Skip to main content
main-content
Top

About this book

This book presents the latest research on fundamental aspects of acoustic bubbles, and in particular on various complementary ways to characterize them. It starts with the dynamics of a single bubble under ultrasound, and then addresses few-bubble systems and the formation and development of bubble structures, before briefly reviewing work on isolated bubbles in standing acoustic waves (bubble traps) and multibubble systems where translation and interaction of bubbles play a major role. Further, it explores the interaction of bubbles with objects, and highlights non-spherical bubble dynamics and the respective collapse geometries. It also discusses the important link between bubble dynamics and energy focusing in the bubble, leading to sonochemistry and sonoluminescence.

The second chapter focuses on the emission of light by cavitation bubbles at collapse (sonoluminescence) and on the information that can be gained by sonoluminescence (SL) spectroscopy, e.g. the conditions reached inside the bubbles or the nature of the excited species formed. This chapter also includes a section on the use of SL intensity measurement under pulsed ultrasound as an indirect way to estimate bubble size and size distribution.

Lastly, since one very important feature of cavitation systems is their sonochemical activity, the final chapter presents chemical characterizations, the care that should be taken in using them, and the possible visualization of chemical activity. It also explores the links between bubble dynamics, SL spectroscopy and sonochemical activity.

This book provides a fundamental basis for other books in the Molecular Science: Ultrasound and Sonochemistry series that are more focused on applied aspects of sonochemistry. A basic knowledge of the characterization of cavitation bubbles is indispensable for the optimization of sonochemical processes, and as such the book is useful for specialists (researchers, engineers, PhD students etc.) working in the wide area of ultrasonic processing.

Table of Contents

Frontmatter

Chapter 1. Bubble Dynamics

Bubble dynamics and cavitation have been recognized as a relevant topic of physics and engineering for more than 100 years. Starting with erosion problems at ship propellers end of the nineteenth century [1, 2], experimental and theoretical research went on to intense ultrasound fields in liquids after World War I [3]. However, the phenomena are intrinsically difficult to investigate since the involved spatial scales span many orders of magnitude, the timescales are partly extremely fast, and the behavior includes important nonlinearities.
Rachel Pflieger, Sergey I. Nikitenko, Carlos Cairós, Robert Mettin

Chapter 2. Sonoluminescence

The previous chapter presented physical characterizations of cavitation bubbles on the microscopic scale, looking, e.g., on the bubble shape, on its stability and evolution, and on the way bubble dynamics can explain energy focusing that leads to sonochemistry and sonoluminescence. These latter two phenomena are macroscopic manifestations of acoustic cavitation and can also serve to characterize bubbles and their activity.
Rachel Pflieger, Sergey I. Nikitenko, Carlos Cairós, Robert Mettin

Chapter 3. Sonochemistry

Sonochemical splitting of thermodynamically very stable water molecule provides the evidence for drastic conditions inside the cavitation bubble. Kinetics of OH radicals or H2O2 molecules formation during sonolysis of water can be used for quantification of acoustic power delivered to the system. This chapter focuses on the influence of several fundamental parameters, such as ultrasonic frequency, saturating gas, and some soluble nitrogen compounds on chemical reactivity of multibubble cavitation in homogeneous aqueous media in connection with the recent data on multibubble sonoluminescence.
Rachel Pflieger, Sergey I. Nikitenko, Carlos Cairós, Robert Mettin

Backmatter

Additional information

Premium Partner

image credits