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22-10-2021 | Original Research

Copper nanoparticles induced, trimesic acid grafted cellulose–an effective, non-hazardous processing approach for multifunctional textile with low chemical induction

Authors: Nasir Sarwar, Usama Bin Humayoun, Ghulam Dastgeer, Dae Ho Yoon

Published in: Cellulose | Issue 18/2021

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Abstract

Cross-linkers have great importance in textile due to the widespread utilization of cellulosic fibers for clothing. Unfortunately, the acute toxicity of formaldehyde-based resins and the poor performance of non-formaldehyde resins still keep the research door open for scientists in this area. Herein, we demonstrated copper nanoparticles induced trimesic acid grafted cellulose as a sustainable solution for multifunctional easy-care clothing. Our treated fabric presents crease recovery angle value of 248° comparable to that of most promising citric acid-based cross-linkers at the chemical concentration of trimesic acid as low as 2% with a sweeping improvement of around 30% in strength retention, not reported earlier. The relatively low fabric stiffness, without any yellowing, is contributing to the comfort and aesthetic demand while nanoparticles induction promoting utmost antimicrobial need. For the first time, the superiority of the development was validated by interlacing the fabric/finish traits with sustainability building blocks that provide the step forward for rapid industrialization. Furthermore, environmental, health, and safety mapping comparison provides a better understanding of the intensity of hazards that different finishing crosslinkers pose on the environment and public health. With improved performance and superior sustainability, such fabric can act as a preferable alternative to the multifunctional easy-care fabric market.

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previous article A novel polydimethylsiloxane comb-shaped copolymer containing P–N elements toward cotton fabrics: flame retardancy and antibacterial property

next article Effect of a synthesized chitosan flame retardant on the flammability, thermal properties, and mechanical properties of vinyl ester/bamboo nonwoven fiber composites

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Abdel-Salam OME, Youness ER, Mohammed NA, Morsy SMY, Omara EA, Sleem AA (2014) Citric acid effects on brain and liver oxidative stress in lipopolysaccharide-treated mice. J Med Food 17:588–598. https://doi.org/10.1089/jmf.2013.0065CrossRefPubMedPubMedCentral

Ahmed M, Sukumar N, Gideon RK (2021) Crease resistance finishing optimization of citric acid and fibroin solution for cotton fabrics. J Nat Fibers 18:297–307. https://doi.org/10.1080/15440478.2019.1623740CrossRef

Arafa Badr A (2018) Anti-microbial and durability characteristics of socks made of cotton and regenerated cellulosic fibers. Alexandria Eng J 57:3367–3373. https://doi.org/10.1016/j.aej.2017.11.015CrossRef

Berradi M, Hsissou R, Khudhair M, Assouag M, Cherkaoui O, El Bachiri A, El Harfi A (2019) Textile finishing dyes and their impact on aquatic environs. Heliyon 5. https://doi.org/10.1016/j.heliyon.2019.e02711CrossRefPubMedPubMedCentral

Bhaduri R, Bagchi S (2019) Demand aware voltage control of hybrid renewable energy tied uneven multi-level smart inverter. Trans Electr Electron Mater 20:257–268. https://doi.org/10.1007/s42341-018-00095-2CrossRef

Chen Q, Tang KPM, Ma P, Jiang G, Xu C (2017) Thermophysiological comfort properties of polyester weft-knitted fabrics for sports T-shirt. J Text Inst 108:1421–1429. https://doi.org/10.1080/00405000.2016.1255122CrossRef

Deng D, Jin Y, Cheng Y, Qi T, Xiao F (2013) Copper nanoparticles: aqueous phase synthesis and conductive films fabrication at low sintering temperature. ACS Appl Mater Interfaces 5:3839–3846. https://doi.org/10.1021/am400480kCrossRefPubMed

Doh SJ, Lee JY, Lim DY, Im JN (2013) Manufacturing and analyses of wet-laid nonwoven consisting of carboxymethyl cellulose fibers. Fibers Polym 14:2176–2184. https://doi.org/10.1007/s12221-013-2176-yCrossRef

Global Antimicrobial Textile Markets to 2025: Massive use of antimicrobial textiles in hospitals.https://www.globenewswire.com/newsrelease/2020/09/11/2092293/0/en/Global-Antimicrobial-Textile-Markets-to-2025-Massive-Use-of-Antimicrobial-Textiles-in-Hospitals.html. Accessed February 2021.

Guesmi A, Taha K, Houas A, Houas A, Hamadi NB, Hellal K, Substances N (2019) Preparation and deposition of copper nanoparticles on cellulose and their antibacterial propriety. J Optoelectron Biomed Mater 11:1–8

Hameed S, Hussain MA, Masood R, Haseeb MT (2016) Cross-linking of cotton fabric using maleic anhydride and sodium hypophosphite. Cellul Chem Technol 50:321–328

Ibrahim NA, Amr A, Eid BM (2020) Multipurpose treatment of cellulose-containing fabrics to impart durable antibacterial and repellent properties. Fibers Polym 21:513–521. https://doi.org/10.1007/s12221-020-9221-4CrossRef

Ibrahim NA, Emam EAM, Eid BM, Tawfik TM (2018) An eco-friendly multifunctional nano-finishing of cellulose/wool blends. Fibers Polym 19:797–804. https://doi.org/10.1007/s12221-018-7922-8CrossRef

Karim N, Afroj S, Lloyd K, Oaten LC, Andreeva DV, Carr C, Novoselov KS (2020) Sustainable personal protective clothing for healthcare applications: a review. ACS Nano 14:12313–12340. https://doi.org/10.1021/acsnano.0c05537CrossRefPubMedPubMedCentral

Kolotuchin SV, Fenlon EE, Wilson SR, Loweth CJ, Zimmerman SC (1996) Self-Assembly of 1,3,5-benzenetricarboxylic acids(trimesic acids) and several analogues in the solid state. Angew Chemie Int Ed English 34:2654–2657. https://doi.org/10.1002/anie.199526541CrossRef

Kumar M, Jeong DI, Yoon DH (2020) Copper nickel alloy nanorods textured nanoparticles for oxygen evolution reaction. Electrochim Acta 333:135545. https://doi.org/10.1016/j.electacta.2019.135545CrossRef

Lange LE, Obendorf SK (2015) Functionalization of cotton fiber by partial etherification and self-assembly of polyoxometalate encapsulated in Cu₃(BTC)₂ metal-organic framework. ACS Appl Mater Interfaces 7:3974–3980. https://doi.org/10.1021/am506510qCrossRefPubMed

Lee IS, Shin DM, Chung YK (2003) Self-assembly of organometallic−organic hybrid supramolecular arrays from ferrocenyl dipyridines and aromatic carboxylic acids. Cryst Growth Des 3:521–529. https://doi.org/10.1021/cg0340695CrossRef

Li X, Pillai SC, Wei L, Liu Z, Huang L, Huang Q, Wang H (2020) Facile synthesis of polyoxometalate-modified metal organic frameworks for eliminating tetrabromobisphenol-A from water. J Hazard Mater 399:122946. https://doi.org/10.1016/j.jhazmat.2020.122946CrossRefPubMed

Liang T, Yan K, Zhao T, Ji B (2020) Synthesis of a low-molecular-weight copolymer by maleic acid and acrylic acid and its application for the functional modification of cellulose. Cellulose 27:5665–5675. https://doi.org/10.1007/s10570-020-03201-xCrossRef

Lindahl E (2019) The Outdoor Apparel Industry: Measuring the premium for sustainability with a hedonic pricing model. Scripps Senior Theses. 1322. https://scholarship.claremont.edu/scripps_theses/1322/

Liu J, Wang B, Xu X, Chen J, Chen L, Yang Y (2016) Green finishing of cotton fabrics using a xylitol-extended citric acid cross-linking system on a pilot scale. ACS Sustain Chem Eng 4:1131–1138. https://doi.org/10.1021/acssuschemeng.5b01213CrossRef

Luo X, Shao D, Wang X, Xu C, Gao W (2020) Whitening citric acid treated cotton fabrics by a TBCC-activated peroxide post-bleaching. Cellulose 27:5367–5376. https://doi.org/10.1007/s10570-020-03111-yCrossRef

Manasoglu G, Kanik M, Yildirim K (2019) Effect of fixation conditions on yellowing behavior of cellulose powder-coated fabrics. J Eng Fibers Fabr 14:1–14. https://doi.org/10.1177/1558925019829049CrossRef

Mohsin M, Carr CM, Rigout M (2013) Development of zero formaldehyde easy care finishing system by using nano titanium dioxide with citric acid and its impact on physical properties. Fibers Polym 14:1440–1444. https://doi.org/10.1007/s12221-013-1440-5CrossRef

Mohsin M, Sarwar N, Ahmad S, Rasheed A, Ahmad F, Afzal A, Zafar S (2016) Maleic acid crosslinking of C-6 fluorocarbon as oil and water repellent finish on cellulosic fabrics. J Clean Prod. https://doi.org/10.1016/j.jclepro.2015.10.045CrossRef

Nimkar U (2018) Sustainable chemistry: a solution to the textile industry in a developing world. Curr Opin Green Sustain Chem 9:13–17. https://doi.org/10.1016/j.cogsc.2017.11.002CrossRef

Patil NV, Netravali AN (2020) Multifunctional sucrose acid as a ‘green’ crosslinker for wrinkle-free cotton fabrics. Cellulose 27:5407–5420. https://doi.org/10.1007/s10570-020-03130-9CrossRef

Polimbetova GS, Aleshkova MM, Bugubaeva GO, Ibraimova ZU, Borangazieva AK (2004) Oxidative alkoxylation of hypophosphite in coordination sphere of iron(III). Koord Khimiya 30:436–442

Qi H, Zhao C, Qing F, Yan K, Sun G (2016) Antiwrinkle finishing of cotton fabrics with 5-(carbonyloxy succinic)-benzene-1,2,4-tricarboxylic acid: comparison with other acids. Ind Eng Chem Res 55:11850–11856. https://doi.org/10.1021/acs.iecr.6b03287CrossRef

Sarwar N, Ashraf M, Mohsin M, Rehman A, Younus A, Javid A, Riaz S (2019) Multifunctional formaldehyde free finishing of cotton by using metal oxide nanoparticles and ecofriendly cross-linkers. Fibers Polym. https://doi.org/10.1007/s12221-019-9170-yCrossRef

Sarwar N, Choi SH, Dastgeer G, Humayoun UB, Kumar M, Nawaz A, Yoon DH (2021) Synthesis of citrate-capped copper nanoparticles: A low temperature sintering approach for the fabrication of oxidation stable flexible conductive film. Appl Surf Sci 542:148609. https://doi.org/10.1016/j.apsusc.2020.148609CrossRef

Sarwar N, Bin HU, Khan AA, Kumar M, Nawaz A, Yoo JH (2020) Engineering of sustainable clothing with improved comfort and thermal properties-A step towards reducing chemical footprint. J Clean Prod 261:121189. https://doi.org/10.1016/j.jclepro.2020.121189CrossRef

Schramm C, Amann A (2019) Formaldehyde-free, crease-resistant functionalization of cellulosic material modified by a hydrolyzed dicarboxylic acid based alkoxysilane/melamine finishing system. Cellulose 26:4641–4654. https://doi.org/10.1007/s10570-019-02391-3CrossRef

Shams S, Ahmad W, Memon AH, Shams S, Wei Y, Yuan Q, Liang H (2020) Cu/H 3 BTC MOF as a potential antibacterial therapeutic agent against Staphylococcus aureus and Escherichia coli. New J Chem 44:17671–17678. https://doi.org/10.1039/D0NJ04120CCrossRef

Suman R, Javaid M, Haleem A, Vaishya R, Bahl S, Nandan D (2020) Sustainability of coronavirus on different surfaces. J Clin Exp Hepatol. https://doi.org/10.1016/j.jceh.2020.04.020CrossRefPubMedPubMedCentral

Tahvildar A, Ezazshahabi N, Mousazadegan F (2019) Appearance and comfort properties considering yarn-spinning system and weave structure in worsted woven fabrics. J Eng Fiber Fabr. https://doi.org/10.1177/1558925019845978CrossRef

Tausif M, Jabbar A, Naeem MS, Basit A, Ahmad F, Cassidy T (2018) Cotton in the new millennium: advances, economics, perceptions and problems. Text Prog 50:1–66. https://doi.org/10.1080/00405167.2018.1528095CrossRef

TBRC- The Business Research Company, 2020. Globe News Wire: Sustainable fashion market analysis shows the market progress in attempt to decrease pollution in the global ethical fashion market 2020 https://www.globenewswire.com/news-release/2020/10/28/2116073/0/en/Sustainable-Fashion-Market-Analysis-Shows-The-Market-Progress-In-Attempt-To-Decrease-Pollution-In-The-Global-Ethicalfashion-Market-2020.html. Accessed March 2021.

Van-den-Broek J, Klein CD, Pratsinis SE, Güntner AT (2020) Selective formaldehyde detection at ppb in indoor air with a portable sensor. J Hazard Mater 399:123052. https://doi.org/10.1016/j.jhazmat.2020.123052CrossRefPubMed

Wan C, Zhang G, Zhang F (2020) A novel guanidine ammonium phosphate for preparation of a reactive durable flame retardant for cotton fabric. Cellulose 27:3469–3483. https://doi.org/10.1007/s10570-020-03003-1CrossRef

Woźniak-Budych MJ, Przysiecka L, Langer K, peplinska B, Jarek M, wiesner M, Nowaczyk G, Jurga S, (2017) Green synthesis of rifampicin-loaded copper nanoparticles with enhanced antimicrobial activity. J Mater Sci Mater Med 28:42. https://doi.org/10.1007/s10856-017-5857-zCrossRefPubMed

Yokoyama S, Suzuki I, Motomiya K, Takahashi H, Tohji K (2018) Aqueous electrophoretic deposition of citric-acid-stabilized copper nanoparticles. Colloids Surfaces A Physicochem Eng Asp 545:93–100. https://doi.org/10.1016/j.colsurfa.2018.02.056CrossRef

Yan L, Li S, Song X (2017) Preparation of paper strengthening agent by esterification of cellulosic fines. Bioresour 12:469–477

Title: Copper nanoparticles induced, trimesic acid grafted cellulose–an effective, non-hazardous processing approach for multifunctional textile with low chemical induction
Authors: Nasir Sarwar
Usama Bin Humayoun
Ghulam Dastgeer
Dae Ho Yoon
Publication date: 22-10-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 18/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04251-5

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