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Published in: Journal of Polymer Research 12/2017

01-11-2017 | ORIGINAL PAPER

Chitosan-g-poly(4-acrylamidobenzenesulfonamide) copolymers: synthesis, characterization, and bioactivity

Authors: Fakhreia Al-Sagheer, Khaled Khalil, Huda Mahmoud, Abdel-Zaher Elassar, Enas Ibrahim

Published in: Journal of Polymer Research | Issue 12/2017

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Abstract

The monomer, 4-acrylamidobenzenesulfonamide (ABS), was synthesized via reaction of acryloyl chloride with 4-aminobenzenesulfonamide in acetone at 0 °C. This monomer was then grafted onto chitosan using solution containing 2% acetic acid and mixture of K2S2O8 and Na2SO3 as the redox promoter. An optimal G% of 150% was obtained when the process is conducted at 60 °C for 3 h employing 3.0 × 10−3 M K2S2O8 and 1.5 × 10−3 M Na2SO3. The graft copolymers, chitosan-g-poly(4-acrylamidobenzenesulfonamide), were characterized by using FTIR, XRD, and SEM. The results were shown that the crystallinity of chitosan is enhanced by increasing the monomer content through the grafting process. Potential Antimicrobial activities of the permethyl ammonium salt forms of chitosan and its grafted copolymers against selected microorganisms were evaluated. The results show that the graft copolymers display better inhibitory effects on the growth of bacteria and some fungi than does chitosan.

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Appendix
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Metadata
Title
Chitosan-g-poly(4-acrylamidobenzenesulfonamide) copolymers: synthesis, characterization, and bioactivity
Authors
Fakhreia Al-Sagheer
Khaled Khalil
Huda Mahmoud
Abdel-Zaher Elassar
Enas Ibrahim
Publication date
01-11-2017
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 12/2017
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1381-6

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