Top

previous article Synthesis of Trifluoroacetylacetone Resin Throu...

next article Synthesis, Structural and Biological Studies of...

Hint

Swipe to navigate through the articles of this issue

12-04-2020 | Research Article-Chemistry | Issue 6/2020

Corrosion Inhibition Performance of Acarbose on Mild Steel Corrosion in Acidic Medium: An Experimental and Computational Study

Journal:: Arabian Journal for Science and Engineering > Issue 6/2020

Authors:: Sumayah Bashir, Abhinay Thakur, Hassane Lgaz, Ill-Min Chung, Ashish Kumar

» Get access to the full-text

Abstract

Acarbose was investigated for the first time as a green inhibitor of mild steel corrosion in 1.0 M HCl using theoretical and experimental techniques. Acarbose was seen to act as a mixed type of inhibitor from polarization studies. Activation and thermodynamic parameters and their effect on inhibition efficiency are reported. Langmuir adsorption isotherm was obeyed as a result of adsorption of inhibitor on metal surface. Computational calculations, i.e., molecular dynamic simulations and density functional theory, were used to acquire detailed theoretical insights. Appreciable inhibition efficiency was obtained from all the combined results. A maximum inhibition efficiency of 96% was recorded at 4000 ppm at 298 K. SEM and AFM techniques were performed for morphological and topographical studies.

Please log in to get access to this content

To get access to this content you need the following product:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 69.000 Bücher
über 500 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Umwelt
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Testen Sie jetzt 30 Tage kostenlos.

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 50.000 Bücher
über 380 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Umwelt
Maschinenbau + Werkstoffe

Testen Sie jetzt 30 Tage kostenlos.

inform now

Mahmoud, S.S.: Corrosion inhibition of iron by amphoteric surfactants in hydrochloric acid solutions. J. Mater. Sci. 42, 989–997 (2007) CrossRef

Behpour, M.; Ghoreishi, S.M.; Gandomi-Niasar, A.; Soltani, N.; Salavati-Niasari, M.: The inhibition of mild steel corrosion in hydrochloric acid media by two Schiff base compounds. J. Mater. Sci. 44, 2444–2453 (2009) CrossRef

Tang, L.; Li, X.; Mu, G.; Liu, G.; Li, L.; Liu, H.; Si, Y.: The synergistic inhibition between hexadecyltrimethyl ammonium bromide (HTAB) and NaBr for the corrosion of cold rolled steel in 0.5 M sulfuric acid. J. Mater. Sci. 41, 3063–3069 (2006) CrossRef

Kumar, A.; Bashir, S.: Review on corrosion inhibition of steel in acidic media. Int. J. ChemTech Res. 8, 391–396 (2015)

Verma, C.; Lgaz, H.; Verma, D.K.; Ebenso, E.E.; Bahadur, I.; Quraishi, M.A.: Molecular dynamics and Monte Carlo simulations as powerful tools for study of interfacial adsorption behavior of corrosion inhibitors in aqueous phase: a review. J. Mol. Liq. 260, 99–120 (2018) CrossRef

Parveen, G.; Bashir, S.; Thakur, A.; Saha, S.K.; Banerjee, P.; Kumar, A.: Experimental and computational studies of imidazolium based ionic liquid 1-methyl-3-propylimidazolium iodide on mild steel corrosion in acidic solution. Mater. Res. Express 7, 016510 (2019) CrossRef

Okafor, P.C.; Osabor, V.I.; Ebenso, E.E.: Eco-friendly corrosion inhibitors: inhibitive action of ethanol extracts of Garcinia kola for the corrosion of mild steel in H ₂SO ₄ solutions. Pigment Resin Technol. 36, 134–140 (2007) CrossRef

Bashir, S.; Singh, G.; Kumar, A.: Shatavari ( Asparagus racemosus) as green corrosion inhibitor of aluminium in acidic medium. J. Mater. Environ. Sci. 8, 4284 (2017)

Matad, P.B.; Mokshanatha, P.B.; Hebbar, N.; Venkatesha, V.T.; Tandon, H.C.: Ketosulfone drug as a green corrosion inhibitor for mild steel in acidic medium. Ind. Eng. Chem. Res. 53, 8436–8444 (2014) CrossRef

10.

Shukla, S.K.; Singh, A.K.; Ahamad, I.; Quraishi, M.A.: Streptomycin: a commercially available drug as corrosion inhibitor for mild steel in hydrochloric acid solution. Mater. Lett. 63, 819–822 (2009) CrossRef

11.

Ahamad, I.; Prasad, R.; Quraishi, M.A.: Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media. Corros. Sci. 52, 1472–1481 (2010) CrossRef

12.

Reza, I.; Saleemi, A.; Naveed, S.: Corrosion inhibition of mild steel in HCl solution by tinidazole. Pol. J. Chem. Technol. 13, 67–71 (2011) CrossRef

13.

Vaszilcsin, N.; Ordodi, V.; Borza, A.: Corrosion inhibitors from expired drugs. Int. J. Pharm. 431, 241–244 (2012) CrossRef

14.

Bashir, S.; Thakur, A.; Lgaz, H.; Chung, I.M.; Kumar, A.: Computational and experimental studies on phenylephrine as anti-corrosion substance of mild steel in acidic medium. J. Mol. Liq. 82, 233–251 (2018)

15.

Kumar, A.; Bashir, S.: Ethambutol: a new and effective corrosion inhibitor of mild steel in acidic medium. Russ. J. Appl. Chem. 89, 1158–1163 (2016) CrossRef

16.

Kumar, R.; Chahal, S.; Kumar, S.; Lata, S.; Lgaz, H.; Salghi, R.; Jodeh, S.: Corrosion inhibition performance of chromone-3-acrylic acid derivatives for low alloy steel with theoretical modeling and experimental aspects. J. Mol. Liq. 243, 439–450 (2017) CrossRef

17.

Delley, B.: From molecules to solids with the DMol ³ approach. J. Chem. Phys. 113, 7756–7764 (2007) CrossRef

18.

Materials Studio, Revision 6.0. Accelrys Inc., San Diego, USA (2013)

19.

Perdew, J.P.; Burke, K.; Wang, Y.: Erratum: Generalized gradient approximation for the exchange-correlation hole of a many-electron system. Phys. Rev. B 57, 14999 (1996) CrossRef

20.

Mulliken, R.S.: Electronic population analysis on LCAO–MO molecular wave functions. J. Chem. Phys. 23, 1833–1840 (1995) CrossRef

21.

Pearson, R.G.: Absolute electronegativity and hardness: application to inorganic chemistry. Inorg. Chem. 27, 734–740 (1988) CrossRef

22.

Sastri, V.S.; Perumareddi, J.R.: Molecular orbital theoretical studies of some organic corrosion inhibitors. Corrosion 53, 617–622 (1997) CrossRef

23.

Martinez, S.: Inhibitory mechanism of mimosa tannin using molecular modeling and substitutional adsorption isotherms. Mater. Chem. Phys. 77, 97–102 (2003) CrossRef

24.

Cao, Z.; Tang, Y.; Cang, H.; Xu, J.; Lu, G.; Jing, W.: Novel benzimidazole derivatives as corrosion inhibitors of mild steel in the acidic media. Part II: theoretical studies. Corros. Sci. 83, 292–298 (2014) CrossRef

25.

Kokalj, A.: On the HSAB based estimate of charge transfer between adsorbates and metal surfaces. Chem. Phys. 393, 1–12 (2012) CrossRef

26.

Lgaz, H.; Salghi, R.; Bhat, K.S.; Chaouiki, A.; Jodeh, S.: Correlated experimental and theoretical study on inhibition behavior of novel quinoline derivatives for the corrosion of mild steel in hydrochloric acid solution. J. Mol. Liq. 244, 154–168 (2017) CrossRef

27.

Abdallah, M.: Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution. Corros. Sci. 1, 1981–1996 (2004) CrossRef

28.

Dhaundiyal, P.; Bashir, S.; Sharma, V.; Kumar, A.: An investigation on mitigation of corrosion of aluminium by Origanum vulgare in acidic medium. Prot. Met. Phys. Chem. Surf. 54, 148–152 (2018) CrossRef

29.

Solmaz, R.: Investigation of corrosion inhibition mechanism and stability of vitamin B1 on mild steel in 0.5 M HCl solution. Corros. Sci. 81, 75–84 (2014) CrossRef

30.

Bashir, S.; Lgaz, H.; Chung, I.M.; Kumar, A.: Potential of venlafaxine in the inhibition of mild steel corrosion in HCl: insights from experimental and computational studies. Chem. Pap. 73, 2255–2264 (2019) CrossRef

31.

Saha, S.K.; Dutta, A.; Ghosh, P.; Sukul, D.; Banerjee, P.: Adsorption and corrosion inhibition effect of Schiff base molecules on the mild steel surface in 1 M HCl medium: a combined experimental and theoretical approach. Phys. Chem. Chem. Phys. 17, 5679–5690 (2015) CrossRef

32.

Verma, C.; Olasunkanmi, L.O.; Ebenso, E.E.; Quraishi, M.A.; Obot, I.B.: Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: experimental and theoretical studies. J. Phys. Chem. C 120, 11598–11611 (2016) CrossRef

33.

Pavithra, M.K.; Venkatesha, T.V.; Kumar, M.P.; Tondan, H.C.: Inhibition of mild steel corrosion by Rabeprazole sulfide. Corros. Sci. 60, 104–111 (2012) CrossRef

34.

Zhang, D.; Tang, Y.; Qi, S.; Dong, D.; Cang, H.; Lu, G.: The inhibition performance of long-chain alkyl-substituted benzimidazole derivatives for corrosion of mild steel in HCl. Corros. Sci. 102, 517–522 (2016) CrossRef

35.

Lgaz, H.; Salghi, R.; Jodeh, S.; Hammouti, B.: Effect of clozapine on inhibition of mild steel corrosion in 1.0 M HCl medium. J. Mol. Liq. 225, 271–280 (2017) CrossRef

36.

Chen, W.; Hong, S.; Xiang, B.; Luo, H.Q.; Li, M.; Li, N.B.: Corrosion inhibition of copper in hydrochloric acid by coverage with trithiocyanuric acid self-assembled monolayers. Corros. Eng., Sci. Technol. 48, 98–107 (2013) CrossRef

37.

Abu-Dalo, M.A.; Al-Rawashdeh, N.A.; Ababneh, A.: Evaluating the performance of sulfonated kraft lignin agent as corrosion inhibitor for iron-based materials in water distribution systems. Desalination 313, 105–114 (2013) CrossRef

38.

Sharma, V.; Kumar, S.; Bashir, S.; Ghelichkhah, Z.; Obot, I.B.; Kumar, A.: Use of Sapindus (reetha) as corrosion inhibitor of aluminium in acidic medium. Mater. Res. Express 5, 076510 (2018) CrossRef

39.

Mishra, A.; Verma, C.; Lgaz, H.; Srivastava, V.; Quraishi, M.A.; Ebenso, E.E.: Synthesis, characterization and corrosion inhibition studies of N-phenyl-benzamides on the acidic corrosion of mild steel: experimental and computational studies. J. Mol. Liq. 251, 317–332 (2018) CrossRef

40.

Singh, A.; Kumar, A.; Pramanik, T.: A theoretical approach to the study of some plant extracts as green corrosion inhibitor for mild steel in HCl solution. Orient. J. Chem. 29, 277–283 (2013) CrossRef

41.

Lgaz, H.; Bhat, K.S.; Salghi, R.; Jodeh, S.; Algarra, M.; Hammouti, B.; Essamri, A.: Insights into corrosion inhibition behavior of three chalcone derivatives for mild steel in hydrochloric acid solution. J. Mol. Liq. 238, 71–83 (2017) CrossRef

42.

Bashir, S.; Sharma, V.; Lgaz, H.; Chung, I.M.; Singh, A.; Kumar, A.: The inhibition action of analgin on the corrosion of mild steel in acidic medium: a combined theoretical and experimental approach. J. Mol. Liq. 263, 454–462 (2018) CrossRef

43.

Guo, L.; Ren, X.; Zhou, Y.; Xu, S.; Gong, Y.; Zhang, S.: Theoretical evaluation of the corrosion inhibition performance of 1,3-thiazole and its amino derivatives. Arab. J. Chem. 10, 121–130 (2017) CrossRef

44.

Ansari, K.R.; Quraishi, M.A.; Singh, A.: Pyridine derivatives as corrosion inhibitors for N80 steel in 15% HCl: electrochemical, surface and quantum chemical studies. Measurement 76, 136–147 (2015) CrossRef

45.

Singh, A.; Pramanik, T.; Kumar, A.; Gupta, M.: Phenobarbital: a new and effective corrosion inhibitor for mild steel in 1 M HCl solution. Asian J. Chem. 25, 9808 (2013) CrossRef

46.

Musa, A.Y.; Jalgham, R.T.; Mohamad, A.B.: Molecular dynamic and quantum chemical calculations for phthalazine derivatives as corrosion inhibitors of mild steel in 1 M HCl. Corros. Sci. 56, 176–183 (2012) CrossRef

47.

Hmamou, D.B.; Salghi, R.; Zarrouk, A.; Aouad, M.R.; Benali, O.; Zarrok, H.; Ebenso, E.E.: Weight loss, electrochemical, quantum chemical calculation, and molecular dynamics simulation studies on 2-(benzylthio)-1,4,5-triphenyl-1 H-imidazole as an inhibitor for carbon steel corrosion in hydrochloric acid. Ind. Eng. Chem. Res. 52, 14315–14327 (2013) CrossRef

48.

Jiang, L.; Qiang, Y.; Lei, Z.; Wang, J.; Qin, Z.; Xiang, B.: Excellent corrosion inhibition performance of novel quinoline derivatives on mild steel in HCl media: experimental and computational investigations. J. Mol. Liq. 255, 53–63 (2018) CrossRef

49.

Bashir, S.; Sharma, V.; Singh, G.; Lgaz, H.; Salghi, R.; Singh, A.; Kumar, A.: Electrochemical behavior and computational analysis of phenylephrine for corrosion inhibition of aluminum in acidic medium. Met. Mater. Trans. A 50, 468–479 (2019) CrossRef

50.

Singh, A.; Soni, N.; Deyuan, Y.; Kumar, A.: A combined electrochemical and theoretical analysis of environmentally benign polymer for corrosion protection of N80 steel in sweet corrosive environment. Res. Phys. 13, 102116 (2019)

Title: Corrosion Inhibition Performance of Acarbose on Mild Steel Corrosion in Acidic Medium: An Experimental and Computational Study
Authors:: Sumayah Bashir
Abhinay Thakur
Hassane Lgaz
Ill-Min Chung
Ashish Kumar
Publication date: 12-04-2020
DOI: https://doi.org/10.1007/s13369-020-04514-6
Publisher: Springer Berlin Heidelberg
Journal: Arabian Journal for Science and Engineering
Issue 6/2020
Print ISSN: 2193-567X
Electronic ISSN: 2191-4281

Premium Partners

Image Credits

Springer Professional

Hint

Swipe to navigate through the articles of this issue

Abstract

Please log in to get access to this content

To get access to this content you need the following product:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 6/2020

Low-Cost Route for Preparing Carbon–Silica Composite Mesoporous Material from Coal Gasification Slag: Synthesis, Characterization and Application in Purifying Dye Wastewater

Numerical Treatments to Analyze the Nonlinear Radiative Heat Transfer in MHD Nanofluid Flow with Solar Energy

The Dynamic Evolution of Cavitation Vacuolar Cloud with High-Speed Camera

Performance of Cladophora fracta for Bioaccumulation of Critical Raw Materials from Mine Gallery Waters

Simulation of Coplanar Proximity Charge Sensing Electrodes in CZT Detectors

Silica-Functionalized Nano-Graphene Oxide Composite as Potent-Dispersive Solid-Phase Extraction Adsorbent of Methylphenidate from Urine Samples

Premium Partners