Skip to main content
Top

2018 | OriginalPaper | Chapter

8. Cloud Point Extraction

Authors : Sourav Mondal, Mihir Kumar Purkait, Sirshendu De

Published in: Advances in Dye Removal Technologies

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Phase separation of a surfactant-loaded solution happens beyond a certain critical thermodynamic state (known as the cloud point), separating the hydrophobic-rich phase in a nonpolar microenvironment from the aqueous supernatant. The dye molecules are bounded to the surfactant and subsequently separated by changing the environmental factor (temperature is commonly altered in cloud point extraction) beyond the cloud point. This is a popular extraction method in bioseparations but is also applicable for purification of dye solution. The chapter discusses the effect of the various operating conditions and different surfactants on extracting clear water from the dye solution with this technology.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Casero I, Sicilia D, Rubio S, Perez-Bendito D (1999) An acid induced phase cloud point separation approach using anionic surfactants for extraction and preconcentration of organic compounds. Anal Chem 71:4519–4526CrossRef Casero I, Sicilia D, Rubio S, Perez-Bendito D (1999) An acid induced phase cloud point separation approach using anionic surfactants for extraction and preconcentration of organic compounds. Anal Chem 71:4519–4526CrossRef
go back to reference Fernandez AE, Sosa-Ferrera Z, Santana-Rod- riguez JJ (1998) Determination of polychlorinated biphenyls by liquid chromatography following cloud-point extraction. Anal Chim Acta 358:145–155 Fernandez AE, Sosa-Ferrera Z, Santana-Rod- riguez JJ (1998) Determination of polychlorinated biphenyls by liquid chromatography following cloud-point extraction. Anal Chim Acta 358:145–155
go back to reference Ferrer R, Beltran JL, Guiteras J (1996) Use of cloud point extraction methodology for the determination of PAHs priority pollutants in water samples by high performance liquid chromatography with fluorescence detection and wavelength programming. Anal Chim Acta 330:199–206CrossRef Ferrer R, Beltran JL, Guiteras J (1996) Use of cloud point extraction methodology for the determination of PAHs priority pollutants in water samples by high performance liquid chromatography with fluorescence detection and wavelength programming. Anal Chim Acta 330:199–206CrossRef
go back to reference Garcia AL, Gonzalez EB, Alonso JG, Sanz-Medel A (1992) Potential of micelle-mediate procedures in the sample preparation steps for the determination of polynuclear aromatic hydrocarbons in waters. Anal Chim Acta 264:241–248 Garcia AL, Gonzalez EB, Alonso JG, Sanz-Medel A (1992) Potential of micelle-mediate procedures in the sample preparation steps for the determination of polynuclear aromatic hydrocarbons in waters. Anal Chim Acta 264:241–248
go back to reference Heegaard NH, Jakobsen DR, Klattschou D (1997) Purification of wegener’s granulomatosis autoantigen, proleinase 3, from neutrophils by triton X-114 extraction of azurophilic granules. Anal Bio- Chem 253:259–262 Heegaard NH, Jakobsen DR, Klattschou D (1997) Purification of wegener’s granulomatosis autoantigen, proleinase 3, from neutrophils by triton X-114 extraction of azurophilic granules. Anal Bio- Chem 253:259–262
go back to reference Hiemenz PC, Rajagopalan RH (1997) Principles of colloid and surface chemistry. Marcel Dekker, New York, p 377CrossRef Hiemenz PC, Rajagopalan RH (1997) Principles of colloid and surface chemistry. Marcel Dekker, New York, p 377CrossRef
go back to reference Inoue T, Ohmura H, Murata D (2003) Cloud point temperature of polyoxyethylene-type nonionic surfactants and their mixtures. J Colloid Interf Sci 258:374–382CrossRef Inoue T, Ohmura H, Murata D (2003) Cloud point temperature of polyoxyethylene-type nonionic surfactants and their mixtures. J Colloid Interf Sci 258:374–382CrossRef
go back to reference Kimchuwanit W, Osuwan S, Scamehorn JF, Harwell JH, Haller KJ (2000) Use of a micellar-rich Coacervate phase to extract Trichloroethylene from water. Sep Sci Technol 35:1991–2002CrossRef Kimchuwanit W, Osuwan S, Scamehorn JF, Harwell JH, Haller KJ (2000) Use of a micellar-rich Coacervate phase to extract Trichloroethylene from water. Sep Sci Technol 35:1991–2002CrossRef
go back to reference Lindman B, Wennerstrom H (1991) Nonionic micelles grow with increasing temperature. J Phys Chem 95:6053–6054CrossRef Lindman B, Wennerstrom H (1991) Nonionic micelles grow with increasing temperature. J Phys Chem 95:6053–6054CrossRef
go back to reference Liu CL, Nikas YJ, Blankschtein D (1996) Novel bioseparations using two-phase aqueous micellar systems. Biotechnol Bioeng 52:185–192CrossRef Liu CL, Nikas YJ, Blankschtein D (1996) Novel bioseparations using two-phase aqueous micellar systems. Biotechnol Bioeng 52:185–192CrossRef
go back to reference Namasivayam C, Kavitha D (2002) Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith and agricultural solid waste. Dyes Pigments 54:47–58CrossRef Namasivayam C, Kavitha D (2002) Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith and agricultural solid waste. Dyes Pigments 54:47–58CrossRef
go back to reference Pinto CG, Perez-Pavon JL, Moreno-Cordero B (1994) Cloud point preconcentration and high performance liquid chromatography determination of polycyclic aromatic hydrocarbons with fluorescence detection. Anal Chem 66:874–881 Pinto CG, Perez-Pavon JL, Moreno-Cordero B (1994) Cloud point preconcentration and high performance liquid chromatography determination of polycyclic aromatic hydrocarbons with fluorescence detection. Anal Chem 66:874–881
go back to reference Purkait MK, Vijay SS, DasGupta S, De S (2004) Separation of congo red by surfactant mediated cloud point extraction. Dyes Pigments 63:151–159CrossRef Purkait MK, Vijay SS, DasGupta S, De S (2004) Separation of congo red by surfactant mediated cloud point extraction. Dyes Pigments 63:151–159CrossRef
go back to reference Purkait MK, Banerjee S, Mewara S, DasGupta S, De S (2005) Cloud point extraction of toxic eosin dye using Triton X-100 as nonionic surfactant. Water Res 39:3885–3890CrossRef Purkait MK, Banerjee S, Mewara S, DasGupta S, De S (2005) Cloud point extraction of toxic eosin dye using Triton X-100 as nonionic surfactant. Water Res 39:3885–3890CrossRef
go back to reference Purkait MK, Banerjee S, DasGupta S, De S (2006) Performance of TX-100 and TX-114 for the separation of chrysoidine dye using cloud point extraction. J Hazard Mater 137:827–835CrossRef Purkait MK, Banerjee S, DasGupta S, De S (2006) Performance of TX-100 and TX-114 for the separation of chrysoidine dye using cloud point extraction. J Hazard Mater 137:827–835CrossRef
go back to reference Qiao L, Easteal AJ (1998) The interaction between triton X series surfactants and poly (ethylene glycol) in aqueous solutions. Colloid Polym Sci 276:313–320CrossRef Qiao L, Easteal AJ (1998) The interaction between triton X series surfactants and poly (ethylene glycol) in aqueous solutions. Colloid Polym Sci 276:313–320CrossRef
go back to reference Saitoh T, Hinze WL (1995) Use of surfactant mediated phase separation (cloud point extraction) with affinity ligands for the extraction of hydrophilic proteins. Talanta 42:119–127CrossRef Saitoh T, Hinze WL (1995) Use of surfactant mediated phase separation (cloud point extraction) with affinity ligands for the extraction of hydrophilic proteins. Talanta 42:119–127CrossRef
go back to reference Silva MAM, Frescura VLA, Aguilera FJN, Curtius AJ (1998) Determination of Ag and Au in geological samples by flame atomic absorption spectrometry after cloud point extraction. J Anal At Spectrom 13:1369–1373CrossRef Silva MAM, Frescura VLA, Aguilera FJN, Curtius AJ (1998) Determination of Ag and Au in geological samples by flame atomic absorption spectrometry after cloud point extraction. J Anal At Spectrom 13:1369–1373CrossRef
go back to reference Sirimanne SR, Patterson DG, Ma L, Justice JB (1998) Application of cloud point extraction reverse phase high performance liquid chromatography: a preliminary study of the extraction and quantification of vitamins A and E in human serum and whole blood. J Chromatogr B 716:129–137CrossRef Sirimanne SR, Patterson DG, Ma L, Justice JB (1998) Application of cloud point extraction reverse phase high performance liquid chromatography: a preliminary study of the extraction and quantification of vitamins A and E in human serum and whole blood. J Chromatogr B 716:129–137CrossRef
go back to reference Toerne K, Jackson R, Wandruska R (2003) POE chain length selectivity in the clouding of a triton surfactant. J Colloid Interf Sci 257:412–414CrossRef Toerne K, Jackson R, Wandruska R (2003) POE chain length selectivity in the clouding of a triton surfactant. J Colloid Interf Sci 257:412–414CrossRef
go back to reference Wang Z, Zhao F, Li D (2003) Determination of solubilization of phenol at coacervate phase of cloud point extraction. Colloids Surf A 216:207–214CrossRef Wang Z, Zhao F, Li D (2003) Determination of solubilization of phenol at coacervate phase of cloud point extraction. Colloids Surf A 216:207–214CrossRef
go back to reference Watanabe H, Tanaka H (1978) A nonionic surfactant as new solvent for liquid-liquid extraction of zinc(II) with 1-(2-pyridylazo)-2-napthol. Talanta 25:585–589CrossRef Watanabe H, Tanaka H (1978) A nonionic surfactant as new solvent for liquid-liquid extraction of zinc(II) with 1-(2-pyridylazo)-2-napthol. Talanta 25:585–589CrossRef
Metadata
Title
Cloud Point Extraction
Authors
Sourav Mondal
Mihir Kumar Purkait
Sirshendu De
Copyright Year
2018
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-10-6293-3_8