Skip to main content
Top

2018 | OriginalPaper | Chapter

Development of Heat-Treatable High-Strength Mg–Zn–Ca–Zr Sheet Alloy with Excellent Room Temperature Formability

Authors : M. Z. Bian, T. T. Sasaki, B. C. Suh, T. Nakata, S. Kamado, K. Hono

Published in: Magnesium Technology 2018

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Lightweight magnesium (Mg) alloys have attracted considerable attention for potential applications in the automotive industries. However, the low strength or poor formability at room temperature (RT) hinders the wider applications of wrought Mg alloy sheets. The newly developed a heat-treatable magnesium sheet alloy, Mg–0.6Zn–0.3Ca–0.1Zr (at. %), shows a large Index Erichsen value of 8.0 mm at RT in a solution treated condition. The excellent RT formability can be ascribed to a weak basal texture. Subsequent artificial aging at 170 °C for 4 h (T6) increases the 0.2% proof strength from 165 to 213 MPa. This improvement in strength by the T6 treatment is associated with a dense distribution of Guinier–Preston zones lying on the basal planes of the Mg matrix. Our finding overcomes the trade-off relationship of the room temperature formability and proof strength in Mg alloy sheets and this can be used as “bake hardenable” magnesium sheet alloy with excellent RT formability.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference W.J. Joost, P.E. Krajewski, Towards magnesium alloys for high-volume automotive applications, Scr. Mater. 128 (2017) 107–112. W.J. Joost, P.E. Krajewski, Towards magnesium alloys for high-volume automotive applications, Scr. Mater. 128 (2017) 107–112.
2.
go back to reference K. Hono, C.L. Mendis, T.T. Sasaki, K. Oh-ishi, Towards the development of heat-treatable high-strength wrought Mg alloys, Scr. Mater. 63 (2010) 710–715. K. Hono, C.L. Mendis, T.T. Sasaki, K. Oh-ishi, Towards the development of heat-treatable high-strength wrought Mg alloys, Scr. Mater. 63 (2010) 710–715.
3.
go back to reference A.A. Luo, Magnesium casting technology for structural applications, J. Magnes. Alloy. 1 (2013) 2–22. A.A. Luo, Magnesium casting technology for structural applications, J. Magnes. Alloy. 1 (2013) 2–22.
4.
go back to reference B.C. Suh, M.S. Shim, K.S. Shin, N.J. Kim, Current issues in magnesium sheet alloys: Where do we go from here?, Scr. Mater. 84–85 (2014) 1–6. B.C. Suh, M.S. Shim, K.S. Shin, N.J. Kim, Current issues in magnesium sheet alloys: Where do we go from here?, Scr. Mater. 84–85 (2014) 1–6.
5.
go back to reference M.Z. Bian, T.T. Sasaki, B.C. Suh, T. Nakata, S. Kamado, K. Hono, A heat-treatable Mg–Al–Ca–Mn–Zn sheet alloy with good room temperature formability, Scr. Mater. 138 (2017) 151–155. M.Z. Bian, T.T. Sasaki, B.C. Suh, T. Nakata, S. Kamado, K. Hono, A heat-treatable Mg–Al–Ca–Mn–Zn sheet alloy with good room temperature formability, Scr. Mater. 138 (2017) 151–155.
6.
go back to reference J.F. Nie, B.C. Muddle, Precipitation hardening of Mg-Ca(-Zn) alloys, Scr. Mater. 37 (1997) 1475–1481. J.F. Nie, B.C. Muddle, Precipitation hardening of Mg-Ca(-Zn) alloys, Scr. Mater. 37 (1997) 1475–1481.
7.
go back to reference J.C. Oh, T. Ohkubo, T. Mukai, K. Hono, TEM and 3DAP characterization of an age-hardened Mg–Ca–Zn alloy, Scr. Mater. 53 (2005) 675–679. J.C. Oh, T. Ohkubo, T. Mukai, K. Hono, TEM and 3DAP characterization of an age-hardened Mg–Ca–Zn alloy, Scr. Mater. 53 (2005) 675–679.
8.
go back to reference Y. Chino, X. Huang, K. Suzuki, M. Mabuchi, Enhancement of stretch formability at room temperature by addition of Ca in Mg–Zn alloy, Mater. Trans. 51 (2010) 818–821. Y. Chino, X. Huang, K. Suzuki, M. Mabuchi, Enhancement of stretch formability at room temperature by addition of Ca in Mg–Zn alloy, Mater. Trans. 51 (2010) 818–821.
9.
go back to reference Y. Chino, K. Sassa, X.S. Huang, K. Suzuki, M. Mabuchi, Effects of zinc concentration on the stretch formability at room temperature of the rolled Mg–Zn–Ca alloys, J. Japan Inst. Met. Mater. 75 (2011) 35–41. Y. Chino, K. Sassa, X.S. Huang, K. Suzuki, M. Mabuchi, Effects of zinc concentration on the stretch formability at room temperature of the rolled Mg–Zn–Ca alloys, J. Japan Inst. Met. Mater. 75 (2011) 35–41.
10.
go back to reference M.Z. Bian, Z.R. Zeng, S.W. Xu, S.M. Zhu, Y.M. Zhu, C.H.J. Davies, N. Birbilis, J.F. Nie, Improving formability of Mg–Ca–Zr sheet alloy by microalloying of Zn, Adv. Eng. Mater. 18 (2016) 1763–1769. M.Z. Bian, Z.R. Zeng, S.W. Xu, S.M. Zhu, Y.M. Zhu, C.H.J. Davies, N. Birbilis, J.F. Nie, Improving formability of Mg–Ca–Zr sheet alloy by microalloying of Zn, Adv. Eng. Mater. 18 (2016) 1763–1769.
11.
go back to reference M. Qian, D.H. StJohn, M.T. Frost, Characteristic zirconium-rich coring structures in Mg–Zr alloys, Scr. Mater. 46 (2002) 649–654. M. Qian, D.H. StJohn, M.T. Frost, Characteristic zirconium-rich coring structures in Mg–Zr alloys, Scr. Mater. 46 (2002) 649–654.
12.
go back to reference T. Bhattacharjee, T. Nakata, T.T. Sasaki, S. Kamado, K. Hono, Effect of microalloyed Zr on the extruded microstructure of Mg–6.2Zn-based alloys, Scr. Mater. 90 (2014) 37–40. T. Bhattacharjee, T. Nakata, T.T. Sasaki, S. Kamado, K. Hono, Effect of microalloyed Zr on the extruded microstructure of Mg–6.2Zn-based alloys, Scr. Mater. 90 (2014) 37–40.
13.
go back to reference J.W. Christian, S. Mahajan, Deformation twinning, Prog. Mater. Sci. 39 (1995) 1–157. J.W. Christian, S. Mahajan, Deformation twinning, Prog. Mater. Sci. 39 (1995) 1–157.
14.
go back to reference Y.N. Wang, J.C. Huang, The role of twinning and untwinning in yielding behavior in hot-extruded Mg–Al–Zn alloy, Acta Mater. 55 (2007) 897–905. Y.N. Wang, J.C. Huang, The role of twinning and untwinning in yielding behavior in hot-extruded Mg–Al–Zn alloy, Acta Mater. 55 (2007) 897–905.
15.
go back to reference G. Gottstein, T. Alsamman, Texture development in pure Mg and Mg alloy AZ31, Mater. Sci. Forum. 195–197 (2005) 623–632. G. Gottstein, T. Alsamman, Texture development in pure Mg and Mg alloy AZ31, Mater. Sci. Forum. 195–197 (2005) 623–632.
16.
go back to reference M.A. Steiner, J.J. Bhattacharyya, S.R. Agnew, The origin and enhancement of {0001}〈11–20〉 texture during heat treatment of rolled AZ31B magnesium alloys, Acta Mater. 95 (2015) 443–455. M.A. Steiner, J.J. Bhattacharyya, S.R. Agnew, The origin and enhancement of {0001}〈11–20〉 texture during heat treatment of rolled AZ31B magnesium alloys, Acta Mater. 95 (2015) 443–455.
17.
go back to reference K. Oh-ishi, R. Watanabe, C.L. Mendis, K. Hono, Age-hardening response of Mg-0.3 at.%Ca alloys with different Zn contents, Mater. Sci. Eng. A. 526 (2009) 177–184. K. Oh-ishi, R. Watanabe, C.L. Mendis, K. Hono, Age-hardening response of Mg-0.3 at.%Ca alloys with different Zn contents, Mater. Sci. Eng. A. 526 (2009) 177–184.
Metadata
Title
Development of Heat-Treatable High-Strength Mg–Zn–Ca–Zr Sheet Alloy with Excellent Room Temperature Formability
Authors
M. Z. Bian
T. T. Sasaki
B. C. Suh
T. Nakata
S. Kamado
K. Hono
Copyright Year
2018
DOI
https://doi.org/10.1007/978-3-319-72332-7_55

Premium Partners