A, Al-Mustafa JA (2012) Corrosion inhibition of iota-carrageenan natural polymer on aluminum in presence of zwitterion mediator in HCl media. Corros Sci 65:223–230
Gan T et al (2017) Esterification of bagasse cellulose with metal salts as efficient catalyst in mechanical activation-assisted solid phase reaction system. Cellulose 24:5371–5387
Harrad MA et al (2013) Colloidal nickel (0)-carboxymethyl cellulose particles: a biopolymer-inorganic catalyst for hydrogenation of nitro-aromatics and carbonyl compounds. Catal Commun 32:92–100
Hasanov R, Sadıkoğlu M, Bilgiç S (2007) Electrochemical and quantum chemical studies of some Schiff bases on the corrosion of steel in H2SO4 solution. Appl Surf Sci 253:3913–3921
Hefni HH, Azzam EM, Badr EA, Hussein M, Tawfik SM (2016) Synthesis, characterization and anticorrosion potentials of chitosan-g-PEG assembled on silver nanoparticles. Int J Biol Macromol 83:297–305PubMed
Heydari M, Javidi M (2012) Corrosion inhibition and adsorption behaviour of an amido-imidazoline derivative on API 5L X52 steel in CO2-saturated solution and synergistic effect of iodide ions. Corros Sci 61:148–155
Jawich MW, Oweimreen G, Ali SA (2012) Heptadecyl-tailed mono-and bis-imidazolines: a study of the newly synthesized compounds on the inhibition of mild steel corrosion in a carbon dioxide-saturated saline medium. Corros Sci 65:104–112
Jiao Y, Wan C, Bao W, Gao H, Liang D, Li J (2018) Facile hydrothermal synthesis of Fe3O4@ cellulose aerogel nanocomposite and its application in Fenton-like degradation of Rhodamine B. Carbohydr Polym 189:371–378PubMed
John S, Joseph A, Jose AJ, Narayana B (2015) Enhancement of corrosion protection of mild steel by chitosan/ZnO nanoparticle composite membranes. Prog Org Coat 84:28–34
Karthikeyan P, Malathy M, Rajavel R (2017) Poly (ophenylenediaminecoaniline)/ZnO coated on passivated low nickel stainless steel. J Sci Adv Mater Devices 2:86–92
Khalaf MM, Tantawy AH, Soliman KA, Abd El-Lateef HM (2020) Cationic gemini-surfactants based on waste cooking oil as new ‘green’inhibitors for N80-steel corrosion in sulphuric acid: a combined empirical and theoretical approaches. J Mol Struct 1203:127442
Khalil MI, Abdel-Halim MG (2000) Preparation of some starch-based neutral chelating agents. Carbohydr Res 324:189–199PubMed
Li X, He Y, Sui H, He L (2018) One-step fabrication of dual responsive lignin coated Fe3O4 nanoparticles for efficient removal of cationic and anionic dyes. Nanomaterials 8:162–178PubMedCentral
Lin Y, Singh A, Ebenso EE, Wu Y, Zhu C, Zhu H (2015) Effect of poly (methyl methacrylate-co-N-vinyl-2-pyrrolidone) polymer on J55 steel corrosion in 3.5% NaCl solution saturated with CO2. J Taiwan Inst Chem Eng 46:214–222
Lopez D, Schreiner W, De Sanchez S, Simison S (2004) The influence of inhibitors molecular structure and steel microstructure on corrosion layers in CO2 corrosion: an XPS and SEM characterization. Appl Surf Sci 236:77–97
Luna-Martinez JF, Hernandez-Uresti DB, Reyes-Melo ME, Guerrero-Salazar CA, Gonzalez-Gonzalez VA, Sepulveda-Guzman S (2011) Synthesis and optical characterization of ZnS– sodium carboxymethyl cellulose nanocomposite films. Carbohydr Polym 84:566–570
Mobin M, Rizvi M (2016) Inhibitory effect of xanthan gum and synergistic surfactant additives for mild steel corrosion in 1 M HCl. Carbohyd Polym 136:384–393
Morad M (2008) Inhibition of iron corrosion in acid solutions by Cefatrexyl: behaviour near and at the corrosion potential. Corros Sci 50:436–448
Mourya P, Banerjee S, Singh M (2014) Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor. Corros Sci 85:352–363
Musa AY, Kadhum AAH, Mohamad AB, Takriff MS, Daud AR, Kamarudin SK (2010) On the inhibition of mild steel corrosion by 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol. Corros Sci 52:526–533
Oh H-J, Dao V-D, Choi H-S (2018) Electromagnetic shielding effectiveness of a thin silver layer deposited onto PET film via atmospheric pressure plasma reduction. Appl Surf Sci 435:7–15
Ortega-Toledo D, Gonzalez-Rodriguez J, Casales M, Martinez L, Martinez-Villafañe A (2011) CO2 corrosion inhibition of X-120 pipeline steel by a modified imidazoline under flow conditions. Corros Sci 53:3780–3787
Prabhu R, Venkatesha T, Shanbhag A, Kulkarni G, Kalkhambkar R (2008) Inhibition effects of some Schiff’s bases on the corrosion of mild steel in hydrochloric acid solution. Corros Sci 50:3356–3362
Priya MV, Sabitha M, Jayakumar R (2016) Colloidal chitin nanogels: a plethora of applications under one shell. Carbohydr Polym 136:609–617
Qin Y, Qin Z, Liu Y, Cheng M, Qian P, Wang Q, Zhu M (2015) Superparamagnetic iron oxide coated on the surface of cellulose nanospheres for the rapid removal of textile dye under mild condition. Appl Surf Sci 357:2103–2111
Rajeswari V, Kesavan D, Gopiraman M, Viswanathamurthi P (2013) Physicochemical studies of glucose, gellan gum, and hydroxypropyl cellulose—inhibition of cast iron corrosion. Carbohydr Polym 95:288–294PubMed
Saleh M, Mahmoud MG, El-Lateef HMA (2019) Comparative study of synergistic inhibition of mild steel and pure iron by 1-hexadecylpyridinium chloride and bromide ions. Corros Sci 154:70–79
Sharma AK, Desnavi S, Dixit C, Varshney U, Sharma A (2015) Extraction of nickel nanoparticles from electroplating waste and their application in production of bio-diesel from biowaste. Int J Chem Eng Appl 6:156–161
Solomon M, Umoren S, Udosoro I, Udoh A (2010) Inhibitive and adsorption behaviour of carboxymethyl cellulose on mild steel corrosion in sulphuric acid solution. Corros Sci 52:1317–1325
Solomon MM, Gerengi H, Umoren SA (2017) Carboxymethyl cellulose/silver nanoparticles composite: synthesis, characterization and application as a benign corrosion inhibitor for St37 steel in 15% H2SO4 medium. ACS Appl Mater Interfaces 9:6376–6389PubMed
Tantawy AH, Soliman KA, Abd El-Lateef HM (2020) Novel synthesized cationic surfactants based on natural piper nigrum as sustainable-green inhibitors for steel pipeline corrosion in CO2–3.5% NaCl: DFT, Monte Carlo simulations and experimental approaches. J Clean Prod 250:119510
Umoren S (2008) Inhibition of aluminium and mild steel corrosion in acidic medium using Gum Arabic. Cellulose 15:751
Umoren S, Ogbobe O, Igwe I, Ebenso E (2008) Inhibition of mild steel corrosion in acidic medium using synthetic and naturally occurring polymers and synergistic halide additives. Corros Sci 50:1998–2006
Umoren SA, Banera MJ, Alonso-Garcia T, Gervasi CA, Mirífico MV (2013) Inhibition of mild steel corrosion in HCl solution using chitosan. Cellulose 20:2529–2545
Umoren SA, Obot IB, Madhankumar A, Gasem ZM (2015) Performance evaluation of pectin as ecofriendly corrosion inhibitor for X60 pipeline steel in acid medium: experimental and theoretical approaches. Carbohydr Polym 124:280–291PubMed
Valença DP, Alves KGB, Melo CPd, Bouchonneau N (2015) Study of the efficiency of polypyrrole/ZnO nanocomposites as additives in anticorrosion coatings. Mater Res 18:273–278
Wadhwani PM, Ladha DG, Panchal VK, Shah NK (2015) Enhanced corrosion inhibitive effect of p-methoxybenzylidene-4, 4′-dimorpholine assembled on nickel oxide nanoparticles for mild steel in acid medium. RSC Adv 5:7098–7111
Yesudass S, Olasunkanmi LO, Bahadur I, Kabanda MM, Obot I, Ebenso EE (2016) Experimental and theoretical studies on some selected ionic liquids with different cations/anions as corrosion inhibitors for mild steel in acidic medium. J Taiwan Inst Chem Eng 64:252–268
Zhang Y et al (2015) A green and efficient technology for the degradation of cellulosic materials: structure changes and enhanced enzymatic hydrolysis of natural cellulose pretreated by synergistic interaction of mechanical activation and metal salt. Bioresour Technol 177:176–181PubMed
Zheng Y et al (2013) Synthesis of flexible magnetic nanohybrid based on bacterial cellulose under ultrasonic irradiation. Mater Sci Eng 33:2407–2412
Metadata
Title
Carboxymethyl cellulose/metal (Fe, Cu and Ni) nanocomposites as non-precious inhibitors of C-steel corrosion in HCl solutions: synthesis, characterization, electrochemical and surface morphology studies
Authors
Hany M. Abd El-Lateef
W. A. Albokheet
M. Gouda
Publication date
22-07-2020
Publisher
Springer Netherlands
Published in
Cellulose / Issue 14/2020
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-020-03292-6

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