Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 7/2022

07-02-2022 | Technical Article

Effect of Salinity, Total Dissolved Solids, Conductivity, and pH on Corrosion Behavior of Different Microstructures Made from High-Carbon Rail Steel

Authors: Kirtiratan Godbole, K. Mondal

Published in: Journal of Materials Engineering and Performance | Issue 7/2022

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The work discusses the effect of salinity, conductivity, total dissolved solids (TDS), and pH on corrosion behavior of bainite, martensite, and tempered martensite steels made from high-carbon rail steel using austempering, water quenching, and tempering of quenched steel, respectively. Immersion test in freely aerated 3.5% NaCl solution was carried out for 5-28 days. Even though the salinity and conductivity increase with decrease in pH with time, the increased TDS and α/γ* ratio, wherein α designates weight fraction of α-FeOOH, and γ* represents the combination of the weight proportions of γ-FeOOH and β-FeOOH rust phases finally induce enhanced corrosion resistance to the steels irrespective of their microstructure. In addition, the steel with bainitic microstructure shows better corrosion resistance than the other two steels.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference E.C. De Souza, S.M. Rossitti, C.A. Fortulan, J.M. Domingos and D.A. Rollo, Influence of Ferrite Phase Content on the Electrochemical Properties of Duplex Stainless Steels, Mater. Res., 2016, 20, p 21–29. CrossRef E.C. De Souza, S.M. Rossitti, C.A. Fortulan, J.M. Domingos and D.A. Rollo, Influence of Ferrite Phase Content on the Electrochemical Properties of Duplex Stainless Steels, Mater. Res., 2016, 20, p 21–29. CrossRef
2.
go back to reference R. Balasubramaniam, B. Panda, G. Dwivedi, A.P. Moon, S. Mahapatra, A.K. Manuwal, A. Bhattacharyya, K. Srikanth and R.K. Rathi, Alloy Development of Corrosion-Resistant Rail Steel, Curr. Sci., 2011, 100, p 52–57. R. Balasubramaniam, B. Panda, G. Dwivedi, A.P. Moon, S. Mahapatra, A.K. Manuwal, A. Bhattacharyya, K. Srikanth and R.K. Rathi, Alloy Development of Corrosion-Resistant Rail Steel, Curr. Sci., 2011, 100, p 52–57.
3.
go back to reference K. Godbole, C.R. Das, J. Joardar, S.K. Albert, M. Ramji and B.B. Panigrahi, Toughening and Effect of Prolonged Ageing on Microstructure and Mechanical Properties of AISI 410 Stainless Steel, Metall. Mater. Trans. A, 2020, 51, p 3377–3383. CrossRef K. Godbole, C.R. Das, J. Joardar, S.K. Albert, M. Ramji and B.B. Panigrahi, Toughening and Effect of Prolonged Ageing on Microstructure and Mechanical Properties of AISI 410 Stainless Steel, Metall. Mater. Trans. A, 2020, 51, p 3377–3383. CrossRef
4.
go back to reference D.A. Lopez, W.H. Schreiner, S.R. Sanchez and S.N. Simison, The Influence of Carbon Steel Microstructure on Corrosion Layers an XPS and SEM Characterization, Appl. Surf. Sci., 2003, 207, p 69. CrossRef D.A. Lopez, W.H. Schreiner, S.R. Sanchez and S.N. Simison, The Influence of Carbon Steel Microstructure on Corrosion Layers an XPS and SEM Characterization, Appl. Surf. Sci., 2003, 207, p 69. CrossRef
5.
go back to reference C. Zhang, D. Cai, B. Liao, T. Zhao and Y. Fan, A Study on the Dual-Phase Treatment of Weathering Steel 09CuPCrNi, Mater. Lett., 2004, 58, p 1524–1529. CrossRef C. Zhang, D. Cai, B. Liao, T. Zhao and Y. Fan, A Study on the Dual-Phase Treatment of Weathering Steel 09CuPCrNi, Mater. Lett., 2004, 58, p 1524–1529. CrossRef
6.
go back to reference Y.Y. Chen, H.J. Tzeng, L.I. Wei, L.H. Wang, J.C. Oung and H.C. Shih, Corrosion Resistance and Mechanical Properties of Low-Alloy Steels under Atmospheric Conditions, Corros. Sci., 2005, 47, p 1001–1021. CrossRef Y.Y. Chen, H.J. Tzeng, L.I. Wei, L.H. Wang, J.C. Oung and H.C. Shih, Corrosion Resistance and Mechanical Properties of Low-Alloy Steels under Atmospheric Conditions, Corros. Sci., 2005, 47, p 1001–1021. CrossRef
7.
go back to reference H.H. Uhlig, Corrosion and Corrosion Control, 3rd ed. J. Wiley & Sons, New York, 1991. H.H. Uhlig, Corrosion and Corrosion Control, 3rd ed. J. Wiley & Sons, New York, 1991.
8.
go back to reference D. Clover, B. Kinsella, B. Pejcic and R.D. Marco, The Influence of Microstructure on the Corrosion Rate of Various Carbon Steels, J. Appl. Electrochem., 2005, 35, p 139. CrossRef D. Clover, B. Kinsella, B. Pejcic and R.D. Marco, The Influence of Microstructure on the Corrosion Rate of Various Carbon Steels, J. Appl. Electrochem., 2005, 35, p 139. CrossRef
9.
go back to reference L.R. Bhagavathi, G.P. Chaudhari and S.K. Nath, Mechanical and Corrosion Behavior of Plain Low Carbon Dual-Phase Steels, Mater. Des., 2011, 32, p 433. CrossRef L.R. Bhagavathi, G.P. Chaudhari and S.K. Nath, Mechanical and Corrosion Behavior of Plain Low Carbon Dual-Phase Steels, Mater. Des., 2011, 32, p 433. CrossRef
10.
go back to reference P.P. Sarkar, P. Kumar, M.K. Manna and P.C. Chakraborti, Microstructural Influence on the Electrochemical Corrosion Behavior of Dual-Phase Steels in 35% NaCl Solution, Mater. Lett., 2005, 59, p 248. CrossRef P.P. Sarkar, P. Kumar, M.K. Manna and P.C. Chakraborti, Microstructural Influence on the Electrochemical Corrosion Behavior of Dual-Phase Steels in 35% NaCl Solution, Mater. Lett., 2005, 59, p 248. CrossRef
11.
go back to reference W.T. Tsai and J.R. Chen, Galvanic Corrosion Between the Constituent Phases in Duplex Stainless Steel, Corros. Sci., 2007, 49, p 3659. CrossRef W.T. Tsai and J.R. Chen, Galvanic Corrosion Between the Constituent Phases in Duplex Stainless Steel, Corros. Sci., 2007, 49, p 3659. CrossRef
12.
go back to reference P.K. Katiyar, S. Misra and K. Mondal, Effect of Different Cooling Rates on the Corrosion Behavior of High-Carbon Pearlitic Steel, J. Mater. Eng. Perform., 2018, 27, p 1753–1762. CrossRef P.K. Katiyar, S. Misra and K. Mondal, Effect of Different Cooling Rates on the Corrosion Behavior of High-Carbon Pearlitic Steel, J. Mater. Eng. Perform., 2018, 27, p 1753–1762. CrossRef
13.
go back to reference S. Qu, X. Pang, Y. Wang and K. Gao, Corrosion Behavior of Each Phase in Low Carbon Microalloyed Ferrite–Bainite Dual-Phase Steel: Experiments and Modeling, Corros. Sci., 2013, 75, p 67. CrossRef S. Qu, X. Pang, Y. Wang and K. Gao, Corrosion Behavior of Each Phase in Low Carbon Microalloyed Ferrite–Bainite Dual-Phase Steel: Experiments and Modeling, Corros. Sci., 2013, 75, p 67. CrossRef
14.
go back to reference O. Kazum, M.B. Bobby Kannan, H. Beladi, I.B. Timokhina, P.D. Hodgson and S. Khoddam, Aqueous Corrosion Performance of Nanostructured Bainitic Steel, Mater. Des., 2014, 54, p 67–71. CrossRef O. Kazum, M.B. Bobby Kannan, H. Beladi, I.B. Timokhina, P.D. Hodgson and S. Khoddam, Aqueous Corrosion Performance of Nanostructured Bainitic Steel, Mater. Des., 2014, 54, p 67–71. CrossRef
15.
go back to reference J. Wei, X.X. Fu, J.H. Dong and W. Ke, Corrosion Evolution of Reinforcing Steel in Concrete Under Dry/Wet Cyclic Conditions Contaminated with Chloride, J. Mater. Sci. Technol., 2012, 28(10), p 905–912. CrossRef J. Wei, X.X. Fu, J.H. Dong and W. Ke, Corrosion Evolution of Reinforcing Steel in Concrete Under Dry/Wet Cyclic Conditions Contaminated with Chloride, J. Mater. Sci. Technol., 2012, 28(10), p 905–912. CrossRef
16.
go back to reference C.Q. Ye, R.G. Hua, S.G. Dong, X.J. Zhang, R.Q. Hou, R.G. Du, C.J. Lin and J.S. Pan, EIS Analysis on Chloride-Induced Corrosion Behavior of Reinforcement Steel in Simulated Carbonated Concrete Pore Solutions, J. Electro. Chem., 2013, 688, p 275–281. CrossRef C.Q. Ye, R.G. Hua, S.G. Dong, X.J. Zhang, R.Q. Hou, R.G. Du, C.J. Lin and J.S. Pan, EIS Analysis on Chloride-Induced Corrosion Behavior of Reinforcement Steel in Simulated Carbonated Concrete Pore Solutions, J. Electro. Chem., 2013, 688, p 275–281. CrossRef
17.
go back to reference P.K. Katiyar, S. Misra and K. Mondal, Comparative Corrosion Behavior of Five Microstructures (Pearlite, Bainite, Spheroidized, Martensite, and Tempered Martensite) Made from a High Carbon Steel, Metall. Mater. Trans. A, 2019, 50, p 1489–1501. CrossRef P.K. Katiyar, S. Misra and K. Mondal, Comparative Corrosion Behavior of Five Microstructures (Pearlite, Bainite, Spheroidized, Martensite, and Tempered Martensite) Made from a High Carbon Steel, Metall. Mater. Trans. A, 2019, 50, p 1489–1501. CrossRef
18.
go back to reference K. Zakowski, M. Narozny, M. Szocinski and K. Darowicki, Influence of Water Salinity on Corrosion Risk: The Case of the Southern Baltic Sea Coast, Environ. Monit. Assess, 2014, 186, p 4871–4879. CrossRef K. Zakowski, M. Narozny, M. Szocinski and K. Darowicki, Influence of Water Salinity on Corrosion Risk: The Case of the Southern Baltic Sea Coast, Environ. Monit. Assess, 2014, 186, p 4871–4879. CrossRef
19.
go back to reference W. Kirk and S. Pikul, Seawater corrosivity around the world: results from three years of testing in corrosion in natural waters, ASTM International. C. Baloun Ed., West Conshohocken, 1990 W. Kirk and S. Pikul, Seawater corrosivity around the world: results from three years of testing in corrosion in natural waters, ASTM International. C. Baloun Ed., West Conshohocken, 1990
20.
go back to reference S.A. Al-Fozan and A.U. Malik, Effect of Seawater Level on Corrosion Behavior of Different Alloys, Desalination, 2008, 228, p 61–67. CrossRef S.A. Al-Fozan and A.U. Malik, Effect of Seawater Level on Corrosion Behavior of Different Alloys, Desalination, 2008, 228, p 61–67. CrossRef
21.
go back to reference F. Smith, F. Brownlie, T. Hodgkiess, A. Toumpis, A. Pearson and A.M. Galloway, Effect of Salinity on the Corrosive Wear Behaviour of Engineering Steels in Aqueous Solutions, Wear, 2020, 462–463, p 203515. CrossRef F. Smith, F. Brownlie, T. Hodgkiess, A. Toumpis, A. Pearson and A.M. Galloway, Effect of Salinity on the Corrosive Wear Behaviour of Engineering Steels in Aqueous Solutions, Wear, 2020, 462–463, p 203515. CrossRef
22.
go back to reference R. Starosta, Influence of Seawater Salinity on Corrosion of Austenitic Steel, J. Kones Power. Trans., 2019, 26, p 3. R. Starosta, Influence of Seawater Salinity on Corrosion of Austenitic Steel, J. Kones Power. Trans., 2019, 26, p 3.
23.
go back to reference S. Choudhary, A. Garg and K. Mondal, Relation Between Open Circuit Potential and Polarization Resistance with Rust and Corrosion Monitoring of Mild Steel, J. Mater. Eng. Perform., 2016, 25, p 2969–2976. CrossRef S. Choudhary, A. Garg and K. Mondal, Relation Between Open Circuit Potential and Polarization Resistance with Rust and Corrosion Monitoring of Mild Steel, J. Mater. Eng. Perform., 2016, 25, p 2969–2976. CrossRef
24.
go back to reference I. Hlavaty, M. Sigmund, L. Krejci and P. Mohyla, The Bainitic Steels for Rail Applications, Mater. Engg., 2009, 16(4), p 44–50. I. Hlavaty, M. Sigmund, L. Krejci and P. Mohyla, The Bainitic Steels for Rail Applications, Mater. Engg., 2009, 16(4), p 44–50.
26.
go back to reference W.C. Leslie, The physical metallurgy of steels, Hemisphere Pub. Corp., Philadelphia, 1981. W.C. Leslie, The physical metallurgy of steels, Hemisphere Pub. Corp., Philadelphia, 1981.
27.
go back to reference P.K. Behera, P.K. Katiyar, S. Misra and K. Mondal, Effect of Pre-Induced Plastic Strains on the Corrosion Behavior of Reinforcing Bar in 3.5% NaCl solution, Metall. Mater. Trans. A, 2021, 52A, p 605. CrossRef P.K. Behera, P.K. Katiyar, S. Misra and K. Mondal, Effect of Pre-Induced Plastic Strains on the Corrosion Behavior of Reinforcing Bar in 3.5% NaCl solution, Metall. Mater. Trans. A, 2021, 52A, p 605. CrossRef
28.
go back to reference J.G. Castano, C.A. Botero, A.H. Restrepo, E.A. Agudelo, E. Correa and F. Echeverria, Atmospheric Corrosion of Carbon Steel in Colombia, Corros. Sci., 2010, 52, p 216–223. CrossRef J.G. Castano, C.A. Botero, A.H. Restrepo, E.A. Agudelo, E. Correa and F. Echeverria, Atmospheric Corrosion of Carbon Steel in Colombia, Corros. Sci., 2010, 52, p 216–223. CrossRef
29.
go back to reference D. de la Fuente, J. Alcantara, B. Chico, I. Diaz, J.A. Jimenez and M. Morcillo, Characterisation of Rust Surfaces Formed on Mild Steel Exposed to Marine Atmospheres Using XRD and SEM/Micro-Raman Techniques, Corros. Sci., 2016, 110, p 253–264. CrossRef D. de la Fuente, J. Alcantara, B. Chico, I. Diaz, J.A. Jimenez and M. Morcillo, Characterisation of Rust Surfaces Formed on Mild Steel Exposed to Marine Atmospheres Using XRD and SEM/Micro-Raman Techniques, Corros. Sci., 2016, 110, p 253–264. CrossRef
30.
go back to reference B. Panda, R. Balasubramaniam and G. Dwivedi, On the Corrosion Behaviour of Novel high Carbon Rail Steels in Simulated Cyclic Wet-Dry Salt Fog Conditions, Corros. Sci., 2008, 50, p 1684–1692. CrossRef B. Panda, R. Balasubramaniam and G. Dwivedi, On the Corrosion Behaviour of Novel high Carbon Rail Steels in Simulated Cyclic Wet-Dry Salt Fog Conditions, Corros. Sci., 2008, 50, p 1684–1692. CrossRef
31.
go back to reference P.K. Behera, A.P.K. Moon, K. Mondal and S. Misra, Estimating Critical Corrosion for Initiation of Longitudinal Cracks in RC Structures Considering Phases and Composition of Corrosion Products, J. Mater. Civ. Eng., 2016, 28(12), p 04016158. CrossRef P.K. Behera, A.P.K. Moon, K. Mondal and S. Misra, Estimating Critical Corrosion for Initiation of Longitudinal Cracks in RC Structures Considering Phases and Composition of Corrosion Products, J. Mater. Civ. Eng., 2016, 28(12), p 04016158. CrossRef
32.
go back to reference M. Morcillo, B. Chico, J. Alcantara, I. Diaz, R. Wolthuis and D. de la Fuente, SEM/Micro-Raman Characterisation of the Morphologies of Marine Atmospheric Corrosion Products Formed on Mild Steel, J. Electrochem. Soc., 2016, 163, p 426–439. CrossRef M. Morcillo, B. Chico, J. Alcantara, I. Diaz, R. Wolthuis and D. de la Fuente, SEM/Micro-Raman Characterisation of the Morphologies of Marine Atmospheric Corrosion Products Formed on Mild Steel, J. Electrochem. Soc., 2016, 163, p 426–439. CrossRef
33.
go back to reference T. Misawa, K. Asami, K. Hashimoto and S. Shimodaira, The Mechanism of Atmospheric Rusting and the Protective Amorphous rUst on Low Alloy Steel, Corros. Sci., 1974, 14, p 279–289. CrossRef T. Misawa, K. Asami, K. Hashimoto and S. Shimodaira, The Mechanism of Atmospheric Rusting and the Protective Amorphous rUst on Low Alloy Steel, Corros. Sci., 1974, 14, p 279–289. CrossRef
34.
go back to reference C.Y. Da-Allada, G. Alory, Y. du Penhoat, E. Kestenare, F. Durand and N.M. Hounkonnou, Seasonal Mixed-Layer Salinity Balance in the Tropical Atlantic Ocean: Mean State and Seasonal Cycle, J. Geo. Res. Oceans, 2013, 118, p 332–345. CrossRef C.Y. Da-Allada, G. Alory, Y. du Penhoat, E. Kestenare, F. Durand and N.M. Hounkonnou, Seasonal Mixed-Layer Salinity Balance in the Tropical Atlantic Ocean: Mean State and Seasonal Cycle, J. Geo. Res. Oceans, 2013, 118, p 332–345. CrossRef
35.
go back to reference A. Toloei, S. Atashin and M. Pakshir, Corrosion Rate of Carbon Steel Under Synergistic Effect of Seawater Parameters Including pH, Temperature, and Salinity in Turbulent Condition, Corros. Rev, 2013, 31(3–6), p 135–144. CrossRef A. Toloei, S. Atashin and M. Pakshir, Corrosion Rate of Carbon Steel Under Synergistic Effect of Seawater Parameters Including pH, Temperature, and Salinity in Turbulent Condition, Corros. Rev, 2013, 31(3–6), p 135–144. CrossRef
36.
go back to reference G. Sundjono, L. Priyaotomo and S. Nuraini, Prifiharni, Corrosion behaviour of mild steel in seawater from Northern Coast of Java and Southern Coast of Bali, Indonesia, J. Eng. Technol. Sci., 2017, 49(6), p 770–784. CrossRef G. Sundjono, L. Priyaotomo and S. Nuraini, Prifiharni, Corrosion behaviour of mild steel in seawater from Northern Coast of Java and Southern Coast of Bali, Indonesia, J. Eng. Technol. Sci., 2017, 49(6), p 770–784. CrossRef
37.
go back to reference P.K. Katiyar, S. Misra and K. Mondal, Corrosion Behavior of Annealed Steels with Different Carbon Contents (0.002, 0.17, 0.43 and 0.7% C) in Freely Aerated 3.5% NaCl Solution, J. Mater. Eng. Perform., 2019, 28, p 4041–4052. CrossRef P.K. Katiyar, S. Misra and K. Mondal, Corrosion Behavior of Annealed Steels with Different Carbon Contents (0.002, 0.17, 0.43 and 0.7% C) in Freely Aerated 3.5% NaCl Solution, J. Mater. Eng. Perform., 2019, 28, p 4041–4052. CrossRef
Metadata
Title
Effect of Salinity, Total Dissolved Solids, Conductivity, and pH on Corrosion Behavior of Different Microstructures Made from High-Carbon Rail Steel
Authors
Kirtiratan Godbole
K. Mondal
Publication date
07-02-2022
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 7/2022
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-022-06630-w

Other articles of this Issue 7/2022

Journal of Materials Engineering and Performance 7/2022 Go to the issue

Premium Partners