Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Published in:
Introduction Read chapter Read first chapter

2019 | OriginalPaper | Chapter

2. Differential Phonon Spectrometrics (DPS)

Author : Prof. Dr. Chang Q Sun

Published in: Solvation Dynamics

Publisher: Springer Singapore

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

An incorporation of the hydrogen bond cooperativity theory to the DPS strategy and surface stress (contact angle) detection could resolve the solvation bonding and nonbonding dynamics and solute capabilities. The enabled information includes bond length and stiffness transition, electron polarization, and the fraction of bonds transformed from the mode of ordinary water to the hydration shells. A combination of the DPS and the ultrafast IR spectroscopy would be more revealing towards solute-solvent and solute-solute molecular interactions, solute capabilities, and solution properties. The DPS is focused on the solvation O:H–O segmental cooperative bonding dynamics and the ultrafast IR on molecular motion dynamics by measuring phonon relaxation time.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
previous chapter Introduction
next chapter Theory: Aqueous Charge Injection by Solvation
Literature
1.
C.M. Johnson, S. Baldelli, Vibrational sum frequency spectroscopy studies of the influence of solutes and phospholipids at vapor/water interfaces relevant to biological and environmental systems. Chem. Rev. 114(17), 8416–8446 (2014)CrossRef
2.
M. Thämer, L. De Marco, K. Ramasesha, A. Mandal, A. Tokmakoff, Ultrafast 2D IR spectroscopy of the excess proton in liquid water. Science 350(6256), 78–82 (2015)CrossRef
3.
Z.S. Nickolov, J. Miller, Water structure in aqueous solutions of alkali halide salts: FTIR spectroscopy of the OD stretching band. J. Colloid Interface Sci. 287(2), 572–580 (2005)CrossRef
4.
S. Park, M.B. Ji, K.J. Gaffney, Ligand exchange dynamics in aqueous solution studied with 2DIR spectroscopy. J. Phys. Chem. B 114(19), 6693–6702 (2010)CrossRef
5.
T. Brinzer, E.J. Berquist, Z. Ren, 任哲, S. Dutta, C.A. Johnson, C.S. Krisher, D.S. Lambrecht, S. Garrett-Roe, Ultrafast vibrational spectroscopy (2D-IR) of CO2 in ionic liquids: carbon capture from carbon dioxide’s point of view. The J. Chem. Phys. 142(21), 212425 (2015)
6.
Y.R. Shen, Basic theory of surface sum-frequency generation. The J. Phys. Chem. C 116, 15505–15509 (2012)CrossRef
7.
Y.R. Shen, V. Ostroverkhov, Sum-frequency vibrational spectroscopy on water interfaces: polar orientation of water molecules at interfaces. Chem. Rev. 106(4), 1140–1154 (2006)CrossRef
8.
J. Verlet, A. Bragg, A. Kammrath, O. Cheshnovsky, D. Neumark, Observation of large water-cluster anions with surface-bound excess electrons. Science 307(5706), 93–96 (2005)CrossRef
9.
I. Michalarias, I. Beta, R. Ford, S. Ruffle, J.C. Li, Inelastic neutron scattering studies of water in DNA. Appl. Phys. A Mater. Sci. Process. 74, s1242–s1244 (2002)CrossRef
10.
J.C. Li, A.I. Kolesnikov, Neutron spectroscopic investigation of dynamics of water ice. J. Mol. Liq. 100(1), 1–39 (2002)CrossRef
11.
S.T. van der Post, C.S. Hsieh, M. Okuno, Y. Nagata, H.J. Bakker, M. Bonn, J. Hunger, Strong frequency dependence of vibrational relaxation in bulk and surface water reveals sub-picosecond structural heterogeneity. Nat. Commun. 6, 8384 (2015)CrossRef
12.
J. Wang, Ultrafast two-dimensional infrared spectroscopy for molecular structures and dynamics with expanding wavelength range and increasing sensitivities: from experimental and computational perspectives. Int. Rev. Phys. Chem. 36(3), 377–431 (2017)CrossRef
13.
R.A. Street, Hydrogenated Amorphous Silicon (Cambridge University Press, 1991)
14.
X. Zhang, Y. Xu, Y. Zhou, Y. Gong, Y. Huang, C.Q. Sun, HCl, KCl and KOH solvation resolved solute-solvent interactions and solution surface stress. Appl. Surf. Sci. 422, 475–481 (2017)CrossRef
15.
C.Q. Sun, Atomic scale purification of electron spectroscopic information (U.S. 2017 Patent No. 9,625,397B2) (United States, 2017)
16.
X.J. Liu, M.L. Bo, X. Zhang, L. Li, Y.G. Nie, H. TIan, Y. Sun, S. Xu, Y. Wang, W. Zheng, C.Q. Sun, Coordination-resolved electron spectrometrics. Chem. Rev. 115(14), 6746–6810 (2015)CrossRef
17.
Q. Zeng, C. Yao, K. Wang, C.Q. Sun, B. Zou, Room-temperature NaI/H2O compression icing: solute–solute interactions. PCCP 19, 26645–26650 (2017)CrossRef
18.
Q. Zeng, T. Yan, K. Wang, Y. Gong, Y. Zhou, Y. Huang, C.Q. Sun, B. Zou, Compression icing of room-temperature NaX solutions (X = F, Cl, Br, I). Phys. Chem. Chem. Phys. 18(20), 14046–14054 (2016)CrossRef
19.
X. Zhang, Y. Zhou, Y. Gong, Y. Huang, C. Sun, Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress. Chem. Phys. Lett. 678, 233–240 (2017)CrossRef
20.
M. Nagasaka, H. Yuzawa, N. Kosugi, Development and application of in situ/operando soft X-ray transmission cells to aqueous solutions and catalytic and electrochemical reactions. J. Electron Spectrosc. Relat. Phenom. 200, 293–310 (2015)CrossRef
21.
Y.L. Huang, X. Zhang, Z.S. Ma, Y.C. Zhou, W.T. Zheng, J. Zhou, C.Q. Sun, Hydrogen-bond relaxation dynamics: resolving mysteries of water ice. Coord. Chem. Rev. 285, 109–165 (2015)CrossRef
22.
J.C. Araque, S.K. Yadav, M. Shadeck, M. Maroncelli, C.J. Margulis, How is diffusion of neutral and charged tracers related to the structure and dynamics of a room-temperature ionic liquid? Large deviations from Stokes-Einstein behavior explained. J. Phys. Chem. B 119(23), 7015–7029 (2015)CrossRef
23.
C.Q. Sun, J. Chen, X. Liu, X. Zhang, Y. Huang, (Li, Na, K)OH hydration bondin thermodynamics: solution self-heating. Chem. Phys. Lett. 696, 139–143 (2018)CrossRef
24.
Y. Wang, W. Zhu, K. Lin, L. Yuan, X. Zhou, S. Liu, Ratiometric detection of Raman hydration shell spectra. J. Raman Spectrosc. 47(10), 1231–1238 (2016)CrossRef
25.
V. Vchirawongkwin, B.M. Rode, I. Persson, Structure and dynamics of sulfate ion in aqueous solution an ab initio QMCF MD simulation and large angle X-ray scattering study. J. Phys. Chem. B 111(16), 4150–4155 (2007)CrossRef
26.
N. Galamba, Mapping structural perturbations of water in ionic solutions. J. Phys. Chem. B 116(17), 5242–5250 (2012)CrossRef
27.
A. Bragg, J. Verlet, A. Kammrath, O. Cheshnovsky, D. Neumark, Hydrated electron dynamics: from clusters to bulk. Science 306(5696), 669–671 (2004)CrossRef
28.
M. Nagasaka, H. Yuzawa, N. Kosugi, Interaction between water and alkali metal ions and its temperature dependence revealed by oxygen K-edge X-ray absorption spectroscopy. J. Phys. Chem. B 121(48), 10957–10964 (2017)CrossRef
29.
Y. Otsuki, T. Sugimoto, T. Ishiyama, A. Morita, K. Watanabe, Y. Matsumoto, Unveiling subsurface hydrogen-bond structure of hexagonal water ice. Phys. Rev. B 96(11), 115405 (2017)CrossRef
30.
C.Q. Sun, Y. Sun, The attribute of water: single notion, multiple myths. Springer Ser. Chem. Phys. 113 (2016)
31.
Y. Shi, Z. Zhang, W. Jiang, Z. Wang, Theoretical study on electronic and vibrational properties of hydrogen bonds in glycine-water clusters. Chem. Phys. Lett. 684, 53–59 (2017)CrossRef
32.
Y. Huang, X. Zhang, Z. Ma, Y. Zhou, G. Zhou, C.Q. Sun, Hydrogen-bond asymmetric local potentials in compressed ice. J. Phys. Chem. B 117(43), 13639–13645 (2013)CrossRef
33.
Y.L. Huang, X. Zhang, Z.S. Ma, G.H. Zhou, Y.Y. Gong, C.Q. Sun, Potential paths for the hydrogen-bond relaxing with (H2O)(N) cluster size. J. Phys. Chem. C 119(29), 16962–16971 (2015)CrossRef
34.
C.Q. Sun, Size dependence of nanostructures: Impact of bond order deficiency. Prog. Solid State Chem. 35(1), 1–159 (2007)CrossRef
35.
C.Q. Sun, J. Chen, Y. Gong, X. Zhang, Y. Huang, (H, Li)Br and LiOH solvation bonding dynamics: molecular nonbond interactions and solute extraordinary capabilities. J. Phys. Chem. B 122(3), 1228–1238 (2018)CrossRef
36.
C.Q. Sun, Thermo-mechanical behavior of low-dimensional systems: the local bond average approach. Prog. Mater Sci. 54(2), 179–307 (2009)CrossRef
37.
X.X. Yang, J.W. Li, Z.F. Zhou, Y. Wang, L.W. Yang, W.T. Zheng, C.Q. Sun, Raman spectroscopic determination of the length, strength, compressibility, Debye temperature, elasticity, and force constant of the C-C bond in graphene. Nanoscale 4(2), 502–510 (2012)CrossRef
38.
K. Amann-Winkel, R. Böhmer, F. Fujara, C. Gainaru, B. Geil, T. Loerting, Colloquiu: water’s controversial glass transitions. Rev. Mod. Phys. 88(1), 011002 (2016)CrossRef
39.
A. Wong, L. Shi, R. Auchettl, D. McNaughton, D.R. Appadoo, E.G. Robertson, Heavy snow: IR spectroscopy of isotope mixed crystalline water ice. Phys. Chem. Chem. Phys. 18(6), 4978–4993 (2016)CrossRef
40.
X. Zhang, P. Sun, Y. Huang, T. Yan, Z. Ma, X. Liu, B. Zou, J. Zhou, W. Zheng, C.Q. Sun, Water’s phase diagram: from the notion of thermodynamics to hydrogen-bond cooperativity. Prog. Solid State Chem. 43, 71–81 (2015)CrossRef
41.
C.Q. Sun, X. Zhang, X. Fu, W. Zheng, J.-L. Kuo, Y. Zhou, Z. Shen, J. Zhou, Density and phonon-stiffness anomalies of water and ice in the full temperature range. J. Phys. Chem. Lett. 4, 3238–3244 (2013)CrossRef
42.
C.Q. Sun, X. Zhang, J. Zhou, Y. Huang, Y. Zhou, W. Zheng, Density, elasticity, and stability anomalies of water molecules with fewer than four neighbors. J. Phys. Chem. Lett. 4, 2565–2570 (2013)CrossRef
43.
Y. Zhou, Y. Huang, Z. Ma, Y. Gong, X. Zhang, Y. Sun, C.Q. Sun, Water molecular structure-order in the NaX hydration shells (X= F, Cl, Br, I). J. Mol. Liq. 221, 788–797 (2016)CrossRef
44.
S. Hajati, S. Coultas, C. Blomfield, S. Tougaard, XPS imaging of depth profiles and amount of substance based on Tougaard’s algorithm. Surf. Sci. 600(15), 3015–3021 (2006)CrossRef
45.
M.P. Seah, I.S. Gilmore, S.J. Spencer, Background subtraction—II. General behaviour of REELS and the Tougaard universal cross section in the removal of backgrounds in AES and XPS. Surf. Sci. 461(1–3), 1–15 (2000)CrossRef
46.
X.B. Zhou, J.L. Erskine, Surface core-level shifts at vicinal tungsten surfaces. Phys. Rev. B 79(15), 155422 (2009)CrossRef
47.
Z. Zhang, D. Li, W. Jiang, Z. Wang, The electron density delocalization of hydrogen bond systems. Adv. Phys.: X 3(1), 1428915 (2018)
48.
X. Wu, W. Lu, W. Ou, M.C. Caumon, J. Dubessy, Temperature and salinity effects on the Raman scattering cross section of the water OH-stretching vibration band in NaCl aqueous solutions from 0 to 300 °C. J. Raman Spectrosc. 48(2), 314–322 (2016)CrossRef
49.
Y. Zhou, Y. Huang, L. Li, Y. Gong, X. Liu, X. Zhang, C.Q. Sun, Hydrogen-bond transition from the vibration mode of ordinary water to the (H, Na)I hydration states: molecular interactions and solution viscosity. Vib. Spectrosc. 94, 31–36 (2018)CrossRef
50.
J. Chen, C. Yao, X. Liu, X. Zhang, C.Q. Sun, Y. Huang, H2O2 and HO- solvation dynamics: solute capabilities and solute-solvent molecular interactions. Chem. Sel. 2(27), 8517–8523 (2017)
51.
D.R. Lide, CRC Handbook of Chemistry and Physics, 80th edn. (CRC Press, Boca Raton, 1999)
52.
Q. Wei, D. Zhou, H. Bian, Negligible cation effect on the vibrational relaxation dynamics of water molecules in NaClO4 and LiClO4 aqueous electrolyte solutions. RSC Advances 7(82), 52111–52117 (2017)CrossRef
53.
J.W. Gibbs, On the equilibrium of heterogeneous substances. Am. J. Sci. 96, 441–458 (1878)CrossRef
54.
R.C. Cammarata, Surface and interface stress effects in thin films. Prog. Surf. Sci. 46(1), 1–38 (1994)CrossRef
55.
T. Young, An essay on the cohesion of fluids. Philos. Trans. R. Soc. Lond. 65–87 (1805)
56.
M. Zhao, W.T. Zheng, J.C. Li, Z. Wen, M.X. Gu, C.Q. Sun, Atomistic origin, temperature dependence, and responsibilities of surface energetics: an extended broken-bond rule. Phys. Rev. B 75(8), 085427 (2007)CrossRef
57.
M.T. Suter, P.U. Andersson, J.B. Pettersson, Surface properties of water ice at 150–191 K studied by elastic helium scattering. J. Chem. Phys. 125(17), 174704 (2006)CrossRef
58.
C.Q. Sun, Y. Sun, Y.G. Ni, X. Zhang, J.S. Pan, X.H. Wang, J. Zhou, L.T. Li, W.T. Zheng, S.S. Yu, L.K. Pan, Z. Sun, Coulomb repulsion at the nanometer-sized contact: a force driving superhydrophobicity, superfluidity, superlubricity, and supersolidity. J. Phys. Chem. C 113(46), 20009–20019 (2009)CrossRef
59.
X. Zhang, Y. Huang, Z. Ma, L. Niu, C.Q. Sun, From ice supperlubricity to quantum friction: electronic repulsivity and phononic elasticity. Friction 3(4), 294–319 (2015)CrossRef
Metadata
Title
Differential Phonon Spectrometrics (DPS)
Author
Prof. Dr. Chang Q Sun
Copyright Year
2019
Publisher
Springer Singapore
Book
Solvation Dynamics

Print ISBN: 978-981-13-8440-0

Electronic ISBN: 978-981-13-8441-7

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-981-13-8441-7_2

Premium Partners

    Image Credits