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2020 | OriginalPaper | Chapter

Effect of Sodium Alkali Concentration on Calcification–Carbonization Process

Authors : Yang Chen, Ting-an Zhang, Guo-zhi Lv, Xi Chao

Published in: Light Metals 2020

Publisher: Springer International Publishing

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Abstract

The calcification-carbonization method is a recently developed hydrometallurgical treatment process which can effectively realize the scale of Bayer process residue for aluminium and sodium recovery. In order to reduce the water consumption in the process, and increase extraction efficiency of the low alkali concentration solution generated in the process, the effects of varying alkali concentration of the calcification reaction solution and the alkali concentration of the carbonization reaction solution on the calcification carbonization process were investigated. The experimental results showed that at low alkali concentration (Na2O < 50 g/L), the solution had no significant effect on the calcification-carbonization process, as Al2O3 recovery rate fluctuates between 34–37%. As the alkali concentration of the solution increases (Na2O > 50 g/L), the Al2O3 recovery rate decreases to less than 20%.

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Literature
1.
go back to reference Lv G Z, Zhang T A, Zhu X F (2014) Calcification-carbonation method for cleaner alumina production and CO2 utilization. JOM 66 (9):1616–1621. Lv G Z, Zhang T A, Zhu X F (2014) Calcification-carbonation method for cleaner alumina production and CO2 utilization. JOM 66 (9):1616–1621.
2.
go back to reference Zhu X F, Zhang T A, Wang Y X (2016) Recovery of alkali and alumina in Bayer red mud by the calcification-carbonation process. International Journal of Minerals, Metallurgy, and Materials 23 (3):257–268. Zhu X F, Zhang T A, Wang Y X (2016) Recovery of alkali and alumina in Bayer red mud by the calcification-carbonation process. International Journal of Minerals, Metallurgy, and Materials 23 (3):257–268.
3.
go back to reference Klauber C, Gräfe M, Power G (2011) Bauxite residue issues: II options for residue utilization. Hydrometallurgy 108:11–32. Klauber C, Gräfe M, Power G (2011) Bauxite residue issues: II options for residue utilization. Hydrometallurgy 108:11–32.
4.
go back to reference Lv G Z, Zhang T A, Zhu X F (2016) Research on the phase transformation and separation performance in calcification-carbonation method for alumina production. TMS Light Metals 245–250. Lv G Z, Zhang T A, Zhu X F (2016) Research on the phase transformation and separation performance in calcification-carbonation method for alumina production. TMS Light Metals 245–250.
5.
go back to reference Liu Y, Naidu R (2014) Hidden values in bauxite residue (red mud): recovery of metals. Waste Management 34(12):2662–2673. Liu Y, Naidu R (2014) Hidden values in bauxite residue (red mud): recovery of metals. Waste Management 34(12):2662–2673.
6.
go back to reference Borra C R, Blanpain B, Pontikes Y (2016) Recovery of rare earths and other valuable metals from bauxite residue (red mud): a review. Journal of Sustainable Metallurgy 2(4):365–386. Borra C R, Blanpain B, Pontikes Y (2016) Recovery of rare earths and other valuable metals from bauxite residue (red mud): a review. Journal of Sustainable Metallurgy 2(4):365–386.
7.
go back to reference Tsakiridis P E, Agatzinileonardou S, Oustadakis (2016) Red mud addition in the raw meal for the production of Portland cement clinker. Journal of Hazardous Materials 116(1):103–110. Tsakiridis P E, Agatzinileonardou S, Oustadakis (2016) Red mud addition in the raw meal for the production of Portland cement clinker. Journal of Hazardous Materials 116(1):103–110.
8.
go back to reference Wang S, Ang H M, Tadé M O (2016) Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes. Chemosphere 72(11):1621–1635. Wang S, Ang H M, Tadé M O (2016) Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes. Chemosphere 72(11):1621–1635.
9.
go back to reference Lopez, Soto, Arias (1998) Adsorbent properties of red mud and its use for wastewater treatment. Water Research 32(4):1314–1322. Lopez, Soto, Arias (1998) Adsorbent properties of red mud and its use for wastewater treatment. Water Research 32(4):1314–1322.
10.
go back to reference Zhang T A, Lv G Z, Liu Y, et al. (2015) Method for recovering alkali and aluminum in course of treatment of Bayer red mud by using calcification-carbonization method[P]. United States Patent: US 9,963,353 B2. Zhang T A, Lv G Z, Liu Y, et al. (2015) Method for recovering alkali and aluminum in course of treatment of Bayer red mud by using calcification-carbonization method[P]. United States Patent: US 9,963,353 B2.
11.
go back to reference Xie L Q, Zhang T A, Lv G Z, Zhu, X. F (2018) Direct calcification–carbonation method for processing of Bayer process red mud. Russian Journal of Non-Ferrous Metals 59(2):142–147. Xie L Q, Zhang T A, Lv G Z, Zhu, X. F (2018) Direct calcification–carbonation method for processing of Bayer process red mud. Russian Journal of Non-Ferrous Metals 59(2):142–147.
12.
go back to reference Li R B, Zhang T A, Liu Y (2017) Characteristics of red mud slurry flow in carbonation reactor. Powder Technology 33:66–76. Li R B, Zhang T A, Liu Y (2017) Characteristics of red mud slurry flow in carbonation reactor. Powder Technology 33:66–76.
13.
go back to reference Zhu X F, Zhang T A, Lv G Z, Guo, F F, Zhang, W G, Wang Y X (2017). Processing Diasporic Red Mud by the Calcification-Carbonation Method. Light Metals. Zhu X F, Zhang T A, Lv G Z, Guo, F F, Zhang, W G, Wang Y X (2017). Processing Diasporic Red Mud by the Calcification-Carbonation Method. Light Metals.
14.
go back to reference Xie L Q, Zhang T A, Lv G Z (2017) Treatment of diaspore bayer red mud with calcification-carbonation continuous process. Nonferrous Metals. Xie L Q, Zhang T A, Lv G Z (2017) Treatment of diaspore bayer red mud with calcification-carbonation continuous process. Nonferrous Metals.
15.
go back to reference Li R B, Li X, Wang D (2018) Calcification reaction of red mud slurry with lime. Powder Technology 333:277–285. Li R B, Li X, Wang D (2018) Calcification reaction of red mud slurry with lime. Powder Technology 333:277–285.
16.
go back to reference Lu K Q, Dong J (1991) Non-cubic symmetry of garnet crystal structure. Journal of Synthetic Crystals 21(3):24–27. Lu K Q, Dong J (1991) Non-cubic symmetry of garnet crystal structure. Journal of Synthetic Crystals 21(3):24–27.
17.
go back to reference H. B. Buergi (1993). Acta Crystall graphica B 49:832–838. H. B. Buergi (1993). Acta Crystall graphica B 49:832–838.
18.
go back to reference Zheng C Z (2015). Study on the formation process and carbonization decomposition of hydrated garnet:25–45. Zheng C Z (2015). Study on the formation process and carbonization decomposition of hydrated garnet:25–45.
19.
go back to reference Zhao X G, Lv L N (2010) Effect of Ca/Si Ratio on Morphology of Calcium Hydrate Prepared by Solution Method. The World of Building Materials 31(2):7–8. Zhao X G, Lv L N (2010) Effect of Ca/Si Ratio on Morphology of Calcium Hydrate Prepared by Solution Method. The World of Building Materials 31(2):7–8.
Metadata
Title
Effect of Sodium Alkali Concentration on Calcification–Carbonization Process
Authors
Yang Chen
Ting-an Zhang
Guo-zhi Lv
Xi Chao
Copyright Year
2020
DOI
https://doi.org/10.1007/978-3-030-36408-3_20

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