Skip to main content
Top

2019 | OriginalPaper | Chapter

Distribution and Chemical Species of Chromium in the EAF Dust from Stainless Steel Plant

Authors : Zhi Li, Guojun Ma, Xiang Zhang

Published in: REWAS 2019

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Electric Arc Furnace (EAF) dust generated in the production process of stainless steel is a hazard to the environment and human health due to its large amounts of toxic substances, such as Cr(VI). Cr in the EAF dust is mainly in the form of a residue according to sequential extraction procedure test, and only small amounts of Cr are mobility. Although the formation mechanism of the EAF dust has been gradually understood, the distribution and chemical species of Cr in EAF dust are rarely studied. In this paper, the distribution and chemical species of Cr in EAF dust were studied. The results show that Cr(III) and Cr(VI) are mainly present in the small particles. After sputtering about 140 s with Ar+ ion beam, the Cr(VI) on the surface of dust particles disappears, and the content of Cr(III) reaches 100%, indicating the Cr(VI) in the EAF dust comes from the oxidation of lower valent Cr-containing substances and enrich on the surface of the dust particles.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Yan YF, Chen JX, Hu L (2007) Chromium metallurgy. Metallurgical Industry Press, Beijing Yan YF, Chen JX, Hu L (2007) Chromium metallurgy. Metallurgical Industry Press, Beijing
2.
go back to reference GB/T 12230, General purpose industrial valves-Specification of stainless steel castings GB/T 12230, General purpose industrial valves-Specification of stainless steel castings
3.
go back to reference ASTM A351, Standard specification for castings, austenitic, for pressure-containing parts ASTM A351, Standard specification for castings, austenitic, for pressure-containing parts
4.
go back to reference JIS G5121, Corrosion-resistant cast steels for general application JIS G5121, Corrosion-resistant cast steels for general application
6.
go back to reference Vargas ASD, Ângela B, Masuero, Vilela ACF (2006) Investigations on the use of electric-arc furnace dust (EAFD) in Pozzolan-modified Portland cement I (MP) pastes. Cem Concr Res 36(10):1833–1841 Vargas ASD, Ângela B, Masuero, Vilela ACF (2006) Investigations on the use of electric-arc furnace dust (EAFD) in Pozzolan-modified Portland cement I (MP) pastes. Cem Concr Res 36(10):1833–1841
7.
go back to reference Ma GJ (2005) Cr (VI)-containing electric furnace dust and filter cake: characteristics, formation, leachability and stabilization. University of Pretoria, Pretoria, South Africa, pp 25–98 Ma GJ (2005) Cr (VI)-containing electric furnace dust and filter cake: characteristics, formation, leachability and stabilization. University of Pretoria, Pretoria, South Africa, pp 25–98
8.
go back to reference Peng B, Peng J (2003) Stainless steel electric arc furnace dust physical and chemical properties and formation mechanism. North China Univ Technol 15(1):34–40 Peng B, Peng J (2003) Stainless steel electric arc furnace dust physical and chemical properties and formation mechanism. North China Univ Technol 15(1):34–40
9.
go back to reference Davis A, Ruby MV, Bergstrom PD (1992) Bioavailability of arsenic and lead in soils from the Butte, Montana, mining district. Environ Sci Technol 26(3):461–468CrossRef Davis A, Ruby MV, Bergstrom PD (1992) Bioavailability of arsenic and lead in soils from the Butte, Montana, mining district. Environ Sci Technol 26(3):461–468CrossRef
10.
go back to reference Ma GJ, Fan W, Xue ZL, Wang W, Tang H (2010) Leachability and fractionation of heavy metals in stainless steelmaking plant dusts. Acta Metallurgica Sinica (English Letters) 3(4):267–276 Ma GJ, Fan W, Xue ZL, Wang W, Tang H (2010) Leachability and fractionation of heavy metals in stainless steelmaking plant dusts. Acta Metallurgica Sinica (English Letters) 3(4):267–276
11.
go back to reference Laforest G, Duchesne J (2006) Characterization and leachability of electric arc furnace dust made from remelting of stainless steel. J Hazard Mater 135(1):156–164CrossRef Laforest G, Duchesne J (2006) Characterization and leachability of electric arc furnace dust made from remelting of stainless steel. J Hazard Mater 135(1):156–164CrossRef
12.
go back to reference Sedumedi HN, Mandiwana KL, Ngobeni P, Panichev N (2009) Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter. J Hazard Mater 172(2):1686–1689CrossRef Sedumedi HN, Mandiwana KL, Ngobeni P, Panichev N (2009) Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter. J Hazard Mater 172(2):1686–1689CrossRef
13.
go back to reference Beukes JP, Dawson NF, Zyl PGV (2010) Theoretical and practical aspects of Cr(VI) in the South African ferrochrome industry. J S Afr Inst Min Metall 110(12):743–750 Beukes JP, Dawson NF, Zyl PGV (2010) Theoretical and practical aspects of Cr(VI) in the South African ferrochrome industry. J S Afr Inst Min Metall 110(12):743–750
14.
go back to reference Fan W, Ma GJ, Xue ZL, Yang F, Fang Y (2012) Formation of Cr(VI)-bearing phases in the EAF dust from stainless steel plant. J Mater Metall Fan W, Ma GJ, Xue ZL, Yang F, Fang Y (2012) Formation of Cr(VI)-bearing phases in the EAF dust from stainless steel plant. J Mater Metall
15.
go back to reference Cheng JF, Xu MH, Zeng HC, Feng R, Qiao Y (2002) The study of oxidation dynamic of Cr at high temperature. Chin J Electr Eng 22(8):135–138 Cheng JF, Xu MH, Zeng HC, Feng R, Qiao Y (2002) The study of oxidation dynamic of Cr at high temperature. Chin J Electr Eng 22(8):135–138
16.
go back to reference Ma GJ, Su WH, Xue ZL, Xu ZH (2009) Microstructure and occurrence of chromium of the stainless steel plant dusts. China Iron and Steel Association, Beijing, China, 12 Nov 2009 Ma GJ, Su WH, Xue ZL, Xu ZH (2009) Microstructure and occurrence of chromium of the stainless steel plant dusts. China Iron and Steel Association, Beijing, China, 12 Nov 2009
17.
go back to reference Wu YJ, Jiang ZH, Liang LK, Jiang MF, Huang ZZ, Chen ZP (2003) Analysis of correlative thermodynamic problems in stainless steel smelting process(II)-dephosphorization of chromium- containing hot metal. J Iron Steel Res 15(4):12–17 Wu YJ, Jiang ZH, Liang LK, Jiang MF, Huang ZZ, Chen ZP (2003) Analysis of correlative thermodynamic problems in stainless steel smelting process(II)-dephosphorization of chromium- containing hot metal. J Iron Steel Res 15(4):12–17
18.
go back to reference Zhang JY, Xing XR, Song B (2004) Metallurgical physical chemistry. Metallurgical Industry Press, Beijing, pp 317–318 Zhang JY, Xing XR, Song B (2004) Metallurgical physical chemistry. Metallurgical Industry Press, Beijing, pp 317–318
Metadata
Title
Distribution and Chemical Species of Chromium in the EAF Dust from Stainless Steel Plant
Authors
Zhi Li
Guojun Ma
Xiang Zhang
Copyright Year
2019
DOI
https://doi.org/10.1007/978-3-030-10386-6_43

Premium Partners