Top

Journal of Coatings Technology and Research

Hint

Swipe to navigate through the articles of this issue

Published in:

10-09-2021

Effect of humidity on curing of alkoxysilane-functionalized alkyd coatings

Authors: Brittany Pellegrene, Mark D. Soucek

Published in: Journal of Coatings Technology and Research | Issue 6/2021

Abstract

The effect of relative humidity on the curing of alkoxysilane functional alkyds and reactive diluents was evaluated. Alkoxysilane functional alkyds and tung oil-based reactive diluents were synthesized and used as additives in varying amounts in alkyd coatings. Looking at modified alkyd versus modified reactive diluent allows for the comparison of the humidity effect on high and low molecular weight alkoxysilane functional additives. The coatings were cured at 25 and 75% relative humidity and evaluated for drying time, coating and tensile properties, and gel content. It was found that at higher humidity, the alkoxysilane-containing samples improved properties significantly when compared to the control alkyd.

previous article Liquid film stability and contact line dynamics of emulsion liquid films in curtain coating process

next article The influence of methacrylic acid and urethane methacrylate on the film properties of hybrid urethane–acrylic latexes

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Weiss, KD, Paint and Coatings: A Mature Industry in Transition. Prog. Polym. Sci. 22 (2) 203–245. https://doi.org/10.1016/S0079-6700(96)00019-6 (1997) CrossRef

Ren, X, Meng, L, Soucek, M, Environmentally Friendly Coatings. In: Tiwari, A, Galanis, A, Soucek, MD (eds.) Biobased and Environmental Benign Coatings, Wiley, Hoboken, pp. 183–223. https://doi.org/10.1002/9781119185055.ch8 (2016) CrossRef

Hofland, A, Alkyd Resins: From Down and Out to Alive and Kicking. Prog. Org. Coat. 73 (4) 274–282. https://doi.org/10.1016/j.porgcoat.2011.01.014 (2012) CrossRef

Kobayashi, S, Müllen, K (eds) Encyclopedia of Polymeric Nanomaterials. Springer Berlin Heidelberg, Berlin Heidelberg. https://doi.org/10.1007/978-3-642-29648-2 (2015) CrossRef

Holmberg, K, High Solids Alkyd Resins. Marcel Dekker Inc, New York. (1987)

Wicks, ZW (ed) Organic Coatings: Science and Technology, 3rd edn. Wiley-Interscience, Hoboken, NJ (2007)

Sailer, RA, Soucek, MD, Oxidizing Alkyd Ceramers. Prog. Org. Coat. 33 (1) 36–43. https://doi.org/10.1016/S0300-9440(98)00005-8 (1998) CrossRef

Sailer, RA, Soucek, MD, Viscoelastic Properties of Alkyd Ceramers. J. Appl. Polym. Sci. 73 (10) 2017–2028. https://doi.org/10.1002/(SICI)1097-4628(19990906)73:10%3c2017::AID-APP20%3e3.0.CO;2-1 (1999) CrossRef

Pathan, S, Ahmad, S, Synergistic Effects of Linseed Oil Based Waterborne Alkyd and 3-Isocynatopropyl Triethoxysilane: Highly Transparent, Mechanically Robust, Thermally Stable, Hydrophobic Anticorrosive Coatings. ACS Sustain. Chem. Eng. 4 (6) 3062–3075. https://doi.org/10.1021/acssuschemeng.6b00024 (2016) CrossRef

10.

Wen, J, Wilkes, GL, Organic/Inorganic Hybrid Network Materials by the Sol−Gel Approach. Chem. Mater. 8 (8) 1667–1681. https://doi.org/10.1021/cm9601143 (1996) CrossRef

11.

Zvonkina, I, Soucek, M, Inorganic-Organic Hybrid Coatings: Common and New Approaches. Curr. Opin. Chem. Eng. 11, 123–127. https://doi.org/10.1016/j.coche.2016.01.008 (2016) CrossRef

12.

Wang, D, Bierwagen, GP, Sol–Gel Coatings on Metals for Corrosion Protection. Prog. Org. Coat. 64 (4) 327–338. https://doi.org/10.1016/j.porgcoat.2008.08.010 (2009) CrossRef

13.

Tohge, N, “Formation of SiO ₂-Based Coatings by the Sol–Gel Method and Their Effects on Water Vapour Permeability of Polyimide Films.” 3.

14.

Teng, G, Soucek, MD, Epoxidized Soybean Oil-Based Ceramer Coatings. J. Am. Oil Chem. Soc. 77 (4) 381–387. https://doi.org/10.1007/s11746-000-0062-0 (2000) CrossRef

15.

Zou, K, Soucek, MD, UV-Curable Organic-Inorganic Hybrid Film Coatings Based on Epoxidized Cyclohexene Derivatized Linseed Oil. Macromol. Chem. Phys. 205 (15) 2032–2039. https://doi.org/10.1002/macp.200400115 (2004) CrossRef

16.

Ni, H, Skaja, AD, Sailer, RA, Soucek, MD, Moisture-Curing Alkoxysilane-Functionalized Isocyanurate Coatings. Macromol. Chem. Phys. 201 (6) 722–732. https://doi.org/10.1002/(SICI)1521-3935(20000301)201:6%3c722::AID-MACP722%3e3.0.CO;2-D (2000) CrossRef

17.

Gilberts, J., Tinnemans, AHA, Hogerheide, MP, Koster, TPM, “UV Curable Hard Transparent Hybrid Coating Materials on Polycarbonate Prepared by the Sol–Gel Method”. 7.

18.

Danks, AE, Hall, SR, Schnepp, Z, The Evolution of ‘Sol–Gel’ Chemistry as a Technique for Materials Synthesis. Mater. Horiz. 3 (2) 91–112. https://doi.org/10.1039/C5MH00260E (2016) CrossRef

19.

Hench, LL, West, JK, The Sol–Gel Process. Chem. Rev. 90 (1) 33–72. https://doi.org/10.1021/cr00099a003 (1990) CrossRef

20.

Brinker, CJ, Scherer, GW, Sol–Gel Science: The Physics and Chemistry of Sol–Gel Processing. Academic Press. (2013)

21.

Young, SK, Overview of Sol–Gel Science and Technology. ARL-TR-2650; Army Research Laboratory (2002)

22.

Brinker, CJ, Hydrolysis and Condensation of Silicates: Effects on Structure. J. Non-Cryst. Solids 100 (1–3) 31–50. https://doi.org/10.1016/0022-3093(88)90005-1 (1988) CrossRef

23.

Brinker, C, Frye, G, Ashley, C, Smith, D, Davis, P, Hietala, S, “Sol–Gel Routes to Controlled Pore-Size Amorphous Oxides.” In: Abstracts of Papers of the American Chemical Society; Amer. Chemical Soc, Washington, DC 20036, Vol. 201, pp 348–INOR (1991)

24.

Brinker, CJ, Hurd, AJ, Schunk, PR, Frye, GC, Ashley, CS, Review of Sol–Gel Thin Film Formation. J. Non-Cryst. Solids 147–148, 424–436. https://doi.org/10.1016/S0022-3093(05)80653-2 (1992) CrossRef

25.

Wold, CR, Soucek, MD, Viscoelastic and Thermal Properties of Linseed Oil-Based Ceramer Coatings. Macromol. Chem. Phys. 201 (3) 382–392. https://doi.org/10.1002/(SICI)1521-3935(20000201)201:3%3c382::AID-MACP382%3e3.0.CO;2-9 (2000) CrossRef

26.

Teng, G, Wegner, JR, Hurtt, GJ, Soucek, MD, Novel Inorganic/Organic Hybrid Materials Based on Blown Soybean Oil with Sol–Gel Precursors. Prog. Org. Coat. 42 (1–2) 29–37. https://doi.org/10.1016/S0300-9440(01)00126-6 (2001) CrossRef

27.

Tuman, SJ, Soucek, MD, Novel Inorganic/Organic Coatings Based on Linseed Oil and Sunflower Oil with Sol–Gel Precursors. JCT J. Coat. Technol. 68, 854 (1996)

28.

Wold, CR, Soucek, MD, Mixed Metal Oxide Inorganic/Organic Coatings. J. Coat. Technol. 70 (7) 43–51. https://doi.org/10.1007/BF02720514 (1998) CrossRef

29.

Baghdachi, J, Li, D, LaForest, J, Isocyanate-Free Moisture Cure Coatings. J. Coat. Technol. 74 (9) 81–87. https://doi.org/10.1007/BF02697977 (2002) CrossRef

30.

Chang, W-H, Hartman, ME, Scriven, RL, “Ambient Temperature, Moisture-Curable Acrylic-Silane Coating Compositions Having Improved Potlife.” US Patent 4,043,953, August 23, 1977

31.

Emmerling, W, Padola, T, Unger, L, Majolo, M, “Moisture-Curing Alkoxysilane-Terminated Polyurethanes.” US Patent 5,554,709, September 10, 1996

32.

Ni, H, Skaja, AD, Soucek, MD, Acid-Catalyzed Moisture-Curing Polyurea/Polysiloxane Ceramer Coatings. Prog. Org. Coat. 40 (1–4) 175–184. https://doi.org/10.1016/S0300-9440(00)00116-8 (2000) CrossRef

33.

D01 Committee. Test Methods for Acid Value of Organic Coating Materials; D 1639-90; ASTM International (1996)

34.

D01 Committee. Test Methods for Hydroxyl Value of Fatty Oils and Acids; D 1957-86; ASTM International (2001)

35.

D01 Committee. Test Methods for Hardness of Organic Coatings by Pendulum Damping Tests; D 4366-16; ASTM International. https://doi.org/10.1520/D4366-16

36.

D01 Committee. Test Method for Film Hardness by Pencil Test; D 3363-05; ASTM International. https://doi.org/10.1520/D3363-05R11E02

37.

D01 Committee. Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers; D 4541-17; ASTM International. https://doi.org/10.1520/D4541-17

38.

Salata, RR, Pellegrene, B, Soucek, MD, "Synthesis and Properties of a High Solids Triethoxysilane-Modified Alkyd Coatings." Prog. Org. Coat., 133 340–349 (2019) CrossRef

39.

Wutticharoenwong, K, Soucek, MD, Synthesis of Tung-Oil-Based Reactive Diluents. Macromol. Mater. Eng. 295 (12) 1097–1106. https://doi.org/10.1002/mame.201000099 (2010) CrossRef

40.

Wutticharoenwong, K, Dziczkowski, J, Soucek, MD, Tung Based Reactive Diluents for Alkyd Systems: Film Properties. Prog. Org. Coat. 73 (4) 283–290. https://doi.org/10.1016/j.porgcoat.2011.03.017 (2012) CrossRef

41.

Schmidt, H, Scholze, H, Kaiser, A, Principles of Hydrolysis and Condensation Reaction of Alkoxysilanes. J. Non-Cryst. Solids 63, 1–11 (1984) CrossRef

42.

Greenbank, GR, Holm, GE, Some Factors Concerned in the Autoxidation of Fats. Ind. Eng. Chem. 16 (6) 598–601. https://doi.org/10.1021/ie50174a024 (1924) CrossRef

43.

Minemoto, Y, Adachi, S, Matsuno, R, "Effect of Relative Humidity During Storage on the Autoxidation of Linoleic Acid Encapsulated with a Polysaccharide by Hot-Air-Drying and Freeze-Drying." Food Sci. Technol. Res., 7 (1) 91–93. https://doi.org/10.3136/fstr.7.91 (2001) CrossRef

44.

Sinha, A, Islam Khan, N, Das, S, Zhang, J, Halder, S, Effect of Reactive and Non-Reactive Diluents on Thermal and Mechanical Properties of Epoxy Resin. High Perform. Polym. 30 (10) 1159–1168. https://doi.org/10.1177/0954008317743307 (2018) CrossRef

45.

Wool, RP, “Properties of Triglyceride-Based Thermosets.” In: Bio-Based Polymers and Composites

46.

DiMarzio, EA, The Entropy Theory of Glass Formation after 40 Years. Comput. Mater. Sci. 4, 317–324 (1995) CrossRef

47.

DiMarzio, EA, The Glass Temperature of Polymer Blends. Polymer 31, 2294–2298 (1990) CrossRef

48.

DiMarzio, EA, On the Second-Order Transition of a Rubber. J. Res. Natl. Bur. Stand. Phys. Chem. 68A (6) 611–617 (1964) CrossRef

49.

DiMarzio, EA, Guttman, CM, The Glass Temperature of Polymer Rings. Macromolecules 20, 1403–1407 (1987) CrossRef

50.

Hale, A, Macosko, CW, Bair, HE, Glass Transition Temperature as a Function of Conversion in Thermosetting Polymers. Macromolecules 24 (9) 2610–2621. https://doi.org/10.1021/ma00009a072 (1991) CrossRef

51.

Arkles, B, Commercial Applications of Sol–Gel-Derived Hybrid Materials. MRS Bull. 26 (05) 402–408. https://doi.org/10.1557/mrs2001.94 (2001) CrossRef

Title: Effect of humidity on curing of alkoxysilane-functionalized alkyd coatings
Authors: Brittany Pellegrene
Mark D. Soucek
Publication date: 10-09-2021
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 6/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-021-00494-w

Springer Professional

Hint

Swipe to navigate through the articles of this issue

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 6/2021

Simplification of interior latex paint using biopolymer to replace rheological additives and calcium carbonate extender

Nanolatex technology 1: synthesis and characterization of nanosize acrylic latexes and comparison to their conventional size counterparts

Synthesis, analysis, and application of lactide-based polyester as coating with improved mechanical and rheological behavior

A review of plasma-based superhydrophobic textiles: theoretical definitions, fabrication, and recent developments

Synthesis of silicone-acrylic-modified high-ortho novolac resin with enhanced thermal resistance and surface coating properties

Synthesis of UV-curable polyesters with lateral double bonds by ring-opening polymerization and their properties

Premium Partners