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28-12-2022 | Technical Article

Characterizations and Kinetics of Refractory Niobium Carbide Coatings on AISI D3 Steel

Authors: Ali Günen, Hasan Hüseyin Açıkgöz, Mourad Keddam, İsmail Hakki Karahan

Published in: Journal of Materials Engineering and Performance | Issue 19/2023

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Abstract

Niobium carbide (NbC) coatings were carried out by means of the thermo-reactive diffusion (TRD) on AISI D3 cold work tool steel, in the powder mixture composed of 25 wt.% ferro-niobium, 70 wt.% alumina and 7.5 wt.% ammonium chloride at 1173, 1273 and 1373 K for 2, 4 and 6 h. NbC coatings were inspected with scanning electron microscopy, x-ray diffractometer, Vickers micro-hardness testing. Homogeneous, crack-free and uniform NbC coatings with 8.75-17.10 µm thickness and 1586-2263 HV0.025 hardness were obtained on AISI D3 steel by TRD process. The integral method-based model was used for studying the carbon diffusion by forming NbC coatings. The value of 45.93 kJ mol−1 was determined as the necessary activation energy required for the niobizing process of AISI D3 steel.

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Metadata
Title
Characterizations and Kinetics of Refractory Niobium Carbide Coatings on AISI D3 Steel
Authors
Ali Günen
Hasan Hüseyin Açıkgöz
Mourad Keddam
İsmail Hakki Karahan
Publication date
28-12-2022
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 19/2023
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-022-07768-3

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