Skip to main content
Top
Published in: Cellulose 11/2021

18-06-2021 | Original Research

Changes in the molecular structure of cellulose nanocrystals upon treatment with solvents

Authors: Zahra Hosseinpour Feizi, Pedram Fatehi

Published in: Cellulose | Issue 11/2021

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The morphological properties of nano cellulosic materials affect their industrial applications significantly. Solvents are commonly used in treating cellulosic materials in altered applications. In this work, the treatment of cellulose nanocrystals (CNCs) with dimethyl sulfoxide (DMSO) (99.5%) and N-methyl morpholine-N-oxide (NMMO) (50%) was investigated comprehensively under different conditions to evaluate the effect of solvent treatment on the properties of CNCs. A partial polymorphic transition of cellulose I to II was observed when CNCs were treated with the solvents. The temperature of the treatment was more influential than the time of the treatment in altering the CNC properties. XRD, light scattering, and wettability analyses confirmed that the partial dissolution of CNCs in solvents reordered the cellulosic chains from parallel to antiparallel. It also made more hydroxyl groups accessible on CNCs for hydrogen bonding, facilitating the CNC aggregation and instability in solutions. The XPS analysis revealed a remarkable alteration in the relative amounts of components in C 1s, reflecting transformation in the chemical bonds from C=O/O–C–O to C–O on the CNC surface. The increase in the hydroxyl group of CNCs also improved the water-uptake and hydrophilicity of CNCs when they were treated with solvents. The results of this work would suggest that the alteration in the CNC characteristics should be considered when selecting solvents for developing industrial applications for CNCs.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
go back to reference Aguayo M, Fernández Pérez A, Reyes G, Oviedo C, Gacitúa W, Gonzalez R, Uyarte O (2018) Isolation and characterization of cellulose nanocrystals from rejected fibers originated in the kraft pulping process. Polymers 10(10):1145–1156PubMedCentralCrossRef Aguayo M, Fernández Pérez A, Reyes G, Oviedo C, Gacitúa W, Gonzalez R, Uyarte O (2018) Isolation and characterization of cellulose nanocrystals from rejected fibers originated in the kraft pulping process. Polymers 10(10):1145–1156PubMedCentralCrossRef
go back to reference Arnata IW, Suprihatin S, Fahma F, Richana N, Sunarti TC (2020) Cationic modification of nanocrystalline cellulose from sago fronds. Cellulose 27(6):3121–3141CrossRef Arnata IW, Suprihatin S, Fahma F, Richana N, Sunarti TC (2020) Cationic modification of nanocrystalline cellulose from sago fronds. Cellulose 27(6):3121–3141CrossRef
go back to reference Askadskii A, Popova M, Matseevich T, Kurskaya E (2014) The Influence of the degree of crystallinity on the glass transition temperature of polymers. Adv Mater Res 864:751–754 Askadskii A, Popova M, Matseevich T, Kurskaya E (2014) The Influence of the degree of crystallinity on the glass transition temperature of polymers. Adv Mater Res 864:751–754
go back to reference Banerjee M, Saraswatula S, Williams A, Brettmann B (2020) Effect of purification methods on commercially available cellulose nanocrystal properties and TEMPO Oxidation. Processes 8(6):698–712CrossRef Banerjee M, Saraswatula S, Williams A, Brettmann B (2020) Effect of purification methods on commercially available cellulose nanocrystal properties and TEMPO Oxidation. Processes 8(6):698–712CrossRef
go back to reference Beck-Candanedo S, Roman M, Gray DG (2005) Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules 6(2):1048–1054PubMedCrossRef Beck-Candanedo S, Roman M, Gray DG (2005) Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules 6(2):1048–1054PubMedCrossRef
go back to reference Benselfelt T, Cranston ED, Ondaral S, Johansson E, Brumer H, Rutland MW, Wågberg L (2016) Adsorption of xyloglucan onto cellulose surfaces of different morphologies: an entropy-driven process. Biomacromolecules 17(9):2801–2811PubMedCrossRef Benselfelt T, Cranston ED, Ondaral S, Johansson E, Brumer H, Rutland MW, Wågberg L (2016) Adsorption of xyloglucan onto cellulose surfaces of different morphologies: an entropy-driven process. Biomacromolecules 17(9):2801–2811PubMedCrossRef
go back to reference Biganska O, Navard P (2003) Phase diagram of a cellulose solvent: N-methylmorpholine–N-oxide–water mixtures. Polymer 44(4):1035–1039CrossRef Biganska O, Navard P (2003) Phase diagram of a cellulose solvent: N-methylmorpholine–N-oxide–water mixtures. Polymer 44(4):1035–1039CrossRef
go back to reference Biganska O, Navard P (2009) Morphology of cellulose objects regenerated from cellulose-N-methylmorpholine N-oxide-water solutions. Cellulose 16(2):179–188CrossRef Biganska O, Navard P (2009) Morphology of cellulose objects regenerated from cellulose-N-methylmorpholine N-oxide-water solutions. Cellulose 16(2):179–188CrossRef
go back to reference Casarano R, Pires PA, Borin AC, El Seoud OA (2014) Novel solvents for cellulose: use of dibenzyldimethylammonium fluoride/dimethyl sulfoxide (DMSO) as solvent for the etherification of the biopolymer and comparison with tetra (1-butyl) ammonium fluoride/DMSO. Ind Crops Prod 54:185–191CrossRef Casarano R, Pires PA, Borin AC, El Seoud OA (2014) Novel solvents for cellulose: use of dibenzyldimethylammonium fluoride/dimethyl sulfoxide (DMSO) as solvent for the etherification of the biopolymer and comparison with tetra (1-butyl) ammonium fluoride/DMSO. Ind Crops Prod 54:185–191CrossRef
go back to reference Chen D, van de Ven TG (2016) Flocculation kinetics of precipitated calcium carbonate (PCC) with sterically stabilized nanocrystalline cellulose (SNCC). Coll Surf A 506:789–793CrossRef Chen D, van de Ven TG (2016) Flocculation kinetics of precipitated calcium carbonate (PCC) with sterically stabilized nanocrystalline cellulose (SNCC). Coll Surf A 506:789–793CrossRef
go back to reference Costa LA, Fonseca AF, Pereira FV, Druzian JI (2015) Extraction and characterization of cellulose nanocrystals from corn stover. Cell Chem Technol 49(2):127–133 Costa LA, Fonseca AF, Pereira FV, Druzian JI (2015) Extraction and characterization of cellulose nanocrystals from corn stover. Cell Chem Technol 49(2):127–133
go back to reference Dankovich TA, Gray DG (2011) Contact angle measurements on smooth nanocrystalline cellulose (I) thin films. J Adhes Sci Technol 25(6–7):699–708CrossRef Dankovich TA, Gray DG (2011) Contact angle measurements on smooth nanocrystalline cellulose (I) thin films. J Adhes Sci Technol 25(6–7):699–708CrossRef
go back to reference Dong S, Bortner MJ, Roman M (2016) Analysis of the sulfuric acid hydrolysis of wood pulp for cellulose nanocrystal production: a central composite design study. Ind Crops Prod 93:76–87CrossRef Dong S, Bortner MJ, Roman M (2016) Analysis of the sulfuric acid hydrolysis of wood pulp for cellulose nanocrystal production: a central composite design study. Ind Crops Prod 93:76–87CrossRef
go back to reference Douard L, Bras J, Encinas T, Belgacem N (2020) Natural acidic deep eutectic solvent to obtain cellulose nanocrystals using the design of experience approach. Carbohydr Polym 252:117136–117145PubMedCrossRef Douard L, Bras J, Encinas T, Belgacem N (2020) Natural acidic deep eutectic solvent to obtain cellulose nanocrystals using the design of experience approach. Carbohydr Polym 252:117136–117145PubMedCrossRef
go back to reference El-Wakil NA, Hassan ML (2008) Structural changes of regenerated cellulose dissolved in FeTNa, NaOH/thiourea, and NMMO systems. J Appl Pol Sci 109(5):2862–2871CrossRef El-Wakil NA, Hassan ML (2008) Structural changes of regenerated cellulose dissolved in FeTNa, NaOH/thiourea, and NMMO systems. J Appl Pol Sci 109(5):2862–2871CrossRef
go back to reference Fatona A, Berry RM, Brook MA, Moran-Mirabal JM (2018) Versatile surface modification of cellulose fibers and cellulose nanocrystals through modular triazinyl chemistry. Chem Mater 30(7):2424–2435CrossRef Fatona A, Berry RM, Brook MA, Moran-Mirabal JM (2018) Versatile surface modification of cellulose fibers and cellulose nanocrystals through modular triazinyl chemistry. Chem Mater 30(7):2424–2435CrossRef
go back to reference Feizi ZH, Fatehi P (2020) Carboxymethylated cellulose nanocrystals as clay suspension dispersants: effect of size and surface functional groups. Cellulose 27:3759–3772CrossRef Feizi ZH, Fatehi P (2020) Carboxymethylated cellulose nanocrystals as clay suspension dispersants: effect of size and surface functional groups. Cellulose 27:3759–3772CrossRef
go back to reference Feizi ZH, Fatehi P (2021) Interaction of hairy carboxyalkyl cellulose nanocrystals with cationic surfactant: Effect of carbon spacer. Carbohydr Polym 255:117396–117407PubMedCrossRef Feizi ZH, Fatehi P (2021) Interaction of hairy carboxyalkyl cellulose nanocrystals with cationic surfactant: Effect of carbon spacer. Carbohydr Polym 255:117396–117407PubMedCrossRef
go back to reference Feizi ZH, Kazzaz AE, Kong F, Fatehi P (2019) Evolving a flocculation process for isolating lignosulfonate from solution. Sep Purif Technol 222:254–263CrossRef Feizi ZH, Kazzaz AE, Kong F, Fatehi P (2019) Evolving a flocculation process for isolating lignosulfonate from solution. Sep Purif Technol 222:254–263CrossRef
go back to reference French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21(2):885–896CrossRef French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21(2):885–896CrossRef
go back to reference French AD (2020) Increment in evolution of cellulose crystallinity analysis. Cellulose 27:5445–5448CrossRef French AD (2020) Increment in evolution of cellulose crystallinity analysis. Cellulose 27:5445–5448CrossRef
go back to reference Glińska K, Lerigoleur C, Giralt J, Torrens E, Bengoa C (2020) Valorization of cellulose recovered from WWTP sludge to added value levulinic acid with a Brønsted acidic ionic liquid. Catalysts 10(9):1004–1020CrossRef Glińska K, Lerigoleur C, Giralt J, Torrens E, Bengoa C (2020) Valorization of cellulose recovered from WWTP sludge to added value levulinic acid with a Brønsted acidic ionic liquid. Catalysts 10(9):1004–1020CrossRef
go back to reference Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500PubMedCrossRef Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500PubMedCrossRef
go back to reference Hambardzumyan A, Foulon L, Chabbert B, Aguié-Béghin V (2012) Natural organic UV-absorbent coatings based on cellulose and lignin: designed effects on spectroscopic properties. Biomacromolecules 13(12):4081–4088PubMedCrossRef Hambardzumyan A, Foulon L, Chabbert B, Aguié-Béghin V (2012) Natural organic UV-absorbent coatings based on cellulose and lignin: designed effects on spectroscopic properties. Biomacromolecules 13(12):4081–4088PubMedCrossRef
go back to reference Han J, Zhou C, Wu Y, Liu F, Wu Q (2013) Self-assembling behavior of cellulose nanoparticles during freeze-drying: effect of suspension concentration, particle size, crystal structure, and surface charge. Biomacromolecules 14(5):1529–1540PubMedCrossRef Han J, Zhou C, Wu Y, Liu F, Wu Q (2013) Self-assembling behavior of cellulose nanoparticles during freeze-drying: effect of suspension concentration, particle size, crystal structure, and surface charge. Biomacromolecules 14(5):1529–1540PubMedCrossRef
go back to reference Hauru LK, Hummel M, King AW, Kilpelainen I, Sixta H (2012) Role of solvent parameters in the regeneration of cellulose from ionic liquid solutions. Biomacromolecules 13(9):2896–2905PubMedCrossRef Hauru LK, Hummel M, King AW, Kilpelainen I, Sixta H (2012) Role of solvent parameters in the regeneration of cellulose from ionic liquid solutions. Biomacromolecules 13(9):2896–2905PubMedCrossRef
go back to reference Herrera-Morales J, Morales K, Ramos D, Ortiz-Quiles EO, Lopez-Encarnacion JM, Nicolau E (2017) Examining the use of nanocellulose composites for the sorption of contaminants of emerging concern: an experimental and computational study. ACS Omega 2(11):7714–7722PubMedPubMedCentralCrossRef Herrera-Morales J, Morales K, Ramos D, Ortiz-Quiles EO, Lopez-Encarnacion JM, Nicolau E (2017) Examining the use of nanocellulose composites for the sorption of contaminants of emerging concern: an experimental and computational study. ACS Omega 2(11):7714–7722PubMedPubMedCentralCrossRef
go back to reference Islam MIU, Sherrell R, Langrish TAG (2010) An investigation of the relationship between glass transition temperatures and the crystallinity of spray-dried powders. Dry Technol 28(3):361–368CrossRef Islam MIU, Sherrell R, Langrish TAG (2010) An investigation of the relationship between glass transition temperatures and the crystallinity of spray-dried powders. Dry Technol 28(3):361–368CrossRef
go back to reference Jia X, Chen Y, Shi C, Ye Y, Wang P, Zeng X, Wu T (2013) Preparation and characterization of cellulose regenerated from phosphoric acid. J Agric Food Chem 61(50):12405–12414PubMedCrossRef Jia X, Chen Y, Shi C, Ye Y, Wang P, Zeng X, Wu T (2013) Preparation and characterization of cellulose regenerated from phosphoric acid. J Agric Food Chem 61(50):12405–12414PubMedCrossRef
go back to reference Jiang Z, Tang L, Gao X, Zhang W, Ma J, Zhang L (2019) Solvent regulation approach for preparing cellulose-nanocrystal-reinforced regenerated cellulose fibers and their properties. ACS Omega 4(1):2001–2008PubMedPubMedCentralCrossRef Jiang Z, Tang L, Gao X, Zhang W, Ma J, Zhang L (2019) Solvent regulation approach for preparing cellulose-nanocrystal-reinforced regenerated cellulose fibers and their properties. ACS Omega 4(1):2001–2008PubMedPubMedCentralCrossRef
go back to reference Jin E, Guo J, Yang F, Zhu Y, Song J, Jin Y, Rojas OJ (2016) On the polymorphic and morphological changes of cellulose nanocrystals (CNC-I) upon mercerization and conversion to CNC-II. Carbohydr Polym 143:327–335PubMedCrossRef Jin E, Guo J, Yang F, Zhu Y, Song J, Jin Y, Rojas OJ (2016) On the polymorphic and morphological changes of cellulose nanocrystals (CNC-I) upon mercerization and conversion to CNC-II. Carbohydr Polym 143:327–335PubMedCrossRef
go back to reference Johnson A, Jones A (2019) Testing for water in DMSO: exploring alternatives to volumetric karl fischer analysis. Pharm Technol 43(5):44–48 Johnson A, Jones A (2019) Testing for water in DMSO: exploring alternatives to volumetric karl fischer analysis. Pharm Technol 43(5):44–48
go back to reference Ju X, Bowden M, Brown EE, Zhang X (2015) An improved X-ray diffraction method for cellulose crystallinity measurement. Carbohydr Polym 123:476–481PubMedCrossRef Ju X, Bowden M, Brown EE, Zhang X (2015) An improved X-ray diffraction method for cellulose crystallinity measurement. Carbohydr Polym 123:476–481PubMedCrossRef
go back to reference Kaboorani A, Riedl B (2015) Surface modification of cellulose nanocrystals (CNC) by a cationic surfactant. Ind Crop Prod 65:45–55CrossRef Kaboorani A, Riedl B (2015) Surface modification of cellulose nanocrystals (CNC) by a cationic surfactant. Ind Crop Prod 65:45–55CrossRef
go back to reference Kazzaz AE, Feizi ZH, Kong F, Fatehi P (2018a) Interaction of poly (acrylic acid) and aluminum oxide particles in suspension: particle size effect. Colloid Surf A 556:218–226CrossRef Kazzaz AE, Feizi ZH, Kong F, Fatehi P (2018a) Interaction of poly (acrylic acid) and aluminum oxide particles in suspension: particle size effect. Colloid Surf A 556:218–226CrossRef
go back to reference Kazzaz AE, Feizi ZH, Fatehi P (2018b) Interaction of sulfomethylated lignin and aluminum oxide. Colloid Polym Sci 296(11):1867–1878CrossRef Kazzaz AE, Feizi ZH, Fatehi P (2018b) Interaction of sulfomethylated lignin and aluminum oxide. Colloid Polym Sci 296(11):1867–1878CrossRef
go back to reference King AW, Mäkelä V, Kedzior SA, Laaksonen T, Partl GJ, Heikkinen S, Koskela H, Heikkinen HA, Holding AJ, Cranston ED, Kilpeläinen I (2018) Liquid-state NMR analysis of nanocelluloses. Biomacromolecules 19(7):2708–2720PubMedCrossRef King AW, Mäkelä V, Kedzior SA, Laaksonen T, Partl GJ, Heikkinen S, Koskela H, Heikkinen HA, Holding AJ, Cranston ED, Kilpeläinen I (2018) Liquid-state NMR analysis of nanocelluloses. Biomacromolecules 19(7):2708–2720PubMedCrossRef
go back to reference Krysztof M, Olejnik K, Kulpinski P, Stanislawska A, Khadzhynova S (2018) Regenerated cellulose from N-methylmorpholine N-oxide solutions as a coating agent for paper materials. Cellulose 25(6):3595–3607CrossRef Krysztof M, Olejnik K, Kulpinski P, Stanislawska A, Khadzhynova S (2018) Regenerated cellulose from N-methylmorpholine N-oxide solutions as a coating agent for paper materials. Cellulose 25(6):3595–3607CrossRef
go back to reference Laitinen O, Ojala J, Sirviö JA, Liimatainen H (2017) Sustainable stabilization of oil in water emulsions by cellulose nanocrystals synthesized from deep eutectic solvents. Cellulose 24(4):1679–1689CrossRef Laitinen O, Ojala J, Sirviö JA, Liimatainen H (2017) Sustainable stabilization of oil in water emulsions by cellulose nanocrystals synthesized from deep eutectic solvents. Cellulose 24(4):1679–1689CrossRef
go back to reference Li F, Biagioni P, Bollani M, Maccagnan A, Piergiovanni L (2013) Multi-functional coating of cellulose nanocrystals for flexible packaging applications. Cellulose 20(5):2491–2504CrossRef Li F, Biagioni P, Bollani M, Maccagnan A, Piergiovanni L (2013) Multi-functional coating of cellulose nanocrystals for flexible packaging applications. Cellulose 20(5):2491–2504CrossRef
go back to reference Li Y, Wang J, Liu X, Zhang S (2018) Towards a molecular understanding of cellulose dissolution in ionic liquids: anion/cation effect, synergistic mechanism and physicochemical aspects. Chem Sci 9(17):4027–4043PubMedPubMedCentralCrossRef Li Y, Wang J, Liu X, Zhang S (2018) Towards a molecular understanding of cellulose dissolution in ionic liquids: anion/cation effect, synergistic mechanism and physicochemical aspects. Chem Sci 9(17):4027–4043PubMedPubMedCentralCrossRef
go back to reference Lin N, Dufresne A (2014) Surface chemistry, morphological analysis and properties of cellulose nanocrystals with gradiented sulfation degrees. Nanoscale 6(10):5384–5393PubMedCrossRef Lin N, Dufresne A (2014) Surface chemistry, morphological analysis and properties of cellulose nanocrystals with gradiented sulfation degrees. Nanoscale 6(10):5384–5393PubMedCrossRef
go back to reference Man Z, Muhammad N, Sarwono A, Bustam MA, Kumar MV, Rafiq S (2011) Preparation of cellulose nanocrystals using an ionic liquid. J Polym Environ 19(3):726–731CrossRef Man Z, Muhammad N, Sarwono A, Bustam MA, Kumar MV, Rafiq S (2011) Preparation of cellulose nanocrystals using an ionic liquid. J Polym Environ 19(3):726–731CrossRef
go back to reference Maurer JJ (1965) Relation between glass transition temperature and composition of ethylene propylene copolymers. Rubber Chem Technol 38(4):979–990CrossRef Maurer JJ (1965) Relation between glass transition temperature and composition of ethylene propylene copolymers. Rubber Chem Technol 38(4):979–990CrossRef
go back to reference Medronho B, Lindman B (2014) Competing forces during cellulose dissolution: from solvents to mechanisms. Curr Opin Colloid Interface Sci 19(1):32–40CrossRef Medronho B, Lindman B (2014) Competing forces during cellulose dissolution: from solvents to mechanisms. Curr Opin Colloid Interface Sci 19(1):32–40CrossRef
go back to reference Moriana R, Vilaplana F, Ek M (2016) Cellulose nanocrystals from forest residues as reinforcing agents for composites: a study from macro-to nano-dimensions. Carbohydr Polym 139:139–149PubMedCrossRef Moriana R, Vilaplana F, Ek M (2016) Cellulose nanocrystals from forest residues as reinforcing agents for composites: a study from macro-to nano-dimensions. Carbohydr Polym 139:139–149PubMedCrossRef
go back to reference Ng HM, Sin LT, Tee TT, Hui BST, D, Low CY, Rahmat AR, (2015) Extraction of cellulose nanocrystals from plant sources for application as reinforcing agent in polymers. Compos B Eng 75:176–200CrossRef Ng HM, Sin LT, Tee TT, Hui BST, D, Low CY, Rahmat AR, (2015) Extraction of cellulose nanocrystals from plant sources for application as reinforcing agent in polymers. Compos B Eng 75:176–200CrossRef
go back to reference Poletto M, Pistor V, Zattera AJ (2013) Chapter 2: Structural characteristics and thermal properties of native cellulose. In: van de Ven T (ed) Cellulose fundamental aspects. Intech publisher, pp 45–68 Poletto M, Pistor V, Zattera AJ (2013) Chapter 2: Structural characteristics and thermal properties of native cellulose. In: van de Ven T (ed) Cellulose fundamental aspects. Intech publisher, pp 45–68
go back to reference Rabideau BD, Ismail AE (2015) Effect of water content in N-methylmorpholine N-oxide/cellulose solutions on thermodynamics, structure, and hydrogen bonding. J Phys 119(48):15014–15022 Rabideau BD, Ismail AE (2015) Effect of water content in N-methylmorpholine N-oxide/cellulose solutions on thermodynamics, structure, and hydrogen bonding. J Phys 119(48):15014–15022
go back to reference Reid MS, Villalobos M, Cranston ED (2017) The role of hydrogen bonding in non-ionic polymer adsorption to cellulose nanocrystals and silica colloids. Curr Opp Colloid Interf Sci 29:76–82CrossRef Reid MS, Villalobos M, Cranston ED (2017) The role of hydrogen bonding in non-ionic polymer adsorption to cellulose nanocrystals and silica colloids. Curr Opp Colloid Interf Sci 29:76–82CrossRef
go back to reference Samsudin NA, Low FW, Yusoff Y, Shakeri M, Tan XY, Lai CW, Asim N, Newas KS, Tiong SK, Amin N (2020) Effect of temperature on synthesis of cellulose nanoparticles via ionic liquid hydrolysis process. J Mol Liq 308:113030–113037CrossRef Samsudin NA, Low FW, Yusoff Y, Shakeri M, Tan XY, Lai CW, Asim N, Newas KS, Tiong SK, Amin N (2020) Effect of temperature on synthesis of cellulose nanoparticles via ionic liquid hydrolysis process. J Mol Liq 308:113030–113037CrossRef
go back to reference Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29(10):786–794CrossRef Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29(10):786–794CrossRef
go back to reference Semin DJ, Malone TJ, Paley MT, Woods PW (2005) A novel approach to determine water content in DMSO for a compound collection repository. J Biomol Screen 10(6):568–572PubMedCrossRef Semin DJ, Malone TJ, Paley MT, Woods PW (2005) A novel approach to determine water content in DMSO for a compound collection repository. J Biomol Screen 10(6):568–572PubMedCrossRef
go back to reference Sharma S, Zhang X, Nair SS, Ragauskas A, Zhu J, Deng Y (2014) Thermally enhanced high performance cellulose nano fibril barrier membranes. RSC Adv 4(85):45136–45142CrossRef Sharma S, Zhang X, Nair SS, Ragauskas A, Zhu J, Deng Y (2014) Thermally enhanced high performance cellulose nano fibril barrier membranes. RSC Adv 4(85):45136–45142CrossRef
go back to reference Sirviö JA (2019) Fabrication of regenerated cellulose nanoparticles by mechanical disintegration of cellulose after dissolution and regeneration from a deep eutectic solvent. J Mater Chem A 7(2):755–763CrossRef Sirviö JA (2019) Fabrication of regenerated cellulose nanoparticles by mechanical disintegration of cellulose after dissolution and regeneration from a deep eutectic solvent. J Mater Chem A 7(2):755–763CrossRef
go back to reference Sriamornsak P, Wattanakorn N, Nunthanid J, Puttipipatkhachorn S (2008) Mucoadhesion of pectin as evidence by wettability and chain interpenetration. Carbohydr Polym 74(3):458–467CrossRef Sriamornsak P, Wattanakorn N, Nunthanid J, Puttipipatkhachorn S (2008) Mucoadhesion of pectin as evidence by wettability and chain interpenetration. Carbohydr Polym 74(3):458–467CrossRef
go back to reference Viet D, Beck-Candanedo S, Gray DG (2007) Dispersion of cellulose nanocrystals in polar organic solvents. Cellulose 14(2):109–113CrossRef Viet D, Beck-Candanedo S, Gray DG (2007) Dispersion of cellulose nanocrystals in polar organic solvents. Cellulose 14(2):109–113CrossRef
go back to reference Wan Y, An F, Zhou P, Liu Y, Lu C, Chen H (2017) Effect of the polymorphs of cellulose on its pyrolysis kinetic and char yield. J Anal Appl Pyrolysis 127:223–228CrossRef Wan Y, An F, Zhou P, Liu Y, Lu C, Chen H (2017) Effect of the polymorphs of cellulose on its pyrolysis kinetic and char yield. J Anal Appl Pyrolysis 127:223–228CrossRef
go back to reference Wan Ishak WH, Ahmad I, Ramli S, Mohd Amin MCI (2018) Gamma irradiation-assisted synthesis of cellulose nanocrystal-reinforced gelatin hydrogels. Nanomaterials 8(10):749–762PubMedCentralCrossRef Wan Ishak WH, Ahmad I, Ramli S, Mohd Amin MCI (2018) Gamma irradiation-assisted synthesis of cellulose nanocrystal-reinforced gelatin hydrogels. Nanomaterials 8(10):749–762PubMedCentralCrossRef
go back to reference Yang X, Wang X, Liu H, Zhao Y, Jiang S, Liu L (2017) Impact of dimethyl sulfoxide treatment on morphology and characteristics of nanofibrillated cellulose isolated from corn husks. BioResources 12(1):95–106CrossRef Yang X, Wang X, Liu H, Zhao Y, Jiang S, Liu L (2017) Impact of dimethyl sulfoxide treatment on morphology and characteristics of nanofibrillated cellulose isolated from corn husks. BioResources 12(1):95–106CrossRef
go back to reference Yao W, Weng Y, Catchmark JM (2020) Improved cellulose X-ray diffraction analysis using fourier series modeling. Cellulose 27(10):5563–5579CrossRef Yao W, Weng Y, Catchmark JM (2020) Improved cellulose X-ray diffraction analysis using fourier series modeling. Cellulose 27(10):5563–5579CrossRef
go back to reference Yue Y, Zhou C, French AD, Xia G, Han G, Wang Q, Wu Q (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19(4):1173–1187CrossRef Yue Y, Zhou C, French AD, Xia G, Han G, Wang Q, Wu Q (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19(4):1173–1187CrossRef
go back to reference Zainuddin N, Ahmad I, Kargarzadeh H, Ramli S (2017) Hydrophobic kenaf nanocrystalline cellulose for the binding of curcumin. Carbohydr Polym 163:261–269PubMedCrossRef Zainuddin N, Ahmad I, Kargarzadeh H, Ramli S (2017) Hydrophobic kenaf nanocrystalline cellulose for the binding of curcumin. Carbohydr Polym 163:261–269PubMedCrossRef
go back to reference Zhang D, Karkooti A, Liu L, Sadrzadeh M, Thundat T, Liu Y, Narain R (2018) Fabrication of antifouling and antibacterial polyethersulfone (PES)/cellulose nanocrystals (CNC) nanocomposite membranes. J Membr Sci 549:350–356CrossRef Zhang D, Karkooti A, Liu L, Sadrzadeh M, Thundat T, Liu Y, Narain R (2018) Fabrication of antifouling and antibacterial polyethersulfone (PES)/cellulose nanocrystals (CNC) nanocomposite membranes. J Membr Sci 549:350–356CrossRef
go back to reference Zhao H, Kwak JH, Wang Y, Franz JA, White JM, Holladay JE (2007) Interactions between cellulose and N-methylmorpholine-N-oxide. Carbohydr Polym 67(1):97–103CrossRef Zhao H, Kwak JH, Wang Y, Franz JA, White JM, Holladay JE (2007) Interactions between cellulose and N-methylmorpholine-N-oxide. Carbohydr Polym 67(1):97–103CrossRef
go back to reference Zielińska A, Martins-Gomes C, Ferreira NR, Silva AM, Nowak I, Souto EB (2018) Anti-inflammatory and anti-cancer activity of citral: optimization of citral-loaded solid lipid nanoparticles (SLN) using experimental factorial design and LUMiSizer®. Int J Pharm 553(1–2):428–440PubMedCrossRef Zielińska A, Martins-Gomes C, Ferreira NR, Silva AM, Nowak I, Souto EB (2018) Anti-inflammatory and anti-cancer activity of citral: optimization of citral-loaded solid lipid nanoparticles (SLN) using experimental factorial design and LUMiSizer®. Int J Pharm 553(1–2):428–440PubMedCrossRef
Metadata
Title
Changes in the molecular structure of cellulose nanocrystals upon treatment with solvents
Authors
Zahra Hosseinpour Feizi
Pedram Fatehi
Publication date
18-06-2021
Publisher
Springer Netherlands
Published in
Cellulose / Issue 11/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-021-03972-x

Other articles of this Issue 11/2021

Cellulose 11/2021 Go to the issue