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21-03-2022 | Original Research

Characterization of a magnetic hybrid film fabricated by the in-situ synthesis of iron oxide nanoparticles into ethyl cellulose polymer

Authors: Jesús Gabino Puente-Córdova, Martín Edgar Reyes-Melo, Beatriz López-Walle, Isaac Yair Miranda-Valdez, Alejandro Torres-Castro

Published in: Cellulose | Issue 7/2022

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Abstract

This study deals with the fabrication and characterization of a magnetic hybrid film, IONP/EC, comprised of iron oxide nanoparticles and ethyl cellulose. Its manufacture followed two steps: the fabrication of a precursor hybrid film, and its alkaline treatment. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), high-resolution transmission electron microscopy (HRTEM), and thermogravimetric analysis (TGA) demonstrated a successful in-situ synthesis of IONPs in the EC matrix. Furthermore, through vibrating sample magnetometer (VSM) and dynamic mechanical analysis (DMA), the magnetic and viscoelastic properties of the film were characterized, respectively. Using XRD analysis, the crystalline structure of IONPs showed to be an iron oxide hydroxide phase. Although it cannot be dismissed other phases, such as maghemite and magnetite. FTIR results revealed that the EC matrix preserved its chemical structure. Images obtained by HRTEM evidenced quasi-spherical IONPs embedded into the EC matrix with an average particle size of 2.4 nm. The IONP/EC film exhibited a superparamagnetic-like behavior, showing a blocking temperature at 20 K. After TGA analysis, IONPs slightly impacted the thermal stability of the EC matrix. Finally, DMA results revealed a modification on the structural relaxation phenomena of EC, which arose from the presence of IONPs in the matrix.

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Akbarzadeh A, Samiei M, Davaran S (2012) Magnetic nanoparticles: preparation, physical properties, and applications in biomedicine. Nanoscale Res Lett 7:144. https://doi.org/10.1186/1556-276X-7-144CrossRefPubMedPubMedCentral

Alcoutlabi M, Martinez-Vega JJ (1999) Modified fractional model to describe the viscoelastic behavior of solid amorphous polymers: the effect of physical aging. J Macromol Sci Phys 38:991–1007. https://doi.org/10.1080/00222349908248154CrossRef

Ali AF, Hassan ML, Ward AA, El-Giar EM (2017) Processing, dynamic mechanical thermal analysis, and dielectric properties of barium titanate/cellulosic polymer nanocomposites. Polym Compos 38:893–907. https://doi.org/10.1002/pc.23651CrossRef

Ansari MO, Ahmad MF, Parveen N et al (2017) Iron oxide nanoparticles-synthesis, surface modification, applications and toxicity: a review. Mater Focus 6:1–11. https://doi.org/10.1166/mat.2017.1410CrossRef

Bidault O, Assifaoui A, Champion D, Le Meste M (2005) Dielectric spectroscopy measurements of the sub-Tg relaxations in amorphous ethyl cellulose: a relaxation magnitude study. J Non Cryst Solids 351:1167–1178. https://doi.org/10.1016/j.jnoncrysol.2005.03.014CrossRef

Clark DE (2001) Peroxides and peroxide-forming compounds. Chem Health Saf 8:12–21. https://doi.org/10.1016/S1074-9098(01)00247-7CrossRef

Colombini D, Merle G, Alberola ND (2001) Use of mechanical modeling to study multiphase polymeric materials. Macromolecules 34:5916–5926. https://doi.org/10.1021/ma010076vCrossRef

Davidovich-Pinhas M, Barbut S, Marangoni AG (2014) Physical structure and thermal behavior of ethylcellulose. Cellulose 21(5):3243–3255. https://doi.org/10.1007/s10570-014-0377-1CrossRef

Diogo HP, Moura-Ramos J (2009) Secondary molecular mobility in amorphous ethyl cellulose: aging effects and degree of co-operativity. J Polym Sci Part B Polym Phys 47:820–829. https://doi.org/10.1002/polb.21688CrossRef

Es-haghi H, Mirabedini SM, Imani M, Farnood RR (2014) Preparation and characterization of pre-silane modified ethyl cellulose-based microcapsules containing linseed oil. Coll Surf Physicochem Eng Asp 447:71–80. https://doi.org/10.1016/j.colsurfa.2014.01.021CrossRef

Haigler CH, Roberts AW (2019) Structure/function relationships in the rosette cellulose synthesis complex illuminated by an evolutionary perspective. Cellulose. https://doi.org/10.1007/s10570-018-2157-9CrossRef

Horita S, Hatakeyama T, Hatakeyama H (2008) DSC and DMA of ECs and EC–MC blends. In: Hu Thomas Q (ed) Characterization of lignocellulosic materials. Blackwell Publishing Ltd., Oxford, pp 316–328. https://doi.org/10.1002/9781444305425.ch18CrossRef

Kaur GA, Kumar S, Thakur S et al (2021a) Structural and ferroelectric growth of Ba0.85Mg0.15TiO₃–Ga₂O₃ ceramic through hydrothermal method. J Mater Sci Mater Electron 32:23631–23644. https://doi.org/10.1007/s10854-021-06854-xCrossRef

Kaur GA, Sharma V, Gupta N et al (2021b) Structural and optical amendment of PVDF into CQDs through high temperature calcination process. Mater Lett 304:130616. https://doi.org/10.1016/j.matlet.2021.130616CrossRef

Kesten C, Menna A, Sánchez-Rodríguez C (2017) Regulation of cellulose synthesis in response to stress. Curr Opin Plant Biol 40:106–113. https://doi.org/10.1016/j.pbi.2017.08.010CrossRefPubMed

Kirchberg S, Rudolph M, Ziegmann G, Peuker UA (2012) Nanocomposites based on technical polymers and sterically functionalized soft magnetic magnetite nanoparticles: synthesis, processing, and characterization. J Nanomater. https://doi.org/10.1155/2012/670531CrossRef

Kumar DS, Naidu KCB, Rafi MM et al (2018) Structural and dielectric properties of superparamagnetic iron oxide nanoparticles (SPIONs) stabilized by sugar solutions. Mater Sci Pol 36:123–133. https://doi.org/10.1515/msp-2018-0017CrossRef

Llamas-Hernández M, López-Walle B, Rakotondrabe M, Reyes-Melo E (2018) Dynamic behavior of magnetic hybrid films of polyvinyl butyral/iron oxide nanoparticles (PVB/Fe₂O₃) for their control as microactuators. Phys B Condens Matter 549:113–117. https://doi.org/10.1016/j.physb.2017.10.095CrossRef

Lomakin SM, Rogovina SZ, Grachev AV et al (2011) Thermal degradation of biodegradable blends of polyethylene with cellulose and ethylcellulose. Thermochim Acta 521:66–73. https://doi.org/10.1016/j.tca.2011.04.005CrossRef

Luna-Martínez JF, Reyes-Melo E, González-González V et al (2010) Iron oxide nanoparticles obtained from a Fe(II)–Chitosan polymer film. Mater Sci Forum 644:51–55. https://doi.org/10.4028/www.scientific.net/MSF.644.51CrossRef

Luna-Martínez JF, Reyes-Melo E, González-González V et al (2013) Synthesis and characterization of a magnetic hybrid material consisting of iron oxide in a carboxymethyl cellulose matrix. J Appl Polym Sci 127:1–7. https://doi.org/10.1002/app.37892CrossRef

Mallat T, Baiker A (2011) Reactions in ‘“sacrificial”’ solvents. Catal Sci Technol 1:1572–1583. https://doi.org/10.1039/C1CY00207DCrossRef

McNamara JT, Morgan JLW, Zimmer J (2015) A molecular description of cellulose biosynthesis. Annu Rev Biochem 84:895–921. https://doi.org/10.1146/annurev-biochem-060614-033930CrossRefPubMedPubMedCentral

Mehta R, Teckoe J, Schoener C et al (2016) Investigation into the effect of ethylcellulose viscosity variation on the drug release of metoprolol tartrate and acetaminophen extended release multiparticulates—part I. AAPS PharmSciTech 17:1366–1375. https://doi.org/10.1208/s12249-015-0465-zCrossRefPubMed

Puente-Córdova JG, Reyes-Melo ME, Palacios-Pineda LM et al (2018) Fabrication and characterization of isotropic and anisotropic magnetorheological elastomers, based on silicone rubber and carbonyl iron microparticles. Polymers (basel) 10:1–13. https://doi.org/10.3390/polym10121343CrossRef

Qiu X, Hu S (2013) “Smart” materials based on cellulose: a review of the preparations, properties, and applications. Materials 6:738–781. https://doi.org/10.3390/ma6030738CrossRefPubMedPubMedCentral

Rentería-Baltiérrez FY, Reyes-Melo ME, López-Walle B, García-Loera AF (2019) The effect of iron oxide nanoparticles on the mechanical relaxation of magnetic polymer hybrid films composed of a polystyrene matrix, a fractional calculus approach. J Appl Polym Sci 136:1–14. https://doi.org/10.1002/app.47840CrossRef

Rentería-Baltiérrez FY, Reyes-Melo ME, López-Walle B et al (2020) A fractional calculus approach to study mechanical relaxations on hybrid films of Fe₂O₃ nanoparticles and polyvinyl butyral. J Therm Anal Calorim 139:113–124. https://doi.org/10.1007/s10973-019-08369-4CrossRef

Reyes-Melo ME, Puente-Córdova JG, López-Walle B et al (2018) Síntesis y caracterización de un material polimérico híbrido magnético de nanopartículas de óxido de hierro en una matriz de polivinil butiral. Ing Investig y Tecnol 19:113–123

Reyes-Melo ME, Miranda-Valdez IY, Puente-Córdova JG et al (2021) Fabrication and characterization of a biocompatible hybrid film based on silver nanoparticle/ethyl cellulose polymer. Cellulose 28:9227–9240. https://doi.org/10.1007/s10570-021-04066-4CrossRef

Sahu S, Dutta RK (2011) Novel hybrid nanostructured materials of magnetite nanoparticles and pectin. J Magn Magn Mater 323:980–987. https://doi.org/10.1016/j.jmmm.2010.11.085CrossRef

Saruchi TP, Kumar V (2019) Kinetics and thermodynamic studies for removal of methylene blue dye by biosynthesize copper oxide nanoparticles and its antibacterial activity. J Environ Heal Sci Eng 17:367–376. https://doi.org/10.1007/s40201-019-00354-1CrossRef

Saruchi SM, Hatshan MR et al (2021) Sequestration of eosin dye by magnesium (II)-doped zinc oxide nanoparticles: its kinetic, isotherm, and thermodynamic studies. J Chem Eng Data 66:646–657. https://doi.org/10.1021/acs.jced.0c00810CrossRef

Scarpelli F, Crispini A, Giorno E et al (2020) Preparation and characterization of silver(I) ethylcellulose thin films as potential food packaging materials. ChemPlusChem 85:426–440. https://doi.org/10.1002/cplu.201900681CrossRefPubMed

Sethi S, Saruchi KBS et al (2020) Cross-linked xanthan gum–starch hydrogels as promising materials for controlled drug delivery. Cellulose 27:4565–4589. https://doi.org/10.1007/s10570-020-03082-0CrossRef

Shaghaleh H, Xu X, Wang S (2018) Current progress in production of biopolymeric materials based on cellulose, cellulose nanofibers, and cellulose derivatives. RSC Adv 8:825–842. https://doi.org/10.1039/c7ra11157fCrossRef

Shandilya M, Thakur S, Thakur S (2020) Magnetic amendment in the fabrication of environment friendly and biodegradable iron oxide/ethyl cellulose nanocomposite membrane via electrospinning. Cellulose 27:10007–10017. https://doi.org/10.1007/s10570-020-03455-5CrossRef

Sharma V, Anit Kaur G, Gupta N, Shandilya M (2020) Growth mechanism of rGO/CDs by electrospun calcination process: structure and application. FlatChem 24:100195. https://doi.org/10.1016/j.flatc.2020.100195CrossRef

Shi J, Liu W, Jiang X, Liu W (2020) Preparation of cellulose nanocrystal from tobacco-stem and its application in ethyl cellulose film as a reinforcing agent. Cellulose 27:1393–1406. https://doi.org/10.1007/s10570-019-02904-0CrossRef

Thakur S, Shandilya M, Thakur S, Sharma DK (2020) Growth mechanism and characterization of CuO nanostructure as a potent antimicrobial agent. Surf Interfaces 20:100551. https://doi.org/10.1016/j.surfin.2020.100551CrossRef

Torres-Martínez NE, Durán-Guerrero JG, Garza-Navarro MA et al (2019) Polysaccharide-based hybrid nanostructures with tunable magnetic response. Mater Sci Eng B 243:158–166. https://doi.org/10.1016/j.mseb.2019.04.007CrossRef

Trivedi MK, Branton A, Trivedi D et al (2015) Characterization of physicochemical and thermal properties of biofield treated ethyl cellulose and methyl cellulose. Int J Biomed Mater Res 3:83–91

Tufani A, Qureshi A, Niazi JH (2021) Iron oxide nanoparticles based magnetic luminescent quantum dots (MQDs) synthesis and biomedical/biological applications: a review. Mater Sci Eng C 118:111545. https://doi.org/10.1016/j.msec.2020.111545CrossRef

Wasilewska K, Winnicka K (2019) Ethylcellulose-a pharmaceutical excipient with multidirectional application in drug dosage forms development. Materials. https://doi.org/10.3390/ma12203386CrossRefPubMedPubMedCentral

Wüstenberg T (2014) Cellulose and cellulose derivatives in the food industry. Wiley-VCH, GermanyCrossRef

Zhang Q, An C, Fan S et al (2018) Flexible gas sensor based on graphene/ethyl cellulose nanocomposite with ultra-low strain response for volatile organic compounds rapid detection. Nanotechnology 29:285501. https://doi.org/10.1088/1361-6528/aabf2fCrossRefPubMed

Title: Characterization of a magnetic hybrid film fabricated by the in-situ synthesis of iron oxide nanoparticles into ethyl cellulose polymer
Authors: Jesús Gabino Puente-Córdova
Martín Edgar Reyes-Melo
Beatriz López-Walle
Isaac Yair Miranda-Valdez
Alejandro Torres-Castro
Publication date: 21-03-2022
Publisher: Springer Netherlands
Published in: Cellulose / Issue 7/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04528-3

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