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Published in: Metallurgical and Materials Transactions A 6/2023

23-03-2023 | Original Research Article

Deposition Current Density Induced Alterations in Texture and Grain Boundary Constitution of Electrodeposited Zinc Coatings for Enhanced Corrosion Resistance Performance

Authors: K. Sai Jyotheender, Chandan Srivastava

Published in: Metallurgical and Materials Transactions A | Issue 6/2023

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Abstract

Zinc coatings were electrodeposited at different current densities, i.e., 30, 40, 50, 60, and 70 mA/cm2. All the coatings exhibited compact and crack-free morphology. The coating electrodeposited at 50 and 30 mA/cm2 current density showed the highest and lowest corrosion resistance, respectively. Corrosion current density (icorr) and polarization resistance (Rp) values for the 50 mA/cm2 deposited coating were 0.995 µA/cm2 and 5268.62 Ω cm2, respectively. icorr and Rp values for 30 mA/cm2 electrodeposited coating were 64.63 µA/cm2 and 627.51 Ω cm2, respectively. Electron backscatter diffraction analysis showed a direct correlation between the coating micro-texture and its corrosion behavior. The high corrosion resistance of coating electrodeposited at 50 mA/cm2 current density was due to the presence of dominant basal plane surface texture and a higher fraction of low-energy grain boundaries. The high corrosion rate of coating deposited at 30 mA/cm2 current density was due to the presence of high energy texture and large angle boundaries, which promoted corrosive media penetration through grains and grain boundaries, resulting in a higher dissolution rate.

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Metadata
Title
Deposition Current Density Induced Alterations in Texture and Grain Boundary Constitution of Electrodeposited Zinc Coatings for Enhanced Corrosion Resistance Performance
Authors
K. Sai Jyotheender
Chandan Srivastava
Publication date
23-03-2023
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 6/2023
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-023-07025-9

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