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Polymer Bulletin

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01-06-2015 | Original Paper

Complexes of hybrid copolymers with heavy metals: preparation, properties and application as catalysts for oxidation

Authors: Sevdalina Chr. Turmanova, Ivaylo V. Dimitrov, Emilya D. Ivanova, Krassimir G. Vassilev

Published in: Polymer Bulletin | Issue 6/2015

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Abstract

Metal complexes of hybrid copolymers (HC) and amino acid lysine were prepared by complex formation with salts in aqueous (VOSO₄·5H₂O, Na₂MoO₄·2H₂O, FeCl₂·4H₂O, CoCl₂·6H₂O, CuCl₂·2H₂O) and organic [VO(acac)₂ and MoO₂Cl₂] solutions. The optimal conditions for the formation of complexes between the hybrid copolymers and heavy metal ions were established. The studies carried out by FT-IR spectroscopy and electron paramagnetic resonance proved the formation of metal complexes. The one of their possible applications as catalysts for the oxidation of cyclohexene with organic hydroperoxides was shown. Good results from epoxidation were obtained using metal complexes with VO²⁺ and MoO₂ ²⁺. The activities of the complexes obtained toward cyclohexene epoxidation can be arranged in order: HC-MoO₂ ²⁺ > HC-VO²⁺. It was found out that only cyclohexene oxide is selectively obtained in this reaction. The contents of cyclohexene oxide and 2-cyclohexene-1-ol reached 38.5 and 10.4 %, respectively. In the future, new approaches should be sought for the preparation of polymer carriers with suitable amphiphilic properties.

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Title: Complexes of hybrid copolymers with heavy metals: preparation, properties and application as catalysts for oxidation
Authors: Sevdalina Chr. Turmanova
Ivaylo V. Dimitrov
Emilya D. Ivanova
Krassimir G. Vassilev
Publication date: 01-06-2015
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 6/2015
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-015-1338-z

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