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Published in: Journal of Materials Engineering and Performance 10/2018

24-09-2018

Effect of Different Zirconium Contents on the Corrosion Resistance of ZrO2-TiO2 Film-Coated Stainless Steel

Authors: Aiming Bu, Guojun Ji, Quansheng Liu, Zhiming Shi

Published in: Journal of Materials Engineering and Performance | Issue 10/2018

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Abstract

This work discusses the corrosion resistance of x%zirconia (ZrO2)–x%titania (TiO2) nanocomposite films with different percentages of ZrO2 prepared on stainless steel by dipping the substrates in sol–gel solutions. The phase compositions and microstructures of the films were investigated by x-ray diffraction (XRD) and scanning electron microscopy (SEM). Tafel polarization curves and electrochemical impedance spectroscopy (EIS) were employed to investigate the corrosion resistance of the coated steel substrates during immersion in a 5% NaCl solution at room temperature. The results showed that when the percentage of ZrO2 in the sol–gel was relatively low, the film contained cracks, leading to a poor corrosion resistance. When the percentage of ZrO2 was higher, the corrosion resistance of the film was also affected by the sintering temperature; a sintering temperature of 650 °C gave the best protection of the metal surface, and the protection efficiency was 95%.

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Literature
1.
go back to reference J.J. Chen, Q. Xiao, Z.P. Lu, X.K. Ru, H. Peng, Q. Xiong, and H.J. Li, Characterization of Interfacial Reactions and Oxide Films on 316L Stainless Steel in Various Simulated PWR Primary Water Environments, J. Nucl. Mater., 2017, 489, p 137–149CrossRef J.J. Chen, Q. Xiao, Z.P. Lu, X.K. Ru, H. Peng, Q. Xiong, and H.J. Li, Characterization of Interfacial Reactions and Oxide Films on 316L Stainless Steel in Various Simulated PWR Primary Water Environments, J. Nucl. Mater., 2017, 489, p 137–149CrossRef
2.
go back to reference H. Luo, H.Z. Su, C.F. Dong, and X.G. Li, Passivation and Electrochemical Behavior of 316L Stainless Steel in Chlorinated Simulated Concrete Pore Solution, Appl. Surf. Sci., 2017, 400, p 38–48CrossRef H. Luo, H.Z. Su, C.F. Dong, and X.G. Li, Passivation and Electrochemical Behavior of 316L Stainless Steel in Chlorinated Simulated Concrete Pore Solution, Appl. Surf. Sci., 2017, 400, p 38–48CrossRef
3.
go back to reference M.Q. Fan, S.X. Hu, B. Ren et al., Synthesis of Nanocomposite TiO2/ZrO2 Prepared by Different Templates and Photocatalytic Properties for the Photodegradation of Rhodamine B, Powder Technol., 2013, 235, p 27–32CrossRef M.Q. Fan, S.X. Hu, B. Ren et al., Synthesis of Nanocomposite TiO2/ZrO2 Prepared by Different Templates and Photocatalytic Properties for the Photodegradation of Rhodamine B, Powder Technol., 2013, 235, p 27–32CrossRef
4.
go back to reference A. Hidetaka, N. Madoka, and O. Sachiko, Fabrication of Thick Nanoporous Oxide Films on Stainless Steel Via DC Anodization and Subsequent Biofunctionalization, Surf. Coat. Technol., 2016, 307, p 441–451CrossRef A. Hidetaka, N. Madoka, and O. Sachiko, Fabrication of Thick Nanoporous Oxide Films on Stainless Steel Via DC Anodization and Subsequent Biofunctionalization, Surf. Coat. Technol., 2016, 307, p 441–451CrossRef
5.
go back to reference D. Levchuk, F. Koch, H. Maier, and H. Bolt, Deuterium Permeation Through Eurofer and Alpha-Alumina Coated Eurofer, J. Nucl. Mater., 2004, 328, p 103–106CrossRef D. Levchuk, F. Koch, H. Maier, and H. Bolt, Deuterium Permeation Through Eurofer and Alpha-Alumina Coated Eurofer, J. Nucl. Mater., 2004, 328, p 103–106CrossRef
6.
go back to reference D. Levchuk, S. Levchuk, H. Maier, H. Bolt, and A. Suzuki, Erbium Oxide as a New Promising Tritium Permeation Barrier, J. Nucl. Mater., 2007, 367, p 1033–1037CrossRef D. Levchuk, S. Levchuk, H. Maier, H. Bolt, and A. Suzuki, Erbium Oxide as a New Promising Tritium Permeation Barrier, J. Nucl. Mater., 2007, 367, p 1033–1037CrossRef
7.
go back to reference G.K. Zhang, X.L. Wang, Y.F. Xiong, Y. Shi, J.F. Song, and D.L. Luo, Mechanism for Adsorption, Dissociation and Diffusion of Hydrogen in Hydrogen Permeation Barrier of Alpha-Al2O3: A Density Functional Theory Study, Int. J. Hydrogen Energy, 2013, 38, p 1157–1165CrossRef G.K. Zhang, X.L. Wang, Y.F. Xiong, Y. Shi, J.F. Song, and D.L. Luo, Mechanism for Adsorption, Dissociation and Diffusion of Hydrogen in Hydrogen Permeation Barrier of Alpha-Al2O3: A Density Functional Theory Study, Int. J. Hydrogen Energy, 2013, 38, p 1157–1165CrossRef
8.
go back to reference C. Zeng, Y.K. Bai, Y.H. Ling, Z.Y. Xin, H. Liang, and X.K. Deng, Hydrogen Interaction Characteristic of Nanoscale Oxide Films Grown on Iron–nickel Based Stainless Steel by Selective Thermal Oxidation, Int. J. Hydrogen Energy, 2017, 42, p 20910–20921CrossRef C. Zeng, Y.K. Bai, Y.H. Ling, Z.Y. Xin, H. Liang, and X.K. Deng, Hydrogen Interaction Characteristic of Nanoscale Oxide Films Grown on Iron–nickel Based Stainless Steel by Selective Thermal Oxidation, Int. J. Hydrogen Energy, 2017, 42, p 20910–20921CrossRef
9.
go back to reference A. Naumenko, I. Gnatiuk, N. Smirnova, and A. Eremenko, Characterization of Sol–Gel Derived TiO2/ZrO2 Films and Powders by Raman Spectroscopy, Thin Solid Films, 2012, 520, p 4541–4546CrossRef A. Naumenko, I. Gnatiuk, N. Smirnova, and A. Eremenko, Characterization of Sol–Gel Derived TiO2/ZrO2 Films and Powders by Raman Spectroscopy, Thin Solid Films, 2012, 520, p 4541–4546CrossRef
10.
go back to reference S.W. Liu, Y.M. Wang, Z.L. Xiu, M.K. Lu, and C.L. Yu, Preparation and Photocatalytic Properties of La-Doped TiO2/ZrTiO4 Heterogeneous Thin Films, J. Alloy. Compd., 2006, 425, p 274–277CrossRef S.W. Liu, Y.M. Wang, Z.L. Xiu, M.K. Lu, and C.L. Yu, Preparation and Photocatalytic Properties of La-Doped TiO2/ZrTiO4 Heterogeneous Thin Films, J. Alloy. Compd., 2006, 425, p 274–277CrossRef
11.
go back to reference G.N. Shao, S.M. Imran, S.J. Jeon, M. Engole, N. Abbas, M.S. Haider, S.J. Kang, and H.T. Kima, Sol–Gel Synthesis of Photoactive Zirconia-Titania from Metal Salts and Investigation of Their Photocatalytic Properties in the Photodegradation of Methylene Blue, Powder Technol., 2014, 258, p 99–109CrossRef G.N. Shao, S.M. Imran, S.J. Jeon, M. Engole, N. Abbas, M.S. Haider, S.J. Kang, and H.T. Kima, Sol–Gel Synthesis of Photoactive Zirconia-Titania from Metal Salts and Investigation of Their Photocatalytic Properties in the Photodegradation of Methylene Blue, Powder Technol., 2014, 258, p 99–109CrossRef
12.
go back to reference O. Linnik, N. Shestopal, N. Smirnova, A. Eremenko, O. Korduban, V. Kandyba, T. Kryshchuk, G. Socol, N. Stefan, G. Popescu-Pelin, C. Ristoscu, and I.N. Mihailescu, Correlation Between Electronic Structure and Photocatalytic Properties of Non-metal Doped TiO2/ZrO2 Thin Films Obtained by Pulsed Laser Deposition Method, Vacuum, 2015, 114, p 166–171CrossRef O. Linnik, N. Shestopal, N. Smirnova, A. Eremenko, O. Korduban, V. Kandyba, T. Kryshchuk, G. Socol, N. Stefan, G. Popescu-Pelin, C. Ristoscu, and I.N. Mihailescu, Correlation Between Electronic Structure and Photocatalytic Properties of Non-metal Doped TiO2/ZrO2 Thin Films Obtained by Pulsed Laser Deposition Method, Vacuum, 2015, 114, p 166–171CrossRef
13.
go back to reference C.C. Ou, C.S. Yang, and S.H. Lin, Selective Photo-Degradation of Rhodamine B Over Zirconia Incorporated Titania Nanoparticles: A Quantitative Approach, Catal. Sci. Technol., 2011, 1, p 295–307CrossRef C.C. Ou, C.S. Yang, and S.H. Lin, Selective Photo-Degradation of Rhodamine B Over Zirconia Incorporated Titania Nanoparticles: A Quantitative Approach, Catal. Sci. Technol., 2011, 1, p 295–307CrossRef
14.
go back to reference Y. Chi, Q. Yuan, Y. Li, L. Zhao, N. Li, X. Li, and W. Yan, Magnetically Separable Fe3O4@SiO2@ TiO2-Ag Microspheres with Well-Designed Nanostructure and Enhanced Photocatalytic Activity, J. Hazard. Mater., 2013, 262, p 404–411CrossRef Y. Chi, Q. Yuan, Y. Li, L. Zhao, N. Li, X. Li, and W. Yan, Magnetically Separable Fe3O4@SiO2@ TiO2-Ag Microspheres with Well-Designed Nanostructure and Enhanced Photocatalytic Activity, J. Hazard. Mater., 2013, 262, p 404–411CrossRef
15.
go back to reference A.M. Bu, J.Z. Wang, J.B. Zhang, J. Bai, Z.M. Shi, Q.S. Liu, and G.J. Ji, Corrosion Behavior of ZrO2-TiO2 Nanocomposite Thin Films Coating on Stainless Steel Through Sol–Gel Method, J. Sol-Gel. Sci. Technol., 2017, 81, p 633–638CrossRef A.M. Bu, J.Z. Wang, J.B. Zhang, J. Bai, Z.M. Shi, Q.S. Liu, and G.J. Ji, Corrosion Behavior of ZrO2-TiO2 Nanocomposite Thin Films Coating on Stainless Steel Through Sol–Gel Method, J. Sol-Gel. Sci. Technol., 2017, 81, p 633–638CrossRef
16.
go back to reference Y. Wang, W. Tian, T. Zhang, and Y. Yang, Microstructure, Spallation and Corrosion of Plasma Sprayed Al2O3-13%TiO2 Coatings, Corros. Sci., 2009, 51, p 2924–2931CrossRef Y. Wang, W. Tian, T. Zhang, and Y. Yang, Microstructure, Spallation and Corrosion of Plasma Sprayed Al2O3-13%TiO2 Coatings, Corros. Sci., 2009, 51, p 2924–2931CrossRef
17.
go back to reference Q. Yuan, Y. Liu, L.L. Li, Z.X. Li, C.J. Fang, W.T. Duan, X.G. Li, and C.H. Yan, Highly Ordered Mesoporous Titania-Zirconia Photocatalyst for Applications in Degradation of Rhodamine-B and Hydrogen Evolution, Microporous Mesoporous Mater., 2009, 124, p 169–178CrossRef Q. Yuan, Y. Liu, L.L. Li, Z.X. Li, C.J. Fang, W.T. Duan, X.G. Li, and C.H. Yan, Highly Ordered Mesoporous Titania-Zirconia Photocatalyst for Applications in Degradation of Rhodamine-B and Hydrogen Evolution, Microporous Mesoporous Mater., 2009, 124, p 169–178CrossRef
18.
go back to reference A. Verma, R. Dwivedi, R. Prasad, and K.S. Bartwal, Microwave-Assisted Synthesis of Mixed Metal-Oxide Nanoparticles, J. Nanopart., 2013, 2013, p 1–11 A. Verma, R. Dwivedi, R. Prasad, and K.S. Bartwal, Microwave-Assisted Synthesis of Mixed Metal-Oxide Nanoparticles, J. Nanopart., 2013, 2013, p 1–11
19.
go back to reference C.J. Brinker, A.J. Hurd, P.R. Schunk, G.C. Frye, and C.S. Ashley, Review of Sol–Gel Thin Film Formation, J. Non-Cryst. Solids, 1992, 148, p 424–436CrossRef C.J. Brinker, A.J. Hurd, P.R. Schunk, G.C. Frye, and C.S. Ashley, Review of Sol–Gel Thin Film Formation, J. Non-Cryst. Solids, 1992, 148, p 424–436CrossRef
20.
go back to reference E.I. Morosanova, Silica and Silica–Titania Sol–Gel Materials: Synthesis and Analytical Application, Talanta, 2012, 102, p 114–122CrossRef E.I. Morosanova, Silica and Silica–Titania Sol–Gel Materials: Synthesis and Analytical Application, Talanta, 2012, 102, p 114–122CrossRef
21.
go back to reference G.N. Shao, G. Elineema, D.V. Quang, Y.N. Kim, Y.H. Shim, A. Hilonga, J.K. Kim, and H.T. Kim, Two Step Synthesis of a Mesoporous Titania-Silica Composite from Titanium Oxychloride and Sodium Silicate, Powder Technol., 2012, 217, p 489–496CrossRef G.N. Shao, G. Elineema, D.V. Quang, Y.N. Kim, Y.H. Shim, A. Hilonga, J.K. Kim, and H.T. Kim, Two Step Synthesis of a Mesoporous Titania-Silica Composite from Titanium Oxychloride and Sodium Silicate, Powder Technol., 2012, 217, p 489–496CrossRef
22.
go back to reference L. Li, Y. Ma, Y.Z. Cao et al., Nano TiO2-ZrO2 Composite Photocatalysts Preparation, Characterization and Photocatalytic Activity, Chemistry, 2009, 6, p 529–533 L. Li, Y. Ma, Y.Z. Cao et al., Nano TiO2-ZrO2 Composite Photocatalysts Preparation, Characterization and Photocatalytic Activity, Chemistry, 2009, 6, p 529–533
23.
go back to reference H. Cheraghi, M. Shahmiri, and Z. Sadeghian, Corrosion Behavior of TiO2-NiO Nanocomposite Thin Films on AISI, 316L Stainless Steel Prepared by Sol–Gel Method, Thin Solid Films, 2012, 522, p 289–296CrossRef H. Cheraghi, M. Shahmiri, and Z. Sadeghian, Corrosion Behavior of TiO2-NiO Nanocomposite Thin Films on AISI, 316L Stainless Steel Prepared by Sol–Gel Method, Thin Solid Films, 2012, 522, p 289–296CrossRef
24.
go back to reference H.B. Li, K.M. Liang, L.F. Mei, S.R. Gu, and S.X. Wang, Corrosion Protection of Mild Steel by Zirconia Sol–Gel Coatings, J. Mater. Sci. Lett., 2001, 20, p 1081–1083CrossRef H.B. Li, K.M. Liang, L.F. Mei, S.R. Gu, and S.X. Wang, Corrosion Protection of Mild Steel by Zirconia Sol–Gel Coatings, J. Mater. Sci. Lett., 2001, 20, p 1081–1083CrossRef
25.
go back to reference P.R. Romero, R. López Ibáñez, F. Martín, J.R. Ramos-Barrado, and D. Leinen, Corrosion Behaviour of Zirconia Barrier Coatings on Galvanized Steel, Surf. Coat. Technol., 2006, 200, p 6606–6610CrossRef P.R. Romero, R. López Ibáñez, F. Martín, J.R. Ramos-Barrado, and D. Leinen, Corrosion Behaviour of Zirconia Barrier Coatings on Galvanized Steel, Surf. Coat. Technol., 2006, 200, p 6606–6610CrossRef
26.
go back to reference K. Ruben, Y. Sergey, P. Devdas, and S. Jag, Corrosion Behavior of Reactive Sputtered Al2O3 and ZrO2 Thin Films on Mg Disk Immersed in Saline Solution, J. Mater. Sci. Technol., 2015, 31, p 873–880CrossRef K. Ruben, Y. Sergey, P. Devdas, and S. Jag, Corrosion Behavior of Reactive Sputtered Al2O3 and ZrO2 Thin Films on Mg Disk Immersed in Saline Solution, J. Mater. Sci. Technol., 2015, 31, p 873–880CrossRef
27.
go back to reference G.I. Cubillos, M. Bethencourt, and J.J. Olaya, Corrosion Resistance of Zirconium Oxynitride Coatings Deposited Via DC Unbalanced Magnetron Sputtering and Spray Pyrolysis-Nitriding, Appl. Surf. Sci., 2015, 327, p 288–295CrossRef G.I. Cubillos, M. Bethencourt, and J.J. Olaya, Corrosion Resistance of Zirconium Oxynitride Coatings Deposited Via DC Unbalanced Magnetron Sputtering and Spray Pyrolysis-Nitriding, Appl. Surf. Sci., 2015, 327, p 288–295CrossRef
28.
go back to reference M.A. Hany and M.K. Mai, Corrosion Resistance of ZrO2-TiO2 Nanocomposite Multilayer Thin Films Coated on Carbon Steel in Hydrochloric Acid Solution, Mater. Charact., 2015, 108, p 29–41CrossRef M.A. Hany and M.K. Mai, Corrosion Resistance of ZrO2-TiO2 Nanocomposite Multilayer Thin Films Coated on Carbon Steel in Hydrochloric Acid Solution, Mater. Charact., 2015, 108, p 29–41CrossRef
Metadata
Title
Effect of Different Zirconium Contents on the Corrosion Resistance of ZrO2-TiO2 Film-Coated Stainless Steel
Authors
Aiming Bu
Guojun Ji
Quansheng Liu
Zhiming Shi
Publication date
24-09-2018
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 10/2018
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-018-3639-5

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