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Published in: Tribology Letters 1/2022

01-03-2022 | Original Paper

Effect of Surface Topography on ZDDP Tribofilm Formation During Running-in Stage Subject to Boundary Lubrication

Authors: Linqing Bai, Yonggang Meng, Varian Zhang, Zulfiqar Ahmad Khan

Published in: Tribology Letters | Issue 1/2022

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Abstract

Experimental investigations have been conducted to study the effects of surface topography on ZDDP (zinc dialkyldithiophosphate) chemical tribofilm formation during running-in stage under boundary lubrication conditions. The scope of presented work has been limited and focused on reciprocating motion under boundary lubrication to simulate the upper and lower dead centre of piston ring movement, which is prone to adhesive wear failure. Several surface topographies were designed and fabricated to measure, compare coefficient of friction and ZDDP critical time of tribofilm formation. Rubbing surfaces and their corresponding tribofilms were characterized by SEM and EDX. Mechanisms of surface topography effects on the critical time of ZDDP tribofilm formation is presented and discussed. Results from this study have demonstrated that the surface topography has a significant influence on the critical time of ZDDP tribofilm formation during running-in process and corresponding wear performance. This research provides an opportunity to augment anti-wear performance under boundary lubrication condition. This can be achieved by optimizing surface morphology design to influence the formation of anti-wear tribofilms during the running-in stage. In turn, this will result in interacting component’s service life enhancement and significant cost savings from mitigated wear.

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Literature
1.
go back to reference Bowden, F.P., Tabor, D.: The Friction and Lubrication of Solids. Clarendon Press, Oxford (1950) Bowden, F.P., Tabor, D.: The Friction and Lubrication of Solids. Clarendon Press, Oxford (1950)
2.
go back to reference Zhang, J., Meng, Y.: Boundary lubrication by adsorption film. Friction 3, 115–147 (2015)CrossRef Zhang, J., Meng, Y.: Boundary lubrication by adsorption film. Friction 3, 115–147 (2015)CrossRef
3.
go back to reference Spikes, H.: Boundary lubrication and boundary films. Tribology 25, 331–346 (1993) Spikes, H.: Boundary lubrication and boundary films. Tribology 25, 331–346 (1993)
4.
go back to reference Spikes, H.: The history and mechanisms of ZDDP. Tribol. Lett. 17, 469–489 (2004)CrossRef Spikes, H.: The history and mechanisms of ZDDP. Tribol. Lett. 17, 469–489 (2004)CrossRef
5.
go back to reference Ito, K., Martin, J.M., Minfray, C., Kato, K.: Low-friction tribofilm by the reaction of ZDDP on iron oxide. Tribol. Int. 39, 1538–1544 (2006)CrossRef Ito, K., Martin, J.M., Minfray, C., Kato, K.: Low-friction tribofilm by the reaction of ZDDP on iron oxide. Tribol. Int. 39, 1538–1544 (2006)CrossRef
6.
go back to reference Morina, A., Neville, A., Priest, M., Green, J.H.: ZDDP and MoDTC interactions and their effect on tribological performance-tribofilm characteristics and its evolution. Tribol. Lett. 24, 243–256 (2006)CrossRef Morina, A., Neville, A., Priest, M., Green, J.H.: ZDDP and MoDTC interactions and their effect on tribological performance-tribofilm characteristics and its evolution. Tribol. Lett. 24, 243–256 (2006)CrossRef
7.
go back to reference Nicholls, M.A., Do, T., Norton, P.R., Kasrai, M., Bancroft, G.M.: Review of the lubrication of metallic surfaces by zinc dialkyl-dithiophosphates. Tribol. Int. 38, 15–39 (2005)CrossRef Nicholls, M.A., Do, T., Norton, P.R., Kasrai, M., Bancroft, G.M.: Review of the lubrication of metallic surfaces by zinc dialkyl-dithiophosphates. Tribol. Int. 38, 15–39 (2005)CrossRef
8.
go back to reference Barnes, A.M., Bartle, K.D., Thibon, V.R.A.: A review of zinc dialkyldithiophosphates (ZDDPS): characterisation and role in the lubricating oil. Tribol. Int. 34, 389–395 (2001)CrossRef Barnes, A.M., Bartle, K.D., Thibon, V.R.A.: A review of zinc dialkyldithiophosphates (ZDDPS): characterisation and role in the lubricating oil. Tribol. Int. 34, 389–395 (2001)CrossRef
9.
go back to reference Aktary, M., McDermott, M.T., McAlpine, G.A.: Morphology and nanomechanical properties of ZDDP antiwear films as a function of tribological contact time. Tribol. Lett. 12, 155–162 (2002)CrossRef Aktary, M., McDermott, M.T., McAlpine, G.A.: Morphology and nanomechanical properties of ZDDP antiwear films as a function of tribological contact time. Tribol. Lett. 12, 155–162 (2002)CrossRef
10.
go back to reference Fujita, H., Glovnea, R.P., Spikes, H.A.: Study of zinc dialkydithiophosphate antiwear film formation and removal processes, part I: experimental. Tribol. Trans. 48, 558–566 (2005)CrossRef Fujita, H., Glovnea, R.P., Spikes, H.A.: Study of zinc dialkydithiophosphate antiwear film formation and removal processes, part I: experimental. Tribol. Trans. 48, 558–566 (2005)CrossRef
11.
go back to reference Li, Y.R., Pereira, G., Lachenwitzer, A., Kasrai, M., Norton, P.R.: Studies on ZDDP thermal film formation by XANES spectroscopy, atomic force microscopy, FIB/SEM and 31P NMR. Tribol. Lett. 29, 11–22 (2008)CrossRef Li, Y.R., Pereira, G., Lachenwitzer, A., Kasrai, M., Norton, P.R.: Studies on ZDDP thermal film formation by XANES spectroscopy, atomic force microscopy, FIB/SEM and 31P NMR. Tribol. Lett. 29, 11–22 (2008)CrossRef
12.
go back to reference Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Tribological properties of tribofilms formed from ZDDP in DLC/DLC and DLC/steel contacts. Tribol. Int. 44, 165–174 (2011)CrossRef Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Tribological properties of tribofilms formed from ZDDP in DLC/DLC and DLC/steel contacts. Tribol. Int. 44, 165–174 (2011)CrossRef
13.
go back to reference Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Durability of ZDDP tribofilms formed in DLC/DLC contacts. Tribol. Lett. 51, 469–478 (2013)CrossRef Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Durability of ZDDP tribofilms formed in DLC/DLC contacts. Tribol. Lett. 51, 469–478 (2013)CrossRef
14.
go back to reference Shimizu, Y., Spikes, H.A.: The tribofilm formation of ZDDP under reciprocating pure sliding conditions. Tribol. Lett. 64, 46 (2016)CrossRef Shimizu, Y., Spikes, H.A.: The tribofilm formation of ZDDP under reciprocating pure sliding conditions. Tribol. Lett. 64, 46 (2016)CrossRef
15.
go back to reference Ghanbarzadeh, A., Parsaeian, P., Morina, A., Wilson, M.C.T., Eijk, M.C.P.V., Nedelcu, I., Dowson, D., Neville, A.: A semi-deterministic wear model considering the effect of zinc dialkyl dithiophosphate tribofilm. Tribol. Lett. 61, 12 (2016)CrossRef Ghanbarzadeh, A., Parsaeian, P., Morina, A., Wilson, M.C.T., Eijk, M.C.P.V., Nedelcu, I., Dowson, D., Neville, A.: A semi-deterministic wear model considering the effect of zinc dialkyl dithiophosphate tribofilm. Tribol. Lett. 61, 12 (2016)CrossRef
16.
go back to reference Zhang, J., Spikes, H.: On the mechanism of ZDDP antiwear film formation. Tribol. Lett. 63, 24 (2016)CrossRef Zhang, J., Spikes, H.: On the mechanism of ZDDP antiwear film formation. Tribol. Lett. 63, 24 (2016)CrossRef
17.
go back to reference Miklozic, K.T., Forbus, T.R., Spikes, H.A.: Performance of friction modifiers on ZDDP-generated surfaces. Tribol. Trans. 50, 328–335 (2007)CrossRef Miklozic, K.T., Forbus, T.R., Spikes, H.A.: Performance of friction modifiers on ZDDP-generated surfaces. Tribol. Trans. 50, 328–335 (2007)CrossRef
18.
go back to reference Parsaeian, P., Ghanbarzadeh, A., Eijk, M.V., et al.: A new insight into the interfacial mechanisms of the tribofilm formed by zinc dialkyl dithiophosphate. Appl. Surf. Sci. 403, 472–486 (2017)CrossRef Parsaeian, P., Ghanbarzadeh, A., Eijk, M.V., et al.: A new insight into the interfacial mechanisms of the tribofilm formed by zinc dialkyl dithiophosphate. Appl. Surf. Sci. 403, 472–486 (2017)CrossRef
19.
go back to reference Mao, U., Kadiric, A., Spikes, H.: On the crystallinity and durability of ZDDP tribofilm. Tribol. Lett. 67, 1–13 (2019)CrossRef Mao, U., Kadiric, A., Spikes, H.: On the crystallinity and durability of ZDDP tribofilm. Tribol. Lett. 67, 1–13 (2019)CrossRef
20.
go back to reference Gosvami, N.N., Bares, J.A., Mangolini, F., Konicek, A.R., Yablon, D.G., Carpick, R.W.: Mechanisms of antiwear tribofilm growth revealed in situ by single-asperity sliding contacts. Science 348, 102–106 (2015)CrossRef Gosvami, N.N., Bares, J.A., Mangolini, F., Konicek, A.R., Yablon, D.G., Carpick, R.W.: Mechanisms of antiwear tribofilm growth revealed in situ by single-asperity sliding contacts. Science 348, 102–106 (2015)CrossRef
21.
go back to reference Minfray, C., Martin, J.M., Lubrecht, T., et al.: The role of mechanical and chemical processes in anti-wear properties of ZDDP tribofilms. Tribology 43, 367–376 (2003) Minfray, C., Martin, J.M., Lubrecht, T., et al.: The role of mechanical and chemical processes in anti-wear properties of ZDDP tribofilms. Tribology 43, 367–376 (2003)
22.
go back to reference Jie, Z., Mao, U., Campen, S., et al.: Boundary friction of ZDDP Tribofilms. Tribol. Lett. 69, 8 (2021)CrossRef Jie, Z., Mao, U., Campen, S., et al.: Boundary friction of ZDDP Tribofilms. Tribol. Lett. 69, 8 (2021)CrossRef
23.
go back to reference Mao, U., Spikes, H., Kadiric, A.: In-situ observations of the effect of the ZDDP tribofilm growth on micropitting. Tribol. Int. 138, 342–352 (2019)CrossRef Mao, U., Spikes, H., Kadiric, A.: In-situ observations of the effect of the ZDDP tribofilm growth on micropitting. Tribol. Int. 138, 342–352 (2019)CrossRef
24.
go back to reference Cao, H., Meng, Y.: Electrochemical effect on boundary lubrication of ZDDP additive blended in propylene carbonate/diethyl succinate. Tribol. Int. 126, 229–239 (2018)CrossRef Cao, H., Meng, Y.: Electrochemical effect on boundary lubrication of ZDDP additive blended in propylene carbonate/diethyl succinate. Tribol. Int. 126, 229–239 (2018)CrossRef
25.
go back to reference So, H., Lin, Y.C., Huang, G.G.S., Chang, T.S.T.: Antiwear mechanism of zinc dialkyl dithiophosphates added to a paraffinic oil in the boundary lubrication condition. Wear 166, 17–26 (1993)CrossRef So, H., Lin, Y.C., Huang, G.G.S., Chang, T.S.T.: Antiwear mechanism of zinc dialkyl dithiophosphates added to a paraffinic oil in the boundary lubrication condition. Wear 166, 17–26 (1993)CrossRef
26.
go back to reference Rosencrantz, A., Stratmann, A., Gachot, C., et al.: Improved wear behavior of cylindrical roller thrust bearings by three-beam laser interference. Adv. Eng. Mater. 18, 854–862 (2016)CrossRef Rosencrantz, A., Stratmann, A., Gachot, C., et al.: Improved wear behavior of cylindrical roller thrust bearings by three-beam laser interference. Adv. Eng. Mater. 18, 854–862 (2016)CrossRef
27.
go back to reference Hsu, C.-J., Stratmann, A., Rosenkranz, A., et al.: Enhanced growth of ZDDP-based tribofilms on laser-interference patterned cylinder roller bearings. Lubricants 5, 39 (2017)CrossRef Hsu, C.-J., Stratmann, A., Rosenkranz, A., et al.: Enhanced growth of ZDDP-based tribofilms on laser-interference patterned cylinder roller bearings. Lubricants 5, 39 (2017)CrossRef
28.
go back to reference Hsu, C.-J., Stratmann, A., Medina, S., et al.: Does laser surface texturing really have a negative impact on the fatigue lifetime of mechanical components? Friction 9, 1766–1775 (2021)CrossRef Hsu, C.-J., Stratmann, A., Medina, S., et al.: Does laser surface texturing really have a negative impact on the fatigue lifetime of mechanical components? Friction 9, 1766–1775 (2021)CrossRef
29.
go back to reference Ayerdi, J., Slachciak, N., Llavori, I., et al.: On the role of a ZDDP in the tribological performance of femtosecond laser-induced periodic surface structures on titanium alloy against different counterbody materials. Lubricants 7, 79 (2019)CrossRef Ayerdi, J., Slachciak, N., Llavori, I., et al.: On the role of a ZDDP in the tribological performance of femtosecond laser-induced periodic surface structures on titanium alloy against different counterbody materials. Lubricants 7, 79 (2019)CrossRef
30.
go back to reference Xu, Y., Zheng, Q., Abuflaha, R., et al.: Influence of dimple shape on tribofilm formation and tribological properties of textured surfaces under full and starved lubrication. Tribol. Int. 136, 267–275 (2019)CrossRef Xu, Y., Zheng, Q., Abuflaha, R., et al.: Influence of dimple shape on tribofilm formation and tribological properties of textured surfaces under full and starved lubrication. Tribol. Int. 136, 267–275 (2019)CrossRef
31.
go back to reference Zhang, Y., Kovalev, A., Meng, Y.: Combined effect of boundary layer formation and surface smoothing on friction and wear rate of lubricated point contacts during normal running-in processes. Friction 6, 274–288 (2018)CrossRef Zhang, Y., Kovalev, A., Meng, Y.: Combined effect of boundary layer formation and surface smoothing on friction and wear rate of lubricated point contacts during normal running-in processes. Friction 6, 274–288 (2018)CrossRef
32.
go back to reference Benyajati, C., Olver, A.V., Hamer, C.J.: An experimental study of micropitting, using a new miniature test-rig. Tribol. Interface Eng. Ser. 43, 601–610 (2003) Benyajati, C., Olver, A.V., Hamer, C.J.: An experimental study of micropitting, using a new miniature test-rig. Tribol. Interface Eng. Ser. 43, 601–610 (2003)
33.
go back to reference Ueda, M., Spikes, H., Kadiric, A.: Influence of black oxide coating on micropitting and ZDDP tribofilm formation. Tribol. Trans. 2020, 1–21 (2021) Ueda, M., Spikes, H., Kadiric, A.: Influence of black oxide coating on micropitting and ZDDP tribofilm formation. Tribol. Trans. 2020, 1–21 (2021)
34.
go back to reference Tonck, A., Martin, J.M., Kapsa, P., et al.: Boundary lubrication with anti-wear additives: study of interface film formation by electrical contact resistance. Tribol. Int. 12, 209–213 (1979)CrossRef Tonck, A., Martin, J.M., Kapsa, P., et al.: Boundary lubrication with anti-wear additives: study of interface film formation by electrical contact resistance. Tribol. Int. 12, 209–213 (1979)CrossRef
35.
go back to reference Georges, J.M., Martin, J.M., Mathia, T., et al.: Mechanism of boundary lubrication with zinc dithiophosphate. Wear 53, 9–34 (1979)CrossRef Georges, J.M., Martin, J.M., Mathia, T., et al.: Mechanism of boundary lubrication with zinc dithiophosphate. Wear 53, 9–34 (1979)CrossRef
36.
go back to reference Bai, L., Meng, Y., Khan, Z.A., et al.: The synergetic effects of surface texturing and MoDDP additive applied to ball-on-disk friction subject to both flooded and starved lubrication conditions. Tribol. Lett. 65, 163 (2017)CrossRef Bai, L., Meng, Y., Khan, Z.A., et al.: The synergetic effects of surface texturing and MoDDP additive applied to ball-on-disk friction subject to both flooded and starved lubrication conditions. Tribol. Lett. 65, 163 (2017)CrossRef
37.
go back to reference Cao, H., Tian, Y., Meng, Y.: A fracture-induced adhesive wear criterion and its application to the simulation of wear process of the point contacts under mixed lubrication condition. Facta Univ. Ser. Mech. Eng. 19, 023 (2021) Cao, H., Tian, Y., Meng, Y.: A fracture-induced adhesive wear criterion and its application to the simulation of wear process of the point contacts under mixed lubrication condition. Facta Univ. Ser. Mech. Eng. 19, 023 (2021)
38.
go back to reference Ying, T.: Nanotribology application in the coining industry (III)—Thermodynamic model. Tribol. Trans. 56, 816–826 (2013)CrossRef Ying, T.: Nanotribology application in the coining industry (III)—Thermodynamic model. Tribol. Trans. 56, 816–826 (2013)CrossRef
39.
go back to reference Ashtekar, A., Sadeghi, F., Stacke, L.E.: Surface defects effects on bearing dynamics. Proc. Inst. Mech. Eng. 224, 25–35 (2009)CrossRef Ashtekar, A., Sadeghi, F., Stacke, L.E.: Surface defects effects on bearing dynamics. Proc. Inst. Mech. Eng. 224, 25–35 (2009)CrossRef
Metadata
Title
Effect of Surface Topography on ZDDP Tribofilm Formation During Running-in Stage Subject to Boundary Lubrication
Authors
Linqing Bai
Yonggang Meng
Varian Zhang
Zulfiqar Ahmad Khan
Publication date
01-03-2022
Publisher
Springer US
Published in
Tribology Letters / Issue 1/2022
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-021-01552-5

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