Chemisch-katalytische Konversion | springerprofessional.de
Skip to main content
Register
Springer Professional
SEARCH
Menu 1 2 3 4
Top

Hint

Swipe to navigate through the chapters of this book

Published in:
CO2 und CO: nachhaltige Kohlenstoffquellen für die zirkuläre Wertschöpfung Read chapter Read first chapter

2020 | OriginalPaper | Chapter

6. Chemisch-katalytische Konversion

Author : Robert Schlögl

Published in: CO2 und CO – Nachhaltige Kohlenstoffquellen für die Kreislaufwirtschaft

Publisher: Springer Berlin Heidelberg

Login to get access
share
SHARE

Zusammenfassung

Oxidiert man kohlenstoffhaltige Stoffe bis zum thermodynamischen Minimum der Energie, so erhält man Carbonat. In dieser Form ist auf der Erde bei Weitem der meiste Kohlenstoff in Gesteinen gespeichert. Das Gas CO2 dagegen ist noch erheblich reaktiv und kann daher sowohl zu organischen Carbonaten oder Carboxylaten oxidiert als auch zu Kohlenwasserstoffen reduziert werden. Eine zentrale Rolle spielt dabei das erste Reduktionsprodukt CO. Bereits früh wurde dies erkannt, und die Forschung begann sich lange vor einer „Energieforschung“ mit der stofflichen Nutzung von CO2 in der chemischen Industrie zu befassen.

To get access to this content you need the following product:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 69.000 Bücher
  • über 500 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 50.000 Bücher
  • über 380 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe



 


Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 58.000 Bücher
  • über 300 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko





Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

inform now
previous chapter Herstellung von Synthesegas
next chapter Biokatalytische Konversion
Literature
1.
Aresta M, Dibenedetto A (2007) Utilisation of CO 2 as a chemical feedstock: opportunities and challenges. Dalton Trans 28:2975–2992
2.
Leitner W (1996) The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey. Coord Chem Rev 153:257–284
3.
Zhang XJ, Bauer C, Mutel CL, Volkart K (2017) Life cycle assessment of power-to-gas: approaches, system variations and their environmental implications. Appl Energ 190:326–338
4.
Naraharisetti PK, Yeo TY, Bu J (2017) Factors influencing CO 2 and energy penalties of CO 2 mineralization processes. Chemphyschem 18(22):3189–3202
5.
Wilson G, Trusler M, Yao J, Lee JSM, Graham R, Mac Dowell N, Cuellar-Franca R, Dowson G, Fennell P, Styring P, Gibbins J, Mazzotti M, Brandani S, Muller C, Hubble R (2016) End use and disposal of CO 2 – storage or utilisation? General discussion. Faraday Discuss 192:561–579
6.
Smit B (2016) Carbon capture and storage: introductory lecture. Faraday Discuss 192:9–25
7.
Perez-Fortes M, Schoneberger JC, Boulamanti A, Tzimas E (2016) Methanol synthesis using captured CO 2 as raw material: techno-economic and environmental assessment. App Energ 161:718–732
8.
Jadhav SG, Vaidya PD, Bhanage BM, Joshi JB (2014) Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies. Chem Eng Res Des 92(11):2557–2567
9.
Seh ZW, Kibsgaard J, Dickens CF, Chorkendorff IB, Nørskov JK, Jaramillo TF (2017) Combining theory and experiment in electrocatalysis: insights into materials design. Science 355(6321):eaad4998
10.
Bruhn T, Naims H, Olfe-Krautlein B (2016) Separating the debate on CO 2 utilisation from carbon capture and storage. Environ Sci Policy 60:38–43
11.
Markewitz P, Kuckshinrichs W, Leitner W, Linssen J, Zapp P, Bongartz R, Schreiber A, Mueller TE (2012) Worldwide innovations in the development of carbon capture technologies and the utilization of CO 2. Energ Environ Sci 5(6):7281–7305
12.
Lee JSM, Rochelle G, Styring P, Fennell P, Wilson G, Trusler M, Clough P, Blamey J, Dunstan M, MacDowell N, Lyth S, Yao J, Hills T, Gazzani M, Brandl P, Anantharaman R, Brandani S, Stolaroff J, Mazzotti M, Maitland G, Muller C, Dowson G, Gibbins J, Ocone R, Campbell KS, Erans M, Zheng LY, Sutter D, Armutlulu A, Smit B (2016) CCS – a technology for now: general discussion. Faraday Discuss 192:125–151
13.
Aresta M (2017) My journey in the CO 2-chemistry wonderland. Coord Chem Rev 334:150–183
14.
Mac Dowell N, Fennell PS, Shah N, Maitland GC (2017) The role of CO 2 capture and utilization in mitigating climate change. Nat Clim Change 7(4):243–249
15.
Mikkelsen M, Jorgensen M, Krebs FC (2010) The teraton challenge. A review of fixation and transformation of carbon dioxide. Energ Environ Sci 3(1):43–81
16.
Rockstrom J, Gaffney O, Rogelj J, Meinshausen M, Nakicenovic N, Schellnhuber HJ (2017) A roadmap for rapid decarbonization. Science 355(6331):1269–1271
17.
Artz J, Muller TE, Thenert K, Kleinekorte J, Meys R, Sternberg A, Bardow A, Leitner W (2018) Sustainable conversion of carbon dioxide: an integrated review of catalysis and life cycle assessment. Chem Rev 118(2):434–504
18.
Koytsoumpa EI, Bergins C, Kakaras E (2018) The CO 2 economy: review of CO 2 capture and reuse technologies. J Supercrit Fluid 132:3–16
19.
Abanades JC, Rubin ES, Mazzotti M, Herzog HJ (2017) On the climate change mitigation potential of CO 2 conversion to fuels. Energ Environ Sci 10(12):2491–2499
20.
Valente A, Iribarren D, Dufour J (2017) Life cycle assessment of hydrogen energy systems: a review of methodological choices. Int J Life Cycle Assess 22(3):346–363
21.
Cuellar-Franca RM, Azapagic A (2015) Carbon capture, storage and utilisation technologies: a critical analysis and comparison of their life cycle environmental impacts. J CO 2 Util 9:82–102
22.
Haszeldine RS (2009) Carbon capture and storage: how green can black be? Science 325(5948):1647–1652
23.
Philibert C (2017) Renewable energy for industry. International Energy Agency, Paris, S 65
24.
Palzer A, Henning HM (2014) A comprehensive model for the German electricity and heat sector in a future energy system with a dominant contribution from renewable energy technologies – Part II: results. Renew Sust Energ Rev 30:1019–1034
25.
Navarrete A, Centi G, Bogaerts A, Martin A, York A, Stefanidis GD (2017) Harvesting renewable energy for carbon dioxide catalysis. Energ Technol 5(6):796–811
26.
Perathoner S, Gross S, Hensen EJM, Wessel H, Chraye H, Centi G (2017) Looking at the future of chemical production through the European roadmap on science and technology of catalysis the EU effort for a long-term vision. ChemCatChem 9(6):904–909
27.
Bukthiyarova M, Lunkenbein T, Kähler K, Schlögl R (2017) Methanol synthesis from industrial CO 2 sources: a contribution to chemical energy conversion. Catal Lett 147(2):416–427
28.
Maruoka N, Akiyama T (2006) Exergy recovery from steelmaking off-gas by latent heat storage for methanol production. Energy 31(10–11):1632–1642
29.
Yoon YI, Kim YE, Nam SC, Park SY, Chun IS, Lee SD, Kim HS (2017) Economic analysis of CCU in the Korean cement industry: CO 2 capture using KIERSOL & PCC conversion. Energy Procedia 114:6240–6245
30.
Bridgwater AV (1995) The technical and economic feasibility of biomass gasification for power generation. Fuel 74(5):631–653
31.
Aresta M, Dibenedetto A, Angelini A (2014) Catalysis for the valorization of exhaust carbon: from CO 2 to chemicals, materials, and fuels. Technological use of CO 2. Chem Rev 114(3):1709–1742
32.
Boot-Handford ME, Abanades JC, Anthony EJ, Blunt MJ, Brandani S, Mac Dowell N, Fernandez JR, Ferrari MC, Gross R, Hallett JP, Haszeldine RS, Heptonstall P, Lyngfelt A, Makuch Z, Mangano E, Porter RTJ, Pourkashanian M, Rochelle GT, Shah N, Yao JG, Fennell PS (2014) Carbon capture and storage update. Energ Environ Sci 7(1):130–189
33.
Freund HJ, Roberts MW (1996) Surface chemistry of carbon dioxide. Surf Sci Rep 25(8):225–273
34.
Grasa G, Martinez I, Diego ME, Abanades JC (2014) Determination of CaO carbonation kinetics under recarbonation conditions. Energ Fuels 28(6):4033–4042
35.
Hariharan S, Mazzotti M (2017) Kinetics of flue gas CO 2 mineralization processes using partially dehydroxylated lizardite. Chem Eng J 324:397–413
36.
Prigiobbe V, Mazzotti M (2013) Precipitation of Mg-carbonates at elevated temperature and partial pressure of CO 2. Chem Eng J 223:755–763
37.
Klankermayer J, Wesselbaum S, Beydoun K, Leitner W (2016) Selective catalytic synthesis using the combination of carbon dioxide and hydrogen: catalytic chess at the interface of energy and chemistry. Angew Chem Int Ed 55(26):7296–7343
38.
Federsel C, Ziebart C, Jackstell R, Baumann W, Beller M (2012) Catalytic hydrogenation of carbon dioxide and bicarbonates with a well-defined cobalt dihydrogen complex. Chem Eur J 18(1):72–75
39.
Zhang S, Shao Y, Yin G, Lin Y (2010) Facile synthesis of PtAu alloy nanoparticles with high activity for formic acid oxidation. J Power Sources 195(4):1103–1106
40.
Rienacker G, Muller H (1968) Catalytic studies in alloys. 31. Decomposition of formic acid vapor on silver-palladium alloys. Z Anorg Allg Chem 357(4–6):255
41.
Göthel H (1996) Fischer-Tropsch-Synthese und verwandte Verfahren. In: Zerbe C (Hrsg) Mineralöle und verwandte Produkte. Springer, Berlin, S 572–580
42.
Van der Laan GP, Beenackers A (1999) Kinetics and selectivity of the Fischer-Tropsch synthesis: a literature review. Catal Rev Sci Eng 41(3–4):255–318
43.
Anderson RB, Hofer LJE, Storch HH (1958) Der Reaktionsmechanismus der Fischer-Tropsch-Synthese. Chem Ing Tech 9:560–566
44.
Iglesia E, Reyes SC, Madon RJ, Soled SL (1993) Selectivity control and catalyst design in the Fischer-Tropsch synthesis – sites, pellets, and reactors. Adv Catal 39:221–302
45.
Biloen P, Sachtler WMH (1981) Mechanism of hydrocarbon synthesis over Fischer-Tropsch catalysts. Adv Catal 30:165–216
46.
Dry ME (2002) The Fischer-Tropsch process: 1950–2000. Catal Today 71(3–4):227–241
47.
Ponec V (1978) Some aspects of mechanism of methanation and Fischer-Tropsch synthesis. Catal Rev Sci Eng 18(1):151–171
48.
Lorenzi G, Lanzini A, Santarelli M, Martin A (2017) Exergo-economic analysis of a direct biogas upgrading process to synthetic natural gas via integrated high-temperature electrolysis and methanation. Energy 141:1524–1537
49.
Ronsch S, Schneider J, Matthischke S, Schluter M, Gotz M, Lefebvre J, Prabhakaran P, Bajohr S (2016) Review on methanation – from fundamentals to current projects. Fuel 166:276–296
50.
Ichikawa S (1989) Reavtive chemisorption and methanation of carbon-dioxide on rhodium particles approaching atomic dispersion. J Mol Catal 53(1):53–65
51.
Lunde PJ, Kester FL (1974) Carbon-dioxide methanation on a ruthemium catalyst. Ind Eng Chem Process Des Dev 13(1):27–33
52.
Ronsch S, Kochermann J, Schneider J, Matthischke S (2016) Global reaction kinetics of CO and CO 2 methanation for dynamic process modeling. Chem Eng Technol 39(2):208–218
53.
Schwarz H (2011) Chemistry with methane: concepts rather than recipes. Angew Chem Int Ed 50(43):10096–10115
54.
Khodakov AY, Chu W, Fongarland P (2007) Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. Chem Rev 107(5):1692–1744
55.
Roh HS, Koo KY, Joshi UD, Yoon WL (2008) Combined H 2O and CO 2 reforming of methane over Ni-Ce-ZrO 2 catalysts for gas to liquids (GTL). Catal Lett 125(3–4):283–288
56.
Hao X, Djatmiko ME, Xu YY, Wang YN, Chang J, Li YW (2008) Simulation analysis of a GTL process using ASPEN plus. Chem Eng Technol 31(2):188–196
57.
Ail SS, Dasappa S (2016) Biomass to liquid transportation fuel via Fischer Tropsch synthesis – technology review and current scenario. Renew Sust Energ Rev 58:267–286
58.
Leitner W, Klankermayer J, Pischinger S, Pitsch H, Kohse-Hoinghaus K (2017) Advanced biofuels and beyond: chemistry solutions for propulsion and production. Angew Chem Int Ed 56(20):5412–5452
59.
Olah GA (2005) Beyond oil and gas: the methanol economy. Angew Chem Int Ed 44(18):2636–2639
60.
Asinger F (1986) Methanol, Chemie- und Energierohstoff. Springer, Berlin, S 407
61.
Xu XY, Liu Y, Zhang F, Di W, Zhang YL (2007) Clean coal technologies in China based on methanol platform. Catal Today 298:61–68
62.
Schmitz N, Burger J, Strofer E, Hasse H (2016) From methanol to the oxygenated diesel fuel poly(oxymethylene) dimethyl ether: an assessment of the production costs. Fuel 185:67–72
63.
Zhen XD, Wang Y (2015) An overview of methanol as an internal combustion engine fuel. Renew Sust Energ Rev 52:477–493
64.
Maus W, Jacob E (2015) Future-safe combustion-engined drives – the role of sustainable fuels. International Emgione Congress, Baden, S 283–284
65.
Hartl M, Seidenspinner P, Jacob E, Wachtmeister G (2015) Oxygenate screening on a heavy-duty diesel engine and emission characteristics of highly oxygenated oxymethylene ether fuel OME1. Fuel 153:328–335
66.
Lautenschutz L, Oestreich D, Haltenort P, Arnold U, Dinjus E, Sauer J (2017) Efficient synthesis of oxymethylene dimethyl ethers (OME) from dimethoxymethane and trioxane over zeolites. Fuel Process Technol 165:27–33
67.
Deutsch D, Oestreich D, Lautenschutz L, Haltenort P, Arnold U, Sauer J (2017) High purity oligomeric oxymethylene ethers as diesel fuels. Chem Ing Tech 89(4):486–489
68.
Haertl M, Seidenspinner P, Jacob E, Wachtmeister G (2015) Oxygenate screening on a heavy-duty diesel engine and emission characteristics of highly oxygenated oxymethylene ether fuel OME1. Fuel 153:328–335
69.
Deutz S, Bongartz D, Heuser B, Katelhon A, Langenhorst LS, Omari A, Walters M, Klankermayer J, Leitner W, Mitsos A, Pischinger S, Bardow A (2018) Cleaner production of cleaner fuels: wind-to-wheel – environmental assessment of CO 2-based oxymethylene ether as a drop-in fuel. Energ Environ Sci 11(2):331–343
70.
Peter A, Fehr SM, Dybbert V, Himmel D, Lindner I, Jacob E, Ouda M, Schaadt A, White RJ, Scherer H, Krossing I (2018) Towards a sustainable synthesis of oxymethylene dimethyl ether by homogeneous catalysis and uptake of molecular formaldehyde. Angew Chem Int Ed 57(30):9461–9464
71.
Omari A, Heuser B, Pischinger S (2017) Potential of oxymethylenether-diesel blends for ultra-low emission engines. Fuel 209:232–237
72.
Tursunov O, Kustov L, Kustov A (2017) A brief review of carbon dioxide hydrogenation to methanol over copper and iron based catalysts. Oil Gas Sci Technol 72(5):30
73.
Frei MS, Capdevila-Cortada M, Garcia-Muelas R, Mondelli C, Lopez N, Stewart JA, Ferre DC, Perez-Ramirez J (2018) Mechanism and microkinetics of methanol synthesis via CO 2 hydrogenation on indium oxide. J Catal 361:313–321
74.
Studt F, Behrens M, Kunkes EL, Thomas N, Zander S, Tarasov A, Schumann J, Frei E, Varley JB, Abild-Pedersen F, Nørskov JK, Schlögl R (2015) The mechanism of CO and CO 2 hydrogenation to methanol over Cu-based catalysts. ChemCatChem 7(7):1105–1111
75.
Bahruji H, Esquius JR, Bowker M, Hutchings G, Armstrong RD, Jones W (2018) Solvent free synthesis of PdZn/TiO 2 catalysts for the hydrogenation of CO 2 to methanol. Top Catal 61(3–4):144–153
76.
Zurbel A, Kraft M, Kavurucu-Schubert S, Bertau M (2018) Methanol synthesis by CO 2 hydrogenation over Cu/ZnO/Al 2O 3 catalysts under fluctuating conditions. Chem Ing Tech 90(5):721–724
77.
Bukhtiyarova M, Lunkenbein T, Kähler K, Schlögl R (2017) Methanol synthesis from industrial CO 2 sources: a contribution to chemical energy conversion. Catal Lett 147(2):416–427
78.
Kunkes EL, Studt F, Abild-Pedersen F, Schlögl R, Behrens M (2015) Hydrogenation of CO 2 to methanol and CO on Cu/ZnO/Al 2O 3: is there a common intermediate or not? J Catal 328:43–48
79.
Li M, Rao AD, Brouwer J, Samuelsen GS (2010) Design of highly efficient coal-based integrated gasification fuel cell power plants. J Power Sources 195(17):5707–5718
Metadata
Title
Chemisch-katalytische Konversion
Author
Robert Schlögl
Copyright Year
2020
Publisher
Springer Berlin Heidelberg
Book
CO2 und CO – Nachhaltige Kohlenstoffquellen für die Kreislaufwirtschaft

Print ISBN: 978-3-662-60648-3

Electronic ISBN: 978-3-662-60649-0

Copyright Year: 2020

DOI
https://doi.org/10.1007/978-3-662-60649-0_6

Premium Partner

Pluta
    Image Credits