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01-02-2013 | Original Paper | Issue 2/2013

Journal of Polymer Research 2/2013

Development and characterisation of HDPE/EPDM-g-TMEVS blends for mechanical and morphological properties for engineering applications

Journal:
Journal of Polymer Research > Issue 2/2013
Authors:
V. C. Divya, V. V. Pattanshetti, R. Suresh, R. R. N. Sailaja

Abstract

A novel graft copolymer of tris (2-methoxy ethoxy) vinylsilane (TMEVS) onto ethylene propylene diene terpolymer (EPDM) has been developed by grafting TMEVS using dicumyl peroxide as an initiator (EPDM-g-TMVES)in a Brabender plasticorder. Grafting of TMEVS onto EPDM has been ascertained using FTIR. Suitable interfacial compatibilizer was synthesized by grafting of HDPE with glycidyl methacrylate (HDPE-g-GMA) with benzoyl peroxide as initiator. The EPDM-grafted-TMEVS developed has been blended with different weight percentage of HDPE, EPDM-g-TMEVS and nanoclay. The nanoclay was varied from 0 % to 10 % and with incorporation of compatibilizer and without compatibilizer in a brabender plasticorder. Different blend systems were prepared with compatibilizer and without compatibilizer with varying nanoclay and their thermal,mechnical and morphological properties were studied.

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