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Published in: Metallurgical and Materials Transactions A 3/2017

22-12-2016

Complexity of Products of Tungsten Corrosion: Comparison of the 3D Pourbaix Diagrams with the Experimental Data

Authors: Maryana I. Nave, Konstantin G. Kornev

Published in: Metallurgical and Materials Transactions A | Issue 3/2017

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Abstract

Tungsten is one of the most attractive metals in applications where materials are subject to high temperature and strong fields. However, in harsh aqueous environment, tungsten is prone to corrosion. Control of tungsten corrosion in aqueous solutions is a challenging task: as a transition metal, tungsten is able to produce a vast variety of oxides and hydrates. To reveal the thermodynamic pathway of corrosion at different conditions, the 3D Pourbaix diagrams relating the reduction potential, pH, and concentration of different tungsten-based compounds were constructed. These diagrams allow one to identify the most thermodynamically stable tungsten-based compounds. The 3D Pourbaix diagrams were used to explain different regimes of anodic dissolution of tungsten in aqueous solutions of potassium hydroxide.

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Metadata
Title
Complexity of Products of Tungsten Corrosion: Comparison of the 3D Pourbaix Diagrams with the Experimental Data
Authors
Maryana I. Nave
Konstantin G. Kornev
Publication date
22-12-2016
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 3/2017
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-016-3888-6

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