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Journal of Materials Science

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03-05-2017 | Mechanochemical Synthesis

Crystal structure and in situ investigation of a mechanochemical synthesized 3D zinc N-(phosphonomethyl)glycinate

Authors: Manuel Wilke, Anke Kabelitz, Annett Zimathies, Klaus Rademann, Franziska Emmerling

Published in: Journal of Materials Science | Issue 20/2017

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Abstract

The mechanochemical synthesis of the zinc N-(phosphonomethyl)glycinate Zn(O₃PCH₂NH₂CH₂CO₂)·H₂O (1) is presented. The structure was solved from powder X-ray diffraction (PXRD) data. In the three-dimensional pillared structure, the Zn atoms are coordinated tetrahedrally. In situ investigations of the reaction process with synchrotron PXRD and Raman spectroscopy reveal a two-step process including the formation of an intermediate.

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Title: Crystal structure and in situ investigation of a mechanochemical synthesized 3D zinc N-(phosphonomethyl)glycinate
Authors: Manuel Wilke
Anke Kabelitz
Annett Zimathies
Klaus Rademann
Franziska Emmerling
Publication date: 03-05-2017
Publisher: Springer US
Published in: Journal of Materials Science / Issue 20/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1121-7

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