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01-08-2016 | Original Paper

Effect of the Reduction Step on the Catalytic Performance of Pd–CeMO₂ Based Catalysts (M = Gd, Zr) for Propane Combustion

Authors: D. Lopez-Gonzalez, J. Couble, M. Aouine, L. Massin, P. Mascunan, J. Díez-Ramírez, M. Klotz, C. Tardivat, P. Vernoux

Published in: Topics in Catalysis | Issue 17-18/2016

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Abstract

The effect of a reduction step on the catalytic activity of Pd supported doped ceria catalysts was investigated for the propane combustion. Two different oxides based on ceria zirconia (CZ), as a reference three-way catalyst support, and Gadolinia doped ceria (GDC), a mixed ionic electronic conductor, have been used to support Pd nanoparticles. The samples were characterized by H₂–CO chemisorption, temperature programmed reduction, and XPS. In addition, the reduction step in H₂ was in situ observed by environmental transmission electron microscopy. It was found that the catalytic activity of Pd supported on ceria-based supports can be strongly promoted by a reduction step whereas it does not change on alumina. This effect was attributed, in particular on GDC, to the reduction of a surface interaction phase, Pd_xCeO_2−δ, which induces a re-dispersion of metallic Pd nanoparticles.

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Title: Effect of the Reduction Step on the Catalytic Performance of Pd–CeMO2 Based Catalysts (M = Gd, Zr) for Propane Combustion
Authors: D. Lopez-Gonzalez
J. Couble
M. Aouine
L. Massin
P. Mascunan
J. Díez-Ramírez
M. Klotz
C. Tardivat
P. Vernoux
Publication date: 01-08-2016
Publisher: Springer US
Published in: Topics in Catalysis / Issue 17-18/2016
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-016-0683-y

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