Top

Published in:

2021 | OriginalPaper | Chapter

Effect of Temperature on the Leachability of Chromium in EAF Slag

Authors : Ya-Jun Wang, Jun-Guo Li, Ya-Nan Zeng, Zhi-Yuan Gao

Published in: Materials Engineering—From Ideas to Practice: An EPD Symposium in Honor of Jiann-Yang Hwang

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The objective of this study is to evaluate the effect of temperature on the leachability of chromium in EAF slag. Mineral phase identification and micromorphology analysis were used to study the distribution of chromium in the EAF slag and the leaching residue. Sequential leaching tests were performed to study the chromium leachability in EAF slag under different temperature. The results show that the chromium in the EAF slag was mainly present in the Mg-Cr spinel, Fe–Cr alloy, or distributed in the form of oxide in the matrix phase-merwinite. In the sequential leaching process, the leachates under various temperatures were all alkaline and reductive. The release rates of chromium could reach their equilibrium values when the leaching time reached to 48 h, and the trivalent chromium was the predominant speciation of chromium in the leachates. The leachability of chromium in EAF slag decreased gradually with increasing temperature.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

previous chapter Removal of Rare-Scattered Metal Impurities in Zinc Sulfate Solution by Ozone Oxidation

next chapter Development and Management of an Industrial Park for the Chinese Electroplating Industry

Liu B, Li J, Wang Z, Zeng Y, Ren Q (2019) Long-term leaching characterization and geochemical modeling of chromium released from AOD slag. Environ Sci Pollut Res 27:921–929. https://doi.org/10.1007/s11356-019-07008-7

Gupta T, Sachdeva SN (2020) Experimental study and modeling of concrete containing AOD steel slag for pavements. Arab J Sci Eng 45:8111–8127. https://doi.org/10.1007/s13369-020-04619-y

Jiang Y, Ling TC, Shi C, Pan SY (2018) Characteristics of steel slags and their use in cement and concrete–a review. Resour Conserv Recy 136:187–197. https://doi.org/10.1016/j.resconrec.2018.04.023CrossRef

Adegoloye G, Beaucour AL, Ortola S, Noumowé A (2015) Concretes made of EAF slag and AOD slag aggregates from stainless steel process: mechanical properties and durability. Constr Build Mater 76:313–321. https://doi.org/10.1016/j.conbuildmat.2014.12.007CrossRef

Shen H, Forssberg E, Nordström U (2004) Physicochemical and mineralogical properties of stainless steel slags oriented to metal recovery. Resour Conserv Recy 40(3):245–271. https://doi.org/10.1016/s0921-3449(03)00072-7CrossRef

Guo M, Durinck D, Jones PT, Heylen G, Hendrickx R, Baeten R, Blanpain B, Wollants P (2007) EAF stainless steel refining–part I: observational study on chromium recovery in an eccentric bottom tapping furnace and a spout tapping furnace. Steel Res Int 78(2):117–124. https://doi.org/10.1002/srin.200705868CrossRef

Zhao QZ, Zeng YN, Li JG, Wang YJ (2020) Selective extraction of chromium from EAF stainless steel slag by pressurized oxidation in a NaOH solution. Mater Trans 61(10):2030–2039. https://doi.org/10.2320/matertrans.MT-M2020050CrossRef

Gao ZY, Li JG, Liu B, Wang ZM (2017) Mineralogical composition of EAF slag and its short-term leaching characteristics. Ind Safety Environ Prot 43(11):80–83. https://doi.org/10.3969/j.issn.1001-425X.2017.11.021CrossRef

Jing C, Liu S, Korfiatis GP, Meng X (2006) Leaching behavior of Cr(III) in stabilized/solidified soil. Chemosphere 64(3):379–385. https://doi.org/10.1016/j.chemosphere.2005.12.039CrossRef

10.

Shadreck M, Mugadza T (2013) Chromium, an essential nutrient and pollutant: a review. Afr J Pure Appl Chem 7(9):310–317. https://doi.org/10.5897/AJPAC2013.0517CrossRef

11.

Eary LE, Rai D (1987) Kinetics of chromium(III) oxidation to chromium(VI) by reaction with manganese dioxide. Environ Sci Technol 21(12):1187–1193. https://doi.org/10.1021/es00165a005CrossRef

12.

Yang F, Guo J, Dai R, Lan Y (2014) Oxidation of Cr(III)-citrate/tartrate complexes by δ-MnO₂: production of Cr(VI) and its impact factors. Geoderma 213:10–14. https://doi.org/10.1016/j.geoderma.2013.07.022CrossRef

13.

State Environmental Protection Administration of China (2007) Identification standards for hazardous wastes-Identification for extraction toxicity. GB 5085.3-2007

14.

Gago EJ, Roldan J, Pacheco-Torres R, Ordóñez J (2013) The city and urban heat islands: a review of strategies to mitigate adverse effects. Renew Sust Energ Rev 25:749–758. https://doi.org/10.1016/j.rser.2013.05.057CrossRef

15.

Qi S, Shang XJ, Zhao SL, Duo LA (2014) Proceedings of the annual conference of the Chinese society of environmental sciences. Chinese Society of Environmental Sciences and Sichuan University, pp 5936–5940

16.

Baba A, Gurdal G, Sengunalp F, Ozay O (2007) Effects of leachant temperature and pH on leachability of metals from fly ash: a case study: can thermal power plant, province of Canakkale, Turkey. Environ Monit Assess 139(1–3):287–298. https://doi.org/10.1007/s10661-007-9834-8

17.

Wang ZM, Li JG, Liu B, Zeng YN, Gao ZY (2017) Study on mineralogical phase composition and quantitative analysis of argon oxygen decarburization slag. Metall Anal 37(1):15–20

18.

Bian LY (2007) Improvement of total chromic measure by spectrophotometry. Environ Sci Manag 32(12):146–147

19.

Rojas MS, De Rojas MIS (2004) Chemical assessment of the electric arc furnace slag as construction material: expansive compounds. Cement Concrete Res 34(10):1881–1888. https://doi.org/10.1016/j.cemconres.2004.01.029CrossRef

20.

Engström F, Adolfsson D, Samuelsson C, Sandström Å, Björkman B (2013) A study of the solubility of pure slag minerals. Miner Eng 41:46–52. https://doi.org/10.1016/j.mineng.2012.10.004CrossRef

21.

De Windt L, Chaurand P, Rose J (2011) Kinetics of steel slag leaching: batch tests and modeling. Waste Manage 31(2):225–235. https://doi.org/10.1016/j.wasman.2010.05.018CrossRef

22.

Fällman AM (2000) Leaching of chromium and barium from steel slag in laboratory and field tests-a solubility controlled process? Waste Manage 20(2–3):149–154. https://doi.org/10.1016/s0956-053x(99)00313-xCrossRef

23.

Liu B, Li J, Zeng Y, Wang Z (2016) Toxicity assessment and geochemical model of chromium leaching from AOD slag. Chemosphere 144:2052–2057. https://doi.org/10.1016/j.chemosphere.2015.10.103CrossRef

24.

Baciocchi R, Costa G, Polettini A, Pomi R (2015) Effects of thin-film accelerated carbonation on steel slag leaching. J Hazard Mater 286:369–378. https://doi.org/10.1016/j.jhazmat.2014.12.059CrossRef

25.

Rai D, Sass BM, Moore DA (1987) Chromium(III) hydrolysis constants and solubility of chromium(III) hydroxide. Inorg Chem 26(3):345–349. https://doi.org/10.1021/ic00250a002CrossRef

Title: Effect of Temperature on the Leachability of Chromium in EAF Slag
Authors: Ya-Jun Wang
Jun-Guo Li
Ya-Nan Zeng
Zhi-Yuan Gao
Publisher: Springer International Publishing
Book: Materials Engineering—From Ideas to Practice: An EPD Symposium in Honor of Jiann-Yang Hwang
Print ISBN: 978-3-030-65240-1

Electronic ISBN: 978-3-030-65241-8

Copyright Year: 2021
DOI: https://doi.org/10.1007/978-3-030-65241-8_19

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Premium Partners