Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Metallurgist
Published in: Metallurgist 7-8/2016

01-11-2016

Effect of N, Mo, and Si on Local Corrosion Resistance of Unstabilized Cr–Ni and Cr–Mn–Ni Austenitic Steels

Authors: L. A. Pisarevskii, G. A. Filippov, A. A. Lipatov

Published in: Metallurgist | Issue 7-8/2016

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Features of the effect of both individual and combined alloying with nitrogen, molybdenum and silicon of unstabilized cold-worked and heat-treated austenitic Cr–Ni and Cr–Mn–Ni steels on pitting and intercrystalline corrosion (ICC) resistance in weakly oxidizing media are studied. On the basis of corrosion and electrochemical test results (electrochemical method), an ambiguous effect of alloying cold worked Cr–Mn–Ni steels with nitrogen and molybdenum on pitting corrosion resistance is revealed. It is established that a necessary condition for intergranular corrosion resistance of chromium-nickel steels after prolonged tempering at 550–750°C is the presence of silicon in addition to nitrogen and molybdenum, which participates in improving the passivity of chromium-depleted boundary zones. Silicon added to nitrogen-containing steel alloyed with molybdenum and 0.03 wt.% carbon with a balanced content of Cr, N, Mo and Si facilitates an improvement of passivity for boundary zones impoverished in chromium. Introduction of silicon into nitrogen-containing chromium-nickel steel (0.03% C) alloyed with molybdenum with a balanced content of Cr, Ni, Mo, and Si makes its ICC resistance equal to specially low-alloy stainless steel containing 0.003% C.
previous article Effect of Hot Rolling Parameters on Excess Phase Precipitation in Two-Phase Ferritic-Martensitic Steels
next article Effect of Alloying with Aluminum and Deformation-Heat Treatment on Rolled Product Crystal Structure

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
E. A. Ul’yanin, T. V. Svistunova, and F. L. Levin, High-Alloy Corrosion-Resistant Steels, Metallurgiya, Moscow (1987), pp. 39–41.
2.
E. G. Fel’gandler, N. A. Sorokina, T. V. Svistunova, and F. A. Levin, “Contemporary corrosion-resistant steels and alloys for media of different corrosiveness,” in: Contemporary Metallurgy Problems, Metallurgiya, Moscow (1983), pp. 160–168.
3.
T. V. Svistunova, A. P. Shlyamnev, B. S. Litvak, and N. G. Danovskii, Patent 2288967 RF, C22C38/54, "Corrosionresistant alloy and object made from it," subm. 04.15.2005, publ. 12.10.2006.
4.
A. P. Shlyamnev, “Nitrogen-containing stainless steels – structure, properties, manufacturing and application prospects,” Probl. Chern. Met. Meterialoved., No. 1, 53–60 (2007).
5.
A. P. Gulyaev and L. A. Pisarevskii, “Study of the properties and industrial trial of new high-strength low-magnetic steel,” in: High-Strength Nonmagnetic Steels, Nauka, Moscow (1978), pp. 186–191.
6.
A. A. Pisarevskii, “Low-magnetic steels for high-strength wire,” in: Structure and Properties of Nonmagnetic Steels, Nauka, Moscow (1982), pp. 194–197.
7.
L. A. Chigirinskaya, G. P. Chernova, and N. D. Tomashov, “Corrosion behavior of chromium-nickel-molybdenum steel with nitrogen,” Zashchita Met., XX, No. 3, 404–407 (1984).
8.
L. A. Pisarevskii and S. A. Golovanenko, “Structure and properties of stainless steels with nitrogen and molybdenum,” Proc. Conf. New in Materials Science and Heat Treatment of Metals and Alloys, Chelyabinsk, NIIM, June 1983, pp. 6–8.
9.
S. A. Golovanenko and L. A. Pisarevskii, “Corrosion-resistant steels for high-strength cables and wire,” in: Problems of Contemporary Metallurgy, Metallurgiya, Moscow (1983), pp. 153–159.
10.
L. A. Pisarevskii, D. V. Aparin, E. A. Ul’yanin, et al., “Effect of nitrogen and molybdenum on nonmagnetic steel resistance to hydrogen cracking,” in: New Special Steel Manufacturing Technology, TsNIIChM, Elektrostal Plant, Moscow (1990), pp. 133–136.
11.
S. A. Glazkova, G. L. Shvartz, L. I. Freiman, and F. N. Tavadze, “Study of the local corrosion resistance of chromium-nickel steels alloyed with molybdenum and silicon,” Zashchita Met., 10, No. 1, 9–16 (1974).
12.
T. V. Svistunova and N. D. Sakuta, “Effect of carbon, silicon, and phosphorus on mechanical properties of steel NM27,” in: Improvement of the Properties of High-Quality Steels due to Alloying and Structure Optimization, Metallurgiya, Moscow (1984), pp. 33–37.
13.
O. V. Kasparov, “Features of intercrystalline corrosion of silicon-containing austenitic stainless steels,” Zashchita Met.. 40, No. 5, 475–481 (2004).
14.
L. Ya. Savkina and E. G. Fel’gandler, “Effect of alloying on tendency towards intercrystalline corrosion of steel 000X16N15M3,” MiTOM, No. 11, 10–13 (1968).
15.
L. P. Lozovatskaya, I. A. Levin, I. K. Burtseva, et al., “Increase in steel 03Kh18N11 ICC corrosion resistance by adjusting its chemical composition,” Zashchita Met.. 20, No. 3, 411–415 (1984).
16.
O. V. Kasparova, V. M. Mil’man, and S. V. Kostromina, “Question of the mechanism of the effect of silicon on intercrystalline corrosion of tempered austenitic stainless steels,” Zashchita Met., 27, No. 1, 55–63 (1991).
17.
O. V. Kasparova and Yu. V. Baldokhin, “Effect of silicon on the electron structure and corrosion electrochemical behavior of phosphorus-containing steel Kh20N20,” Zashchita Met., 38, No. 5, 463–469 (2002).
18.
A. A. Pisarevskii and I. I. Kaputkin, “Effect of heat treatment for nitrogen-containing corrosion resistant steel on its structure and local corrosion,” in: Optimization of Alloying and Heat Treatment of High Quality Steels, Metallurgiya, Moscow (1987), pp. 31–33.
19.
V. V. Beresovskaya, R. Z. Valiev, and Yu. A. Sokolovskaya, “Mechanism of plasticity and phase stability of austenite alloyed with nitrogen in Cr–Mn–Mo steel with rapid plastic deformation,” Vestn. TGU, 18, No. 4, 1961–1962 (2013).
20.
L. M. Kaputkina, A. G. Svyazhin, and V. G. Prokoshkina, “Dissolution and precipitation of excess phases and distribution of nitrogen between solid solution and nitrides in corrosion resistant steel,” Metally, No. 5, 93 (2006).
21.
E. G. Fel’dgandler and A. V. Plaskeev, “Effect of alloying with Si and Cu on corrosion-electrochemical and mechanical properties of austenitic steel,” MiTOM, No. 10, 12–21 (2003).
22.
L. A. Pisarevskii, D. V. Aparin, E. A. Ul’yanin, et al., Inventor’s Cert. 1571099, IPC5 C22C39/44, "Corrosion-resistant steel," subm. 08.05.1998, publ. 06.15.1990.
23.
L. A. Pisarevskii, I. I. Kaputkin, N. L. Bogatova, et al., “Structure and properties of corrosion resistant steel 30Kh18N4AM3D2S2,” in: Effect of Alloying and Heat Treatment on Properties of High Quality Steels and Alloys, Matallurgiya, Moscow (1985), pp. 30–33.
24.
L. M. Kaputkina, V. G. Prokoshkina, A. G. Svyazhin, et al., “Structure and properties of stainless steel alloyed with nitrogen and copper,” MiTOM, No. 6 (648), 22–28 (2009).
25.
L. A. Pisarevskii, D. V. Aparin, E. A. Ul’yanin, et al., Inventor’s Cert. 1694685, IPC5 C22C39/58, "Corrosion-resistant steel," subm. 10.09.1989, publ. 11.30.1991.
Metadata
Title
Effect of N, Mo, and Si on Local Corrosion Resistance of Unstabilized Cr–Ni and Cr–Mn–Ni Austenitic Steels
Authors
L. A. Pisarevskii
G. A. Filippov
A. A. Lipatov
Publication date
01-11-2016
Publisher
Springer US
Published in
Metallurgist / Issue 7-8/2016
Print ISSN: 0026-0894
Electronic ISSN: 1573-8892
DOI
https://doi.org/10.1007/s11015-016-0372-x

Other articles of this Issue 7-8/2016

Metallurgist 7-8/2016 Go to the issue

OriginalPaper

A Mechanism of Interaction of Metal Oxides with Carbon

OriginalPaper

Effect of Hot Rolling Parameters on Excess Phase Precipitation in Two-Phase Ferritic-Martensitic Steels

OriginalPaper

Optimizing the Geometry of Piercing Stub Mandrels for Tube Extrusion

OriginalPaper

Intensification of Sulfide Copper-Nickel Ore Heap Leaching with Bioreagent-Oxidant Participation

OriginalPaper

Features of Structure and Property Formation of Rolled Coil for Wire Manufacture

OriginalPaper

Treatment with a High-Temperature Pulsed Plasma and Laser Radiation for Die Steel Surface Layer Hardening

Premium Partners

    Image Credits