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Time-Dependent Density Functional Response Theory for Electronic Chiroptical Properties of Chiral Molecules Read chapter Read first chapter

2011 | OriginalPaper | Chapter

Chiral Control of Current Transfer in Molecules

Authors : Vered Ben-Moshe, David N. Beratan, Abraham Nitzan, Spiros S. Skourtis

Published in: Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures

Publisher: Springer Berlin Heidelberg

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Abstract

Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror image structures. This behavior is described in terms of current transfer: the transfer of both charge and momentum. We review recent theoretical developments on the theory of current transfer and discuss related experimental studies of electron transmission through chiral molecular structures adsorbed on surfaces.

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previous chapter Spin Selective Electron Transmission Through Monolayers of Chiral Molecules
next chapter Spin-Polarized Electron Induced Asymmetric Reactions in Chiral Molecules
Footnotes
1
Au photoelectrons are spin polarized due to the high spin-orbit coupling of the metal. Therefore, an alternative mechanism for the transmission asymmetry obseved in [36] could be based on changes in the photoelectron spin angular momentum. We do not attribute the yield asymmetry to spin polarization because the stearoyl-lysine monolayers in [36] contain only low atomic number atoms that do not scatter spin.
 
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Metadata
Title
Chiral Control of Current Transfer in Molecules
Authors
Vered Ben-Moshe
David N. Beratan
Abraham Nitzan
Spiros S. Skourtis
Copyright Year
2011
Publisher
Springer Berlin Heidelberg
Book
Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures

Print ISBN: 978-3-642-18103-0

Electronic ISBN: 978-3-642-18104-7

Copyright Year: 2011

DOI
https://doi.org/10.1007/128_2010_101

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