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2014 | OriginalPaper | Chapter

2. Crystallization-Based Fractionation Techniques

Authors : Harald Pasch, Muhammad Imran Malik

Published in: Advanced Separation Techniques for Polyolefins

Publisher: Springer International Publishing

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Abstract

The vast majority of commercial polyolefins are semi-crystalline materials. Depending on the chemical composition and tacticity, their melting temperatures range from ambient to temperatures exceeding 160 °C. Polyolefins form various crystalline structures that can be investigated with microscopic, spectroscopic and scattering techniques. For the analysis of the chemical composition and branching, crystallization-based fractionation methods can be used. This chapter discusses analytical techniques that are based on the crystallizability of polyolefins from dilute solutions. Experimental set-ups will be presented for the fractionation of olefin copolymers and polyolefin blends.

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Metadata
Title
Crystallization-Based Fractionation Techniques
Authors
Harald Pasch
Muhammad Imran Malik
Copyright Year
2014
DOI
https://doi.org/10.1007/978-3-319-08632-3_2

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