Top

Journal of Nanoparticle Research

Published in:

01-03-2011 | Research Paper

Co₃O₄ @ PFR cube-like core–shell nanocomposite prepared via a facile one-step hydrothermal approach

Authors: Jie Ma, Wei Liu, Shuping Zhang, Yan Zhao

Published in: Journal of Nanoparticle Research | Issue 3/2011

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The Co₃O₄ @ phenol formaldehyde resin (PFR) cube-like nanocomposites are prepared by one-step hydrothermal process at 120–180 °C for 3–9 h. Co(NO₃)₂·6H₂O, hexamethylenetetramine (HMT), and phenol are used as precursors in water solvent. Any adventitious oxidants and additives are not presented. The transmission/scanning electronic microscope (TEM, SEM) images show as-obtained typical samples are consisted of cube-like Co₃O₄ as core and PFR as shell. The X-ray diffraction (XRD) data indicate the samples are consisted of cube-phase Co₃O₄ with amorphous PFR. Fourier transform infrared spectra (FTIR) further confirm Co₃O₄ and PFR are contained in the samples. Room-temperature vibration magnetic strength measurements (VMS) indicate that the antiferromagnetic properties of core–shell nanocomposites evidently differ from the naked-Co₃O₄ nanoparticles.

previous article Heterostructural coaxial nanotubes of CNT@Fe2O3 via atomic layer deposition: effects of surface functionalization and nitrogen-doping

next article Dispersion of dilatation wave propagation in single-wall carbon nanotubes using nonlocal scale effects

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Ahmed J, Ahmad T, Ramanujachary KV, Lofland SE, Ganguli AK (2008) Development of a microemulsion-based process for synthesis of cobalt (Co) and cobalt oxide (Co₃O₄) nanoparticles from submicrometer rods of cobalt oxalate. J Colloid Interface Sci 321:434–441CrossRef

Barakat NAM, Khil MS, Sheikh FA, Kim HY (2008) Synthesis and optical properties of two cobalt oxides (CoO and Co₃O₄) nanofibers produced by electrospinning process. J Phys Chem C 112:12225–12233CrossRef

Benitez MJ, Petracic O, Salabas EL, Radu F, Tüysüz H, Schüth F, Zabel H (2008) Evidence for core-shell magnetic behavior in antiferromagnetic Co₃O₄ nanowires. Phys Rev Lett 101:097206/1–097206/4CrossRef

Caruso F (2001) Nanoengineering of particle surfaces. Adv Mater 13:11–22CrossRef

Chen CH, Abbas SF, Morey A, Sithambaram S, Xu LP, Garces HF, Hines WA, Suib SL (2008) Controlled synthesis of self-assembled metal oxide hollow spheres via tuning redox potentials: versatile nanostructured cobalt oxides. Adv Mater 20:1205–1209CrossRef

Cong HP, Yu SH (2009) Shape control of cobalt carbonate particles by a hydrothermal process in a mixed solvent: an efficient precursor to nanoporous cobalt oxide architectures and their sensing property. Cryst Growth Des 9:210–217CrossRef

Costa L, di Montelera LR, Camino G, Weil ED, Pearce EM (1997) Structure-charring relationship in phenol-formaldehyde type resins. Polym Degrad Stab 56:23–35CrossRef

Ding Y, Xu L, Chen C, Shen X, Suib SL (2008) Syntheses of nanostructures of cobalt hydrotalcite like compounds and Co₃O₄ via a microwave-assisted reflux method. J Phys Chem C 112:8177–8183CrossRef

Gu HW, Xu KM, Xu CJ, Xu B (2006) Biofunctional magnetic nanoparticles for protein separation and pathogen detection. Chem Commun 9:941–949CrossRef

Guo SR, Gong JY, Jiang P, Wu M, Lu Y, Yu SH (2008) Biocompatible, luminescent silver@phenol formaldehyde resin core/shell nanospheres: large-scale synthesis and application for in vivo bioimaging. Adv Funct Mater 18:872–879CrossRef

He T, Chen D, Jiao X, Wang Y (2006) Co₃O₄ nanoboxes: surfactant-templated fabrication and microstructure characterization. Adv Mater 18:1078–1082CrossRef

Hilder TA, Hill JM (2009) Modeling the loading and unloading of drugs into nanotubes. Small 5:300–308CrossRef

Hu J, Wen Z, Wang Q, Yao X, Zhang Q, Zhou J, Li J (2006) Controllable synthesis and enhanced electrochemical properties of multifunctional Au_coreCo₃O_4shell nanocubes. J Phys Chem B 110:24305–24310CrossRef

López M, Blanco M, Vazquez A, Gabilondo N, Arbelaiz A, Echeverrí JM, Mondragon I (2008) Curing characteristics of resol-layered silicate nanocomposites. Thermochim Acta 467:73–79CrossRef

Luisetto I, Pepe F, Bemporad E (2008) Preparation and characterization of nano cobalt oxide. J Nanopart Res 10:59–67CrossRef

Ma J, Zhang SP, Liu W, Zhao Y (2010) Facile preparation of Co₃O₄ nanocrystals via a solvothermal process directly from common Co₂O₃ powder. J Alloys Compd 490:647–651CrossRef

Rosario-Amorin D, Wang X, Gaboyard M, Clerac R, Nlate S, Heuz K (2009) Dendron-functionalized core-shell superparamagnetic nanoparticles: magnetically recoverable and reusable catalysts for Suzuki C–C cross-coupling reactions. Chem Eur J 15:12636–12643CrossRef

Salabas EL, Rumplecker A, Kleitz F, Radu F, Schulth F (2006) Exchange anisotropy in nanocasted Co₃O₄ nanowires. Nano Lett 6:2977–2981CrossRef

Varghese B, Hoong TC, Zhu Y, Reddy MV, Chowdari BVR, Wee ATS, Tan VBC, Lim CT, Sow CH (2007) Co₃O₄ nanostructures with different morphologies and their field-emission properties. Adv Funct Mater 17:1932–1939CrossRef

Wang YZ, Zhao YX, Gao CG, Liu DS (2007) Preparation and catalytic performance of Co₃O₄ catalysts for low-temperature CO oxidation. Catal Lett 116:136–142CrossRef

Wang DC, Chang GW, Chen Y (2008a) Preparation and thermal stability of boron-containing phenolic resin/clay nanocomposites. Polym Degrad Stab 93:125–133CrossRef

Wang DS, Xie T, Peng Q, Zhang SY, Chen J, Li YD (2008b) Direct thermal decomposition of metal nitrates in octadecylamine to metal oxide nanocrystals. Chem Eur J 14:2507–2513CrossRef

Wang G, Shen X, Horvat J, Wang B, Liu H, Wexler D, Yao J (2009) Hydrothermal synthesis and optical, magnetic, and supercapacitance properties of nanoporous cobalt oxide nanorods. J Phys Chem C 113:4357–4361CrossRef

Xie XW, Li Y, Liu ZQ, Haruta M, Shen WJ (2009) Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods. Nature 458:746–749CrossRef

Zhang WM, Sun SX, Yu HY, Song XY (2003) Synthesis of Co₃O₄ nanopowder with different morphologies by hydrothermal treatment followed by decomposition. Chem J China Univ 24:2151–2154

Zhang XF, Dong XL, Huang H, Lv B, Zhu XG, Lei JP, Ma S, Liu W, Zhang ZD (2007) Synthesis, growth mechanism and magnetic properties of SiO₂-coated Co nanocapsules. Acta Mater 55:3727–3733CrossRef

Title: Co3O4 @ PFR cube-like core–shell nanocomposite prepared via a facile one-step hydrothermal approach
Authors: Jie Ma
Wei Liu
Shuping Zhang
Yan Zhao
Publication date: 01-03-2011
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 3/2011
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-010-0115-z

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 3/2011

Upconversion luminescent characteristics and peak shift of CdSeS nanocrystals under different wavelength laser excitation

Heterostructural coaxial nanotubes of CNT@Fe2O3 via atomic layer deposition: effects of surface functionalization and nitrogen-doping

Future conferences and symposia (March 2011–)

A facile pollutant-free approach toward a series of nutritionally effective calcium phosphate nanomaterials for food and drink additives

Erratum to: The long view of nanotechnology development: the National Nanotechnology Initiative at 10 years

Generation of reactive oxygen species and oxidative stress in Escherichia coli and Staphylococcus aureus by a novel semiconductor catalyst

Premium Partners