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Published in: Journal of Material Cycles and Waste Management 4/2018

13-12-2017 | SPECIAL FEATURE: ORIGINAL ARTICLE

Development of Mn recovery process from waste dry cell batteries

Authors: T. Yamaguchi, H. Nagano, R. Murai, H. Sugimori, C. Sekiguchi, I. Sumi

Published in: Journal of Material Cycles and Waste Management | Issue 4/2018

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Abstract

High-purity Mn is necessary for high strength steel production. However, the availability of metal Mn is limited to a few countries. Therefore, as an alternative to direct purchasing of metal Mn, a process for Mn recovery was investigated. Waste dry cell batteries are considered to be one of the most feasible Mn sources. We have developed a high efficiency chemical separation system. This system consists of a three-phase chemical treatment. In the first phase, the metal components of the waste dry cell batteries were dissolved by acid, along with a reducing agent. Afterward, the undissolved carbon particles were separated by filtration. In the second phase, the dissolved Mn was selectively precipitated as manganese oxide by O3 oxidation. Then, the precipitated manganese oxide was separated from the other metal components by filtration. Finally, in the third phase, the manganese oxide was reduced to high-purity Mn using an electric furnace.

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Metadata
Title
Development of Mn recovery process from waste dry cell batteries
Authors
T. Yamaguchi
H. Nagano
R. Murai
H. Sugimori
C. Sekiguchi
I. Sumi
Publication date
13-12-2017
Publisher
Springer Japan
Published in
Journal of Material Cycles and Waste Management / Issue 4/2018
Print ISSN: 1438-4957
Electronic ISSN: 1611-8227
DOI
https://doi.org/10.1007/s10163-017-0679-0

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