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25-09-2018 | Original Paper

Dispersion of reduced graphene oxide with montmorillonite for enhancing dielectric properties and thermal stability of cyanoethyl cellulose nanocomposites

Authors: Feijun Wang, Minghua Wang, Ziqiang Shao

Published in: Cellulose | Issue 12/2018

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Abstract

Eco-friendly polymer composites have drawn much attention over the world because of growing environmental problems. In this study, a new type of nanocomposite film using environmentally friendly cyanoethyl cellulose (CEC) as matrix, reduced graphene oxide (rGO) as conductive filler and montmorillonite (MMT) as disperser of graphene was fabricated by solution blending. The results of SEM, XRD and stationary stand test reveal that MMT increases significantly the dispersibility of rGO. The CEC/rGO/MMT ternary nanocomposite film has a high dielectric constant of 125 and low loss of 0.7 at 1000 Hz when 6.8% rGO and 3.4% MMT were added. Furthermore, the addition of MMT and rGO can notably increase the thermal stability and tensile strength of CEC.

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Allen MJ, Tung VC, Kaner RB (2010) Honeycomb carbon: a review of graphene. Chem Rev 110:132–145CrossRef

Arbatti M, Shan X, Cheng ZY (2007) Ceramic-polymer composites with high dielectric constant. Adv Mater 19:1369–1372CrossRef

Arora A, Choudhary V, Sharma DK (2010) Effect of clay content and clay/surfactant on the mechanical, thermal and barrier properties of polystyrene/organoclay nanocomposites. J Polym Res 18:43–857

Capkova P, Matejka V, Tokarsky J, Peikertova P, Neuwirthova L, Kulhankova L, Beno J, Styskala V (2014) Electrically conductive aluminosilicate/graphene nanocomposite. J Eur Ceram Soc 34:3111–3117CrossRef

Chen P, Deng G, Hu D, Wang Y, Meng Z, Hua W, Xi K (2016) Enhanced mechanical properties and thermal stability of PSMA by functionalized graphene nanosheets. RSC Adv 6:68748–68753CrossRef

Cho S, Kim M, Lee JS, Jang J (2015) Polypropylene/polyaniline nanofiber/reduced graphene oxide nanocomposite with enhanced electrical, dielectric, and ferroelectric properties for a high energy density capacitor. ACS Appl Mater Interfaces 7:22301–22314CrossRef

Choudhary S, Bald A, Sengwa RJ, Checinska-Majak D, Klimaszewski K (2015) Effects of ultrasonic assisted processing and clay nanofiller on dielectric properties and lithium ion transport mechanism of poly (methyl methacrylate) based plasticized polymer electrolytes. J Appl Polym Sci 132:42188

Chu L, Xue Q, Sun J, Xia F, Xing W, Xia D, Dong M (2013) Porous graphene sandwich/poly(vinylidene fluoride) composites with high dielectric properties. Compos Sci Technol 86:70–75CrossRef

Fang X, Liu X, Cui ZK, Qian J, Pan J, Li X et al (2015) Preparation and properties of thermostable well-functionalized graphene oxide/polyimide composite films with high dielectric constant, low dielectric loss and high strength via in situ polymerization. J Mater Chem A 3:10005–10012CrossRef

Galantini F, Bianchi S, Castelvetro V, Gallone G (2013) Functionalized carbon nanotubes as a filler for dielectric elastomer composites with improved actuation performance. Smart Mater Struct 22:1307–1312

Gao K, Shao Z, Wu X, Wang X, Zhang Y, Wang W, Wang F (2013) Paper-based transparent flexible thin film supercapacitors. Nanoscale 5:5307–5311CrossRef

George JJ, Bhowmick AK (2008) Ethylene vinyl acetate/expanded graphite nanocomposites by solution intercalation: preparation, characterization and properties. J Mater Sci 43:702–708CrossRef

Girdthep S, Komrapit N, Molloy R, Lumyong S, Punyodom W, Worajittiphon P (2015) Effect of plate-like particles on properties of poly (lactic acid)/poly(butylene adipate-co-terephthalate) blend: a comparative study between modified montmorillonite and graphene nanoplatelets. Compos Sci Technol 119:115–123CrossRef

Glover AJ, Cai M, Overdeep KR, Kranbuehl DE, Schniepp HC (2011) In situ reduction of graphene oxide in polymers. Macromolecules 44:9821–9829CrossRef

Hardy CG, Islam MS, Gonzalez-Delozier D, Morgan JE, Cash B, Benicewicz BC et al (2013) Converting an electrical insulator into a dielectric capacitor: end-capping polystyrene with oligoaniline. Chem Mater 25:799–807CrossRef

He F, Lam KH, Fan J, Chan LH (2014) Improved dielectric properties for chemically functionalized exfoliated graphite nanoplates/syndiotactic polystyrene composites prepared by a solution-blending method. Carbon 80:496–503CrossRef

Jayalakshmy MS, Philip J (2015) Enhancement in pyroelectric detection sensitivity for flexible LiNbO₃/PVDF nanocomposite films by inclusion content control. J Polym Res 22:1–11CrossRef

Jia C, Shao Z, Fan H, Wang J (2015) Preparation and dielectric properties of cyanoethyl cellulose/BaTiO₃ flexible nanocomposite films. RSC Adv 5:15283–15291CrossRef

Jia C, Shao Z, Fan H, Feng R, Wang F, Wang W, Wang J, Zhang D, Lv Y (2016) Barium titanate as a filler for improving the dielectric property of cyanoethyl cellulose/antimony tin oxide nanocomposite films. Compos Part A 86:1–8CrossRef

Kim JY, Lee WH, Suk JW, Potts JR, Chou H, Kholmanov IN, Piner RD, Lee J, Akinwande D, Ruoff RS (2013) Chlorination of reduced graphene oxide enhances the dielectric constant of reduced graphene oxide/polymer composites. Adv Mater 25:2308–2313CrossRef

Li C, Li Y, She X, Vongsvivut J, Li J, She F, Gao W, Kong L (2015a) Reinforcement and deformation behaviors of polyvinyl alcohol/graphene/montmorillonite clay composites. Compos Sci Technol 118:1–8CrossRef

Li J, Wang F, Shi D, Zhang Y, Shao Z (2015b) Mutifunctional biopolymer nanoparticles for drug delivery and protein immobilization. Ferroelectrics 486:156–167CrossRef

Li Y, Fan M, Wu K, Yu F, Chai S, Chen F, Fu Q (2015c) Polydopamine coating layer on graphene for suppressing loss tangent and enhancing dielectric constant of poly(vinylidene fluoride)/graphene composites. Compos Part A 73:85–92CrossRef

Li L, Yu M, Jia C, Liu J, Lv Y, Liu Y et al (2017) Cellulosic biomass-reinforced polyvinylidene fluoride separators with enhanced dielectric properties and thermal tolerance. ACS Appl Mater Interfaces 9:20885–20894CrossRef

Liu S, Zhai J (2015) Improving the dielectric constant and energy density of poly(vinylidene fluoride) composites induced by surface-modified SrTiO₃ nanofibers by polyvinylpyrrolidone. J Mater Chem A 3:1511–1517CrossRef

Logakis E, Pandis C, Peoglos V, Pissis P, Pionteck J, Poetschke P et al (2009) Electrical/dielectric properties and conduction mechanism in melt processed polyamide/multi-walled carbon nanotubes composites. Polymer 50:5103–5111CrossRef

Losego MD, Blitz IP, Vaia RA, Cahill DG, Braun PV (2013) Ultralow thermal conductivity in organoclay nanolaminates synthesized via simple self-assembly. Nano Lett 13:2215–2219CrossRef

Mahla DK, Rahaman M, Khastgir D (2015) Composition-dependent electrical and dielectric properties of polyaniline/graphene composites produced byin situpolymerization technique. Polym Compos 36:445–453CrossRef

McAllister MJ, Li JL, Adamson DH, Schniepp HC, Abdala AA, Liu J et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–4404CrossRef

Mural PKS, Sharma M, Madras G, Bose S (2015) A critical review on in situ reduction of graphene oxide during preparation of conducting polymeric nanocomposites. RSC Adv 46:32078–32087CrossRef

Poh CL, Mariatti M, Noor AFM, Sidek O, Chuah TP, Chow SC (2016) Dielectric properties of surface treated multi-walled carbon nanotube/epoxy thin film composites. Compos Part B Eng 85:50–58CrossRef

Saad GR (1994) Dielectric behavior of cyanoethylated cellulose. Polym Int 34:411–415CrossRef

Shehzad K, Dang ZM, Ahmad MN, Sagar RUR, Butt S, Farooq MU, Wang TB (2013) Effects of carbon nanotubes aspect ratio on the qualitative and quantitative aspects of frequency response of electrical conductivity and dielectric permittivity in the carbon nanotube/polymer composites. Carbon 54:105–112CrossRef

Shi D, Wang F, Lan T, Zhang Y, Shao Z (2016) Convenient fabrication of carboxymethyl cellulose electrospun nanofibers functionalized with silver nanoparticles. Cellulose 23:1899–1909CrossRef

Takechi S, Teramoto Y, Nishio Y (2016) Improvement of dielectric properties of cyanoethyl cellulose via esterification and film stretching. Cellulose 23:765–777CrossRef

Tian MW, Qu LJ, Zhang XS, Zhang K, Zhu S (2014) Enhanced mechanical and thermal properties of regenerated cellulose/graphene composite fibers. Carbohydr Polym 111:456–462CrossRef

Tong W, Zhang Y, Yu L, Luan X, An Q, Zhang Q, Lv F, Chu PK, Shen B, Zhang Z (2014) Novel method for the fabrication of flexible film with oriented arrays of graphene in poly(vinylidene fluoride-co-hexafluoropropylene) with low dielectric loss. J Phys Chem C 118:10567–10573CrossRef

Wan YJ, Tang LC, Yan D, Zhao L, Li YB, Wu LB et al (2013) Improved dispersion and interface in the graphene/epoxy composites via a facile surfactant-assisted process. Compos Sci Technol 82:60–68CrossRef

Wan YJ, Yang WH, Yu SH, Sun R, Wong CP, Liao WH (2016) Covalent polymer functionalization of graphene for improved dielectric properties and thermal stability of epoxy composites. Compos Sci Technol 122:27–35CrossRef

Wang DR, Bao Y, Zha JW, Zhao J, Dang ZM, Hu GH (2012) Improved dielectric properties of nanocomposites based on poly(vinylidene fluoride) and poly(vinyl alcohol)-functionalized graphene. ACS Appl Mater Interfaces 4:6273–6279CrossRef

Wang B, Liang G, Jiao Y, Gu A, Liu L, Yuan L, Zhang W (2013) Two-layer materials of polyethylene and a carbon nanotube/cyanate ester composite with high dielectric constant and extremely low dielectric loss. Carbon 54:224–233CrossRef

Wang J, Wu J, Xu W, Zhang Q, Fu Q (2014a) Preparation of poly(vinylidene fluoride) films with excellent electric property, improved dielectric property and dominant polar crystalline forms by adding a quaternary phosphorus salt functionalized graphene. Compos Sci Technol 91:1–7CrossRef

Wang Q, Li G, Zhang J, Huang F, Lu K, Wei Q (2014b) PAN nanofibers reinforced with MMT/GO hybrid nanofillers. J Nanomater 2014:1–10

Wang B, Liu L, Huang L, Chi L, Liang G, Yuan L, Gu A (2015) Fabrication and origin of high-k carbon nanotube/epoxy composites with low dielectric loss through layer-by-layer casting technique. Carbon 85:28–37CrossRef

Wu Y, Lin X, Shen X, Sun X, Liu X, Wang Z, Kim JK (2015) Exceptional dielectric properties of chlorine-doped graphene oxide/poly (vinylidene fluoride) nanocomposites. Carbon 89:102–112CrossRef

Wu W, Huang X, Li S, Jiang P, Toshikatsu T (2016) Novel three-dimensional zinc oxide superstructures for high dielectric constant polymer composites capable of withstanding high electric field. J Phy Chem C 116:24887–24895CrossRef

Xie F, Qi SH, Wu D (2016) A facile strategy for the reduction of graphene oxide and its effect on thermal conductivity of epoxy based composites. Expr Polym Lett 10:470–478CrossRef

Xu XL, Yang CJ, Yang JH, Huang T, Zhang N, Wang Y et al (2017) Excellent dielectric properties of poly(vinylidene fluoride) composites based on partially reduced graphene oxide. Compos Part B Eng 109:91–100CrossRef

Yadav M, Ahmad S (2015) Montmorillonite/graphene oxide/chitosan composite: synthesis, characterization and properties. Int J Bio Macromol 79:923–933CrossRef

Ye S, Feng J (2013) A new insight into the in situ thermal reduction of graphene oxide dispersed in a polymer matrix. Polym Chem 4:1765–1768CrossRef

You F, Wang D, Cao J, Li X, Dang ZM, Hu GH (2014) In situ thermal reduction of graphene oxide in a styrene–ethylene/butylene–styrene triblock copolymer via melt blending. Polym Int 63:93–99CrossRef

Yu S, Qin F, Wang G (2016) Improving dielectric properties of poly (vinylidene fluoride) composites induced by poly(vinyl pyrrolidone)-encapsulated polyaniline nanorods. J Mater Chem C 4:1504–1510CrossRef

Zhang B, Ning W, Zhang J, Qiao X, Zhang J, He J et al (2010) Stable dispersions of reduced graphene oxide in ionic liquids. J Mater Chem 20:5401–5403CrossRef

Zhang Z, Luo H, Jiang X, Jiang Z, Yang C (2015) Synthesis of reduced graphene oxide-montmorillonite nanocomposite and its application in hexavalent chromium removal from aqueous solutions. RSC Adv 5:47408–47417CrossRef

Zhang GW, Wang FZ, Dai J, Huang Z (2016) Effect of functionalization of graphene nanoplatelets on the mechanical and thermal properties of silicone rubber composites. Materials 9(2):92CrossRef

Title: Dispersion of reduced graphene oxide with montmorillonite for enhancing dielectric properties and thermal stability of cyanoethyl cellulose nanocomposites
Authors: Feijun Wang
Minghua Wang
Ziqiang Shao
Publication date: 25-09-2018
Publisher: Springer Netherlands
Published in: Cellulose / Issue 12/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-2049-z

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