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Journal of Coatings Technology and Research
Published in: Journal of Coatings Technology and Research 4/2021

07-04-2021

CO2-triggered hydrophobic/hydrophilic switchable waterborne polyurethane–acrylate with simultaneously improved water resistance and mechanical properties

Authors: Liangfeng Xu, Zhaofei Wang, Gongwen Yang, Guobing Zhang, Haibing Wei, Huagao Fang, Yunsheng Ding

Published in: Journal of Coatings Technology and Research | Issue 4/2021

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Abstract

Traditional waterborne polyurethane (WPU) has poor water resistance because of the incorporation of permanent hydrophilic groups, such as carboxyl group or ammonium salt, into polymer chains. Therefore, developing WPU with excellent water resistance and mechanical properties is highly desirable for industrial applications. In this study, CO2-triggered hydrophobic/hydrophilic switchable waterborne polyurethane–acrylate (WPUA) containing methyl methacrylate (MMA) units were designed and synthesized. The molecular structure, hydrophobic/hydrophilic switchable behavior, water resistance, and mechanical properties were systematically investigated and characterized. The WPUA with 10 wt% MMA exhibited a low water uptake (2.15 wt%) and linear swelling ratio (0.17 L%), as well as a high tensile strength (16.7 MPa) and modulus (85.9 MPa), which were much higher than those of the pristine WPU. This study indicated that the CO2-triggered WPUA dispersed stably as latex particles in water and possessed excellent water resistance and mechanical properties after the film formation.
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Metadata
Title
CO2-triggered hydrophobic/hydrophilic switchable waterborne polyurethane–acrylate with simultaneously improved water resistance and mechanical properties
Authors
Liangfeng Xu
Zhaofei Wang
Gongwen Yang
Guobing Zhang
Haibing Wei
Huagao Fang
Yunsheng Ding
Publication date
07-04-2021
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-021-00476-y

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