Skip to main content
Top
Published in:

01-02-2025 | Original Paper

Decoupling interfacial compatibilization and chain extension in polymer blends using rheology: PBAT/EVOH with MDI

Authors: Parsa Dadashi, Ensieh Soltani, Mehdi Elhamnia, Ghodratollah Hashemi Motlagh

Published in: Journal of Polymer Research | Issue 2/2025

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The article delves into the intricate viscoelastic behavior of polymer blends, particularly PBAT/EVOH blends, using rheology as a powerful tool. It highlights the challenge of immiscibility in polymer blends and the crucial role of interfacial compatibilization and chain extension in enhancing material properties. The study focuses on the use of MDI as a compatibilizer and chain extender, employing advanced rheological models and experimental techniques to decouple these effects. The findings reveal that MDI significantly enhances the elasticity of PBAT/EVOH blends through both interfacial compatibilization and chain extension, providing valuable insights into the optimization of polymer blend properties.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Business + Economics & Engineering + Technology"

Online-Abonnement

Springer Professional "Business + Economics & Engineering + Technology" gives you access to:

  • more than 102.000 books
  • more than 537 journals

from the following subject areas:

  • Automotive
  • Construction + Real Estate
  • Business IT + Informatics
  • Electrical Engineering + Electronics
  • Energy + Sustainability
  • Finance + Banking
  • Management + Leadership
  • Marketing + Sales
  • Mechanical Engineering + Materials
  • Insurance + Risk


Secure your knowledge advantage now!

Springer Professional "Engineering + Technology"

Online-Abonnement

Springer Professional "Engineering + Technology" gives you access to:

  • more than 67.000 books
  • more than 390 journals

from the following specialised fileds:

  • Automotive
  • Business IT + Informatics
  • Construction + Real Estate
  • Electrical Engineering + Electronics
  • Energy + Sustainability
  • Mechanical Engineering + Materials





 

Secure your knowledge advantage now!

Appendix
Available only for authorised users
Literature
1.
go back to reference Pal R (1996) Effect of droplet size on the rheology of emulsions. AICHE J 42:3181–3190CrossRef Pal R (1996) Effect of droplet size on the rheology of emulsions. AICHE J 42:3181–3190CrossRef
4.
go back to reference Sagis LMC, Fischer P (2014) Nonlinear rheology of complex fluid–fluid interfaces. Curr Opin Colloid Interface Sci 19:520–529CrossRef Sagis LMC, Fischer P (2014) Nonlinear rheology of complex fluid–fluid interfaces. Curr Opin Colloid Interface Sci 19:520–529CrossRef
5.
go back to reference Paul DR (2012) Polymer Blends, vol 1. Elsevier Paul DR (2012) Polymer Blends, vol 1. Elsevier
7.
go back to reference Koning C, Van Duin M, Pagnoulle C, Jerome R (1998) Strategies for compatibilization of polymer blends. Prog Polym Sci 23:707–757CrossRef Koning C, Van Duin M, Pagnoulle C, Jerome R (1998) Strategies for compatibilization of polymer blends. Prog Polym Sci 23:707–757CrossRef
8.
go back to reference Ajji A, Utracki LA (1996) Interphase and compatibilization of polymer blends. Polym Eng Sci 36:1574–1585CrossRef Ajji A, Utracki LA (1996) Interphase and compatibilization of polymer blends. Polym Eng Sci 36:1574–1585CrossRef
9.
go back to reference Zhao T, Yu J, Pan H et al (2023) Super-tough polylactic acid (PLA)/poly (butylene succinate)(PBS) materials prepared through reactive blending with epoxy-functionalized PMMA-GMA copolymer. Int J Biol Macromol 251:126150CrossRefPubMed Zhao T, Yu J, Pan H et al (2023) Super-tough polylactic acid (PLA)/poly (butylene succinate)(PBS) materials prepared through reactive blending with epoxy-functionalized PMMA-GMA copolymer. Int J Biol Macromol 251:126150CrossRefPubMed
10.
go back to reference Han Y, Shi J, Mao L et al (2020) Improvement of compatibility and mechanical performances of PLA/PBAT composites with epoxidized soybean oil as compatibilizer. Ind Eng Chem Res 59:21779–21790CrossRef Han Y, Shi J, Mao L et al (2020) Improvement of compatibility and mechanical performances of PLA/PBAT composites with epoxidized soybean oil as compatibilizer. Ind Eng Chem Res 59:21779–21790CrossRef
11.
go back to reference de CD Nunes E, de Souza AG, dos S Rosa D (2019) Effect of the Joncryl® ADR Compatibilizing Agent in Blends of Poly (butylene adipate‐co‐terephthalate)/Poly (lactic acid). In: Macromolecular Symposia. Wiley Online Library, p 1800035 de CD Nunes E, de Souza AG, dos S Rosa D (2019) Effect of the Joncryl® ADR Compatibilizing Agent in Blends of Poly (butylene adipate‐co‐terephthalate)/Poly (lactic acid). In: Macromolecular Symposia. Wiley Online Library, p 1800035
13.
go back to reference Hejna A, Przybysz-Romatowska M, Kosmela P et al (2020) Recent advances in compatibilization strategies of wood-polymer composites by isocyanates. Wood Sci Technol 54:1091–1119CrossRef Hejna A, Przybysz-Romatowska M, Kosmela P et al (2020) Recent advances in compatibilization strategies of wood-polymer composites by isocyanates. Wood Sci Technol 54:1091–1119CrossRef
14.
go back to reference Zhao X, Zhang D, Yu S et al (2021) Recent advances in compatibility and toughness of poly (lactic acid)/poly (butylene succinate) blends. e-Polymers 21:793–810CrossRef Zhao X, Zhang D, Yu S et al (2021) Recent advances in compatibility and toughness of poly (lactic acid)/poly (butylene succinate) blends. e-Polymers 21:793–810CrossRef
15.
go back to reference Pan H, Li Z, Yang J et al (2018) The effect of MDI on the structure and mechanical properties of poly (lactic acid) and poly (butylene adipate-co-butylene terephthalate) blends. RSC Adv 8:4610–4623CrossRefPubMedPubMedCentral Pan H, Li Z, Yang J et al (2018) The effect of MDI on the structure and mechanical properties of poly (lactic acid) and poly (butylene adipate-co-butylene terephthalate) blends. RSC Adv 8:4610–4623CrossRefPubMedPubMedCentral
16.
go back to reference Xie X, Zhang C, Weng Y et al (2020) Effect of diisocyanates as compatibilizer on the properties of BF/PBAT composites by in situ reactive compatibilization, crosslinking and chain extension. Materials (Basel) 13:806CrossRefPubMed Xie X, Zhang C, Weng Y et al (2020) Effect of diisocyanates as compatibilizer on the properties of BF/PBAT composites by in situ reactive compatibilization, crosslinking and chain extension. Materials (Basel) 13:806CrossRefPubMed
19.
go back to reference Shi D, Hu G-H, Ke Z et al (2006) Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends. Polymer (Guildf) 47:4659–4666CrossRef Shi D, Hu G-H, Ke Z et al (2006) Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends. Polymer (Guildf) 47:4659–4666CrossRef
20.
go back to reference Kwon MK, Cho KS (2016) Analysis of the Palierne model by relaxation time spectrum. Korea-Australia Rheol J 28:23–31CrossRef Kwon MK, Cho KS (2016) Analysis of the Palierne model by relaxation time spectrum. Korea-Australia Rheol J 28:23–31CrossRef
21.
go back to reference Jacobs U, Fahrländer M, Winterhalter J, Friedrich C (1999) Analysis of Palierne’s emulsion model in the case of viscoelastic interfacial properties. J Rheol (N Y N Y) 43:1495–1509CrossRef Jacobs U, Fahrländer M, Winterhalter J, Friedrich C (1999) Analysis of Palierne’s emulsion model in the case of viscoelastic interfacial properties. J Rheol (N Y N Y) 43:1495–1509CrossRef
22.
go back to reference Staffa LH, Huysecom A-S, Bettini SHP et al (2022) Effect of molecular structure of PEG/PCL multiblock copolymers on the morphology and interfacial properties of PLA/PCL blends. J Polym Res 29:388CrossRef Staffa LH, Huysecom A-S, Bettini SHP et al (2022) Effect of molecular structure of PEG/PCL multiblock copolymers on the morphology and interfacial properties of PLA/PCL blends. J Polym Res 29:388CrossRef
25.
go back to reference Elhamnia M, Hashemi Motlagh G (2020) Predicting Droplet Size by Rheometry Analysis for PBAT/EVOH Blend. Eco-friendly and Smart Polymer Systems. Springer International Publishing, Cham, pp 694–697CrossRef Elhamnia M, Hashemi Motlagh G (2020) Predicting Droplet Size by Rheometry Analysis for PBAT/EVOH Blend. Eco-friendly and Smart Polymer Systems. Springer International Publishing, Cham, pp 694–697CrossRef
26.
go back to reference Elhamnia M, Motlagh GH, Jafari SH (2023) Improved barrier properties of biodegradable PBAT films for packaging applications using EVOH: Morphology, permeability, biodegradation, and mechanical properties. J Appl Polym Sci e53855. https://doi.org/10.1002/app.53855 Elhamnia M, Motlagh GH, Jafari SH (2023) Improved barrier properties of biodegradable PBAT films for packaging applications using EVOH: Morphology, permeability, biodegradation, and mechanical properties. J Appl Polym Sci e53855. https://​doi.​org/​10.​1002/​app.​53855
28.
go back to reference Zhang ZL, Zhang HD, Yang YL et al (2001) Rheology and morphology of phase-separating polymer blends. Macromolecules 34:1416–1429CrossRef Zhang ZL, Zhang HD, Yang YL et al (2001) Rheology and morphology of phase-separating polymer blends. Macromolecules 34:1416–1429CrossRef
29.
go back to reference Gao J, Wang K, Xu N et al (2023) Influence of a multiple epoxy chain extender on the rheological behavior, crystallization, and mechanical properties of polyglycolic acid. Polymers (Basel) 15:2764CrossRefPubMedPubMedCentral Gao J, Wang K, Xu N et al (2023) Influence of a multiple epoxy chain extender on the rheological behavior, crystallization, and mechanical properties of polyglycolic acid. Polymers (Basel) 15:2764CrossRefPubMedPubMedCentral
31.
go back to reference Trinkle S, Friedrich C (2001) Van Gurp-Palmen-plot: a way to characterize polydispersity of linear polymers. Rheol Acta 40:322–328CrossRef Trinkle S, Friedrich C (2001) Van Gurp-Palmen-plot: a way to characterize polydispersity of linear polymers. Rheol Acta 40:322–328CrossRef
32.
go back to reference Katsourinis S, Kontou E (2019) Fractional viscoelastic models for interconverting linear viscoelastic functions of various polymeric structures. Rheol Acta 58:307–320CrossRef Katsourinis S, Kontou E (2019) Fractional viscoelastic models for interconverting linear viscoelastic functions of various polymeric structures. Rheol Acta 58:307–320CrossRef
33.
go back to reference Han B, Yin D, Gao Y (2023) Analysis of the variable-order fractional viscoelastic modeling with application to polymer materials. Polym Adv Technol 34:2707–2720CrossRef Han B, Yin D, Gao Y (2023) Analysis of the variable-order fractional viscoelastic modeling with application to polymer materials. Polym Adv Technol 34:2707–2720CrossRef
35.
go back to reference Fan J, Wu W, Zeng X, et al (2023) Experimental validation of a simple fractional model for viscoelastic behavior of high filled polymer-based composites. In: 2023 24th International Conference on Electronic Packaging Technology (ICEPT). IEEE, pp 1–6 Fan J, Wu W, Zeng X, et al (2023) Experimental validation of a simple fractional model for viscoelastic behavior of high filled polymer-based composites. In: 2023 24th International Conference on Electronic Packaging Technology (ICEPT). IEEE, pp 1–6
36.
go back to reference Lacroix C, Aressy M, Carreau PJ (1997) Linear viscoelastic behavior of molten polymer blends: a comparative study of the Palierne and Lee and Park models. Rheol Acta 36:416–428CrossRef Lacroix C, Aressy M, Carreau PJ (1997) Linear viscoelastic behavior of molten polymer blends: a comparative study of the Palierne and Lee and Park models. Rheol Acta 36:416–428CrossRef
37.
go back to reference Osaki K, Kurata M (1980) Experimental appraisal of the Doi-Edwards theory for polymer rheology based on the data for polystyrene solutions. Macromolecules 13:671–676CrossRef Osaki K, Kurata M (1980) Experimental appraisal of the Doi-Edwards theory for polymer rheology based on the data for polystyrene solutions. Macromolecules 13:671–676CrossRef
38.
go back to reference Coran AY, Patel R (1976) Predicting elastic moduli of heterogeneous polymer compositions. J Appl Polym Sci 20:3005–3016CrossRef Coran AY, Patel R (1976) Predicting elastic moduli of heterogeneous polymer compositions. J Appl Polym Sci 20:3005–3016CrossRef
Metadata
Title
Decoupling interfacial compatibilization and chain extension in polymer blends using rheology: PBAT/EVOH with MDI
Authors
Parsa Dadashi
Ensieh Soltani
Mehdi Elhamnia
Ghodratollah Hashemi Motlagh
Publication date
01-02-2025
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 2/2025
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-025-04260-z

Premium Partners