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Published in: Environmental Earth Sciences 17/2021

01-09-2021 | Original Article

Chronological record, source identification and ecotoxicological impact assessment of heavy metals in sediments of Kallar Kahar Lake, Salt Range-Punjab, Pakistan

Authors: Tariq Javed, Nasir Ahmad, Azhar Mashiatullah, Khalid Khan

Published in: Environmental Earth Sciences | Issue 17/2021

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Abstract

The impact of climate change was studied based on the geochemical indicators, such as total organic carbon (TOC), calcium carbonate, stable carbon isotopes and heavy metals (HMs) in sediments of Kallar Kahar Lake. The sediment core was chronological dated from 1876 to 2011 (135 years back) using 210Pb isotope and sediment accumulation rates were in the range of 0.01–0.85 g cm−2 y−1, signifying the higher sediment accumulation rates during the last decade. Sediment accumulation rates were highly variable and ranged between 0.01 and 0.85 g cm−2 y−1. The δ13C values of total organic carbon (TOC) in surface and sediment core were − 19.8 to − 13.7 and − 19.3 to − 11.9 ‰VPDB, suggesting mainly the prevalence of autochthonous source of carbon. The accumulation of organic carbon (0.3–51.4 mg C cm−2 y−1) over period from bottom to surface layer of sediment core was observed with most significant concentration in recent deposit layer. δ13Ccarb ranged from − 1.9 to 1.7 for surface sediment and − 4.08 to − 0.75 ‰VPDB sediment core; slightly lower its value than marine carbonates (0 ‰VPDB), interpreting precipitation of calcite in sediments. Magnitude of HMs for Cd (7.47-fold), As (2.22-fold), Ni (1.80-fold), Cu (1.23-fold) and Cr (1.19-fold) in surface sediment, and As (3.98-fold), Ni (1.58-fold) and Cu (1.26-fold) in sediment core relative to Upper Continental Crust (UCC) revealed amplification of HMs in lake sediments in the past. Pollution indices and multivariate techniques revealed higher accumulation of HMs in surface and sediment core, deciphering origin of metals from anthropogenic and natural sources. Ecological risk index (312) and sediment quality guidelines revealed that HMs may affect aquatic life in future. Results indicate that lake is highly impacted by rise in sedimentation rate and accumulation of carbon and HMs in sediments during 1950–2011 by climate change.

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Metadata
Title
Chronological record, source identification and ecotoxicological impact assessment of heavy metals in sediments of Kallar Kahar Lake, Salt Range-Punjab, Pakistan
Authors
Tariq Javed
Nasir Ahmad
Azhar Mashiatullah
Khalid Khan
Publication date
01-09-2021
Publisher
Springer Berlin Heidelberg
Published in
Environmental Earth Sciences / Issue 17/2021
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-021-09764-7

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