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Published in: Physics of Metals and Metallography 9/2018

01-09-2018 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Effect of Hydrogen Intercalation on the Structure of YBa2Cu3Oy with a Low Oxygen Content

Authors: I. B. Bobylev, Yu. S. Ponosov, N. A. Zyuzeva, P. B. Terent’ev

Published in: Physics of Metals and Metallography | Issue 9/2018

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Abstract

We used Raman spectroscopy to study the interaction of YBa2Cu3Oy (123) (y ≤ 6.5) with hydrogen at temperatures of 150–200°С. In contrast to the YBa2Cu3O6.96 compound, compositions with low oxygen contents show a lower tendency to form stacking faults. We found that the hydrogenation of these compositions does not lead to the transformation of the 123 phase to the pseudo-124 phase. Absorbed hydrogen does not react with oxygen in 123 and does not form hydroxyl groups. The HxYBa2Cu3Oy oxyhydride is the hydration-reaction product.

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Metadata
Title
Effect of Hydrogen Intercalation on the Structure of YBa2Cu3Oy with a Low Oxygen Content
Authors
I. B. Bobylev
Yu. S. Ponosov
N. A. Zyuzeva
P. B. Terent’ev
Publication date
01-09-2018
Publisher
Pleiades Publishing
Published in
Physics of Metals and Metallography / Issue 9/2018
Print ISSN: 0031-918X
Electronic ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X1809003X

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