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Published in: Journal of Materials Engineering and Performance 4/2022

15-11-2021

Effect of V Content on Phase Formation and Mechanical Properties of the CoFeNiMnVx High-Entropy Alloys

Authors: Man Zhu, Mao Zhang, Lijuan Yao, ZiQi Jie, Yongqin Liu, Kun Li, Zengyun Jian

Published in: Journal of Materials Engineering and Performance | Issue 4/2022

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Abstract

The sigma phase (σ phase) helps to enhance the mechanical properties of high-entropy alloys (HEAs). In this study, several CoFeNiMnVx (x = 0.25, 0.50, 0.75, 1.00, 1.25, and 1.50) HEAs were synthesized using vacuum arc melting to improve the strength of face-centered cubic (FCC)-type CoFeNiMn HEAs. Vanadium (V)’s influence on the microstructure evolution and compressive properties is investigated. Further, only a single-phase FCC solid solution is observed for alloys with x ≤ 1.00. In contrast, a mixture of FCC solid solution and intermetallic σ phase is observed for alloys with x > 1.00. The FCC phase lattice constant first increases and then decreases slightly with an increase in V content. Adding V improves the strength and microhardness of FCC-type CoFeNiMn HEAs but decreases their ductility. As V content increases, the yield strength significantly increases from 223 to 1545 MPa, whereas the fracture strain decreases from >55% (no fracture) to about 9.5%. Increasing V content also results in an increase in microhardness from 213 to 716 HV.

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Literature
1.
go back to reference J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau and S.Y. Chang, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6, p 299–303.CrossRef J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau and S.Y. Chang, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6, p 299–303.CrossRef
2.
go back to reference J.W. Yeh, S.Y. Chang, Y.D. Hong, S.K. Chen and S.J. Lin, Anomalous Decrease in X-ray Diffraction Intensities of Cu–Ni–Al–Co–Cr–Fe–Si Alloy Systems with Multi-Principal Elements, Mater. Chem. Phys., 2007, 103, p 41–46.CrossRef J.W. Yeh, S.Y. Chang, Y.D. Hong, S.K. Chen and S.J. Lin, Anomalous Decrease in X-ray Diffraction Intensities of Cu–Ni–Al–Co–Cr–Fe–Si Alloy Systems with Multi-Principal Elements, Mater. Chem. Phys., 2007, 103, p 41–46.CrossRef
3.
go back to reference Y.P. Lu, Y. Dong, S. Guo, L. Jiang, H.J. Kang, T.M. Wang, B. Wen, Z.J. Wang, J.C. Jie, Z.Q. Cao, H.H. Ruan and T.J. Li, A Promising New Class of High-Temperature Alloys: Eutectic High-Entropy Alloys, Sci. Rep., 2014, 4, p 6200.CrossRef Y.P. Lu, Y. Dong, S. Guo, L. Jiang, H.J. Kang, T.M. Wang, B. Wen, Z.J. Wang, J.C. Jie, Z.Q. Cao, H.H. Ruan and T.J. Li, A Promising New Class of High-Temperature Alloys: Eutectic High-Entropy Alloys, Sci. Rep., 2014, 4, p 6200.CrossRef
4.
go back to reference K.X. Zhou, J.J. Li, Q.F. Wu, Z.L. Zhang, Z.J. Wang and J.C. Wang, Remelting Induced Fully-Equiaxed Microstructures with Anomalous Eutectics in the Additive Manufactured Ni32Co30Cr10Fe10Al18 Eutectic High-Entropy Alloy, Scripta Mater., 2021, 201, p 113952.CrossRef K.X. Zhou, J.J. Li, Q.F. Wu, Z.L. Zhang, Z.J. Wang and J.C. Wang, Remelting Induced Fully-Equiaxed Microstructures with Anomalous Eutectics in the Additive Manufactured Ni32Co30Cr10Fe10Al18 Eutectic High-Entropy Alloy, Scripta Mater., 2021, 201, p 113952.CrossRef
5.
go back to reference N. Liu, W. Ding, X.J. Wang, J. Zhang, P.J. Zhou and C. Mu, Phases, Microstructures and Properties of Multi-Component FeCoNi-Based Alloys, Mater. Sci. Technol., 2020, 36, p 654–660.CrossRef N. Liu, W. Ding, X.J. Wang, J. Zhang, P.J. Zhou and C. Mu, Phases, Microstructures and Properties of Multi-Component FeCoNi-Based Alloys, Mater. Sci. Technol., 2020, 36, p 654–660.CrossRef
6.
go back to reference N. Liu, M. Xu, Y.Y. Qian and P.J. Zhou, Microstructure, Phase Stability, and Oxidation Resistance of (FeCoNi)60Al15Cr25−xTix High-Entropy Alloys, J. Alloys. Compd., 2021, 870, p 159320.CrossRef N. Liu, M. Xu, Y.Y. Qian and P.J. Zhou, Microstructure, Phase Stability, and Oxidation Resistance of (FeCoNi)60Al15Cr25−xTix High-Entropy Alloys, J. Alloys. Compd., 2021, 870, p 159320.CrossRef
7.
go back to reference A. Verma, P. Tarate, A.C. Abhyankar, M.R. Mohape, D.S. Gowtam, V.P. Deshmukh and T. Shanmugasundaram, High Temperature Wear in CoCrFeNiCux High Entropy Alloys: The Role of Cu, Scripta Mater., 2019, 161, p 28–31.CrossRef A. Verma, P. Tarate, A.C. Abhyankar, M.R. Mohape, D.S. Gowtam, V.P. Deshmukh and T. Shanmugasundaram, High Temperature Wear in CoCrFeNiCux High Entropy Alloys: The Role of Cu, Scripta Mater., 2019, 161, p 28–31.CrossRef
8.
go back to reference H. Jiang, D.X. Qiao, Y.P. Lu, Z. Ren, Z.Q. Cao, T.M. Wang and T.J. Li, Direct Solidification of Bulk Ultrafine-Microstructure Eutectic High-Entropy Alloys with Outstanding Thermal Stability, Scripta Mater., 2019, 165, p 145–149.CrossRef H. Jiang, D.X. Qiao, Y.P. Lu, Z. Ren, Z.Q. Cao, T.M. Wang and T.J. Li, Direct Solidification of Bulk Ultrafine-Microstructure Eutectic High-Entropy Alloys with Outstanding Thermal Stability, Scripta Mater., 2019, 165, p 145–149.CrossRef
9.
go back to reference Y. Yu, F. He, Z.H. Qiao, Z.J. Wang, W.M. Liu and J. Yang, Effects of Temperature and Microstructure on the Triblogical Properties of CoCrFeNiNbx Eutectic High Entropy Alloys, J. Alloys Compd., 2019, 775, p 1376–1385.CrossRef Y. Yu, F. He, Z.H. Qiao, Z.J. Wang, W.M. Liu and J. Yang, Effects of Temperature and Microstructure on the Triblogical Properties of CoCrFeNiNbx Eutectic High Entropy Alloys, J. Alloys Compd., 2019, 775, p 1376–1385.CrossRef
10.
go back to reference Z.J. Wang, Y.Y. Huang, Y. Yang, J.C. Wang and C.T. Liu, Atomic-size Effect and Solid Solubility of Multicomponent Alloys, Scripta Mater., 2015, 94, p 28–31.CrossRef Z.J. Wang, Y.Y. Huang, Y. Yang, J.C. Wang and C.T. Liu, Atomic-size Effect and Solid Solubility of Multicomponent Alloys, Scripta Mater., 2015, 94, p 28–31.CrossRef
11.
go back to reference C.B. Wei, L.W. Li, Y.P. Lu, X.H. Du and T.M. Wang, Evolution of Microstructure and Mechanical Properties of As-Cast AlxCrFe2N2 High-Entropy Alloys with Al Content, Metall. Mater. Trans. A, 2021, 52, p 1850–1860.CrossRef C.B. Wei, L.W. Li, Y.P. Lu, X.H. Du and T.M. Wang, Evolution of Microstructure and Mechanical Properties of As-Cast AlxCrFe2N2 High-Entropy Alloys with Al Content, Metall. Mater. Trans. A, 2021, 52, p 1850–1860.CrossRef
12.
go back to reference Y.P. Lu, X.Z. Gao, L. Jiang, Z.N. Chen, T.M. Wang, J.C. Jie, H.J. Kang, Y.B. Zhang, S. Guo, H.H. Ruan, Y.H. Zhao, Z.Q. Cao and T.J. Li, Directly Cast Bulk Eutectic and Near-Eutectic High Entropy Alloys with Balanced Strength and Ductility in a Wide Temperature Range, Acta Mater., 2017, 124, p 143–150.CrossRef Y.P. Lu, X.Z. Gao, L. Jiang, Z.N. Chen, T.M. Wang, J.C. Jie, H.J. Kang, Y.B. Zhang, S. Guo, H.H. Ruan, Y.H. Zhao, Z.Q. Cao and T.J. Li, Directly Cast Bulk Eutectic and Near-Eutectic High Entropy Alloys with Balanced Strength and Ductility in a Wide Temperature Range, Acta Mater., 2017, 124, p 143–150.CrossRef
13.
go back to reference T.X. Li, Y.P. Lu, T.M. Wang and T.J. Li, Grouping Strategy via d-orbit Energy Level to Design Eutectic High-Entropy Alloys, Appl. Phys. Lett., 2021, 119, p 071905.CrossRef T.X. Li, Y.P. Lu, T.M. Wang and T.J. Li, Grouping Strategy via d-orbit Energy Level to Design Eutectic High-Entropy Alloys, Appl. Phys. Lett., 2021, 119, p 071905.CrossRef
14.
go back to reference M.N. Zhang, X.L. Zhou and J.H. Li, Microstructure and Mechanical Properties of a Refractory CoCrMoNbTi High-Entropy Alloy, J. Mater. Eng. Perform., 2017, 26, p 3657–3665.CrossRef M.N. Zhang, X.L. Zhou and J.H. Li, Microstructure and Mechanical Properties of a Refractory CoCrMoNbTi High-Entropy Alloy, J. Mater. Eng. Perform., 2017, 26, p 3657–3665.CrossRef
15.
go back to reference L.P. Huang, M.H. Long, W.S. Liu and S. Li, Effects of Cr on Microstructure, Mechanical Properties and Hydrogen Desorption Behaviors of ZrTiNbMoCr High Entropy Alloys, Mater. Lett., 2021, 293, p 129718.CrossRef L.P. Huang, M.H. Long, W.S. Liu and S. Li, Effects of Cr on Microstructure, Mechanical Properties and Hydrogen Desorption Behaviors of ZrTiNbMoCr High Entropy Alloys, Mater. Lett., 2021, 293, p 129718.CrossRef
16.
go back to reference X.J. Wang, M. Xu, N. Liu and L.X. Liu, The Formation of Sigma Phase in the CoCrFeNi High-Entropy Alloys, Mater. Res. Express, 2021, 8, p 076514.CrossRef X.J. Wang, M. Xu, N. Liu and L.X. Liu, The Formation of Sigma Phase in the CoCrFeNi High-Entropy Alloys, Mater. Res. Express, 2021, 8, p 076514.CrossRef
17.
go back to reference G.A. Salishchev, M.A. Tikhonovsky, D.G. Shaysultanov, A.V. Kuznetsov, I.V. Kolodiy, A.S. Tortika and O.N. Senkov, Effect of Mn and V on Structure and Mechanical Properties of High-Entropy Alloys Based on CoCrFeNi System, J. Alloys Compd., 2014, 591, p 11–21.CrossRef G.A. Salishchev, M.A. Tikhonovsky, D.G. Shaysultanov, A.V. Kuznetsov, I.V. Kolodiy, A.S. Tortika and O.N. Senkov, Effect of Mn and V on Structure and Mechanical Properties of High-Entropy Alloys Based on CoCrFeNi System, J. Alloys Compd., 2014, 591, p 11–21.CrossRef
18.
go back to reference N.D. Stepanov, D.G. Shaysultanov, G.A. Salishchev, M.A. Tikhonovsky, E.E. Oleynik, A.S. Tortika and O.N. Senkov, Effect of V Content on Microstructure and Mechanical Properties of the CoCrFeMnNiVx High Entropy Alloys, J. Alloys Compd., 2015, 628, p 170–185.CrossRef N.D. Stepanov, D.G. Shaysultanov, G.A. Salishchev, M.A. Tikhonovsky, E.E. Oleynik, A.S. Tortika and O.N. Senkov, Effect of V Content on Microstructure and Mechanical Properties of the CoCrFeMnNiVx High Entropy Alloys, J. Alloys Compd., 2015, 628, p 170–185.CrossRef
19.
go back to reference G. Qin, Z.B. Li, R.R. Chen, H.T. Zheng, C.L. Fan, L. Wang, Y.Q. Su, H.S. Ding, J.J. Guo and H.Z. Fu, CoCrFeMnNi High-Entropy Alloys Reinforced with Laves Phase by Adding Nb and Ti Elements, J. Mater. Res., 2019, 34, p 1011–1020.CrossRef G. Qin, Z.B. Li, R.R. Chen, H.T. Zheng, C.L. Fan, L. Wang, Y.Q. Su, H.S. Ding, J.J. Guo and H.Z. Fu, CoCrFeMnNi High-Entropy Alloys Reinforced with Laves Phase by Adding Nb and Ti Elements, J. Mater. Res., 2019, 34, p 1011–1020.CrossRef
20.
go back to reference M.R. Chen, S.J. Lin, J.W. Yeh, M.H. Chuang, S.K. Chen and Y.S. Huang, Effect of Vanadium Addition on the Microstructure, Hardness, and Wear Resistance of Al0.5CoCrCuFeNi High-Entropy Alloy, Metall. Mater. Trans. A, 2006, 37, p 1363–1369.CrossRef M.R. Chen, S.J. Lin, J.W. Yeh, M.H. Chuang, S.K. Chen and Y.S. Huang, Effect of Vanadium Addition on the Microstructure, Hardness, and Wear Resistance of Al0.5CoCrCuFeNi High-Entropy Alloy, Metall. Mater. Trans. A, 2006, 37, p 1363–1369.CrossRef
21.
go back to reference N.Y. Yurchenko, N.D. Stepanov, D.G. Shaysultanov, M.A. Tikhonovsky and G.A. Salishcheva, Effect of Al Content on Structure and Mechanical Properties of the AlxCrNbTiVZr (x = 0; 0.25; 0.5; 1) High-Entropy Alloys, Mater. Charac., 2016, 121, p 125–134.CrossRef N.Y. Yurchenko, N.D. Stepanov, D.G. Shaysultanov, M.A. Tikhonovsky and G.A. Salishcheva, Effect of Al Content on Structure and Mechanical Properties of the AlxCrNbTiVZr (x = 0; 0.25; 0.5; 1) High-Entropy Alloys, Mater. Charac., 2016, 121, p 125–134.CrossRef
22.
go back to reference T.T. Zuo, Microstructure and Properties of Co-Fe-Ni Based Magnetic High Entropy Alloys, Ph.D. Thesis, University of Science and Technology Beijing, 2016 T.T. Zuo, Microstructure and Properties of Co-Fe-Ni Based Magnetic High Entropy Alloys, Ph.D. Thesis, University of Science and Technology Beijing, 2016
23.
go back to reference G. Qin, S. Wang, R.R. Chen, H.T. Zheng, L. Wang, Y.Q. Su, J.J. Guo and H.Z. Fu, Improvement of Microstructure and Mechanical Properties of CoCrCuFeNi High-Entropy Alloys by V Addition, J. Mater. Eng. Perform., 2019, 28, p 1049–1056.CrossRef G. Qin, S. Wang, R.R. Chen, H.T. Zheng, L. Wang, Y.Q. Su, J.J. Guo and H.Z. Fu, Improvement of Microstructure and Mechanical Properties of CoCrCuFeNi High-Entropy Alloys by V Addition, J. Mater. Eng. Perform., 2019, 28, p 1049–1056.CrossRef
24.
go back to reference R.R. Chen, G. Qin, H.T. Zheng, L. Wang, Y.Q. Su, Y.L. Chiu, H.S. Ding, J.J. Guo and H.Z. Fu, Composition Design of High Entropy Alloys Using the Valence Electron Concentration to Balance Strength and Ductility, Acta Mater., 2018, 144, p 129–137.CrossRef R.R. Chen, G. Qin, H.T. Zheng, L. Wang, Y.Q. Su, Y.L. Chiu, H.S. Ding, J.J. Guo and H.Z. Fu, Composition Design of High Entropy Alloys Using the Valence Electron Concentration to Balance Strength and Ductility, Acta Mater., 2018, 144, p 129–137.CrossRef
25.
go back to reference Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen and P.K. Liaw, Solid-solution Phase Formation Rules for Multi-Component Alloys, Adv. Eng. Mater., 2008, 10, p 534–538.CrossRef Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen and P.K. Liaw, Solid-solution Phase Formation Rules for Multi-Component Alloys, Adv. Eng. Mater., 2008, 10, p 534–538.CrossRef
26.
go back to reference S. Guo, C. Ng, J. Lu and C.T. Lu, Effect of valence Electron Concentration on Stability of fcc or bcc Phase in High Entropy Alloys, J. Appl. Phys., 2011, 109, p 103505.CrossRef S. Guo, C. Ng, J. Lu and C.T. Lu, Effect of valence Electron Concentration on Stability of fcc or bcc Phase in High Entropy Alloys, J. Appl. Phys., 2011, 109, p 103505.CrossRef
27.
go back to reference S. Guo and C.T. Liu, Phase Stability in High Entropy Alloys: Formation of Solid-Solution Phase or Amorphous Phase, Prog. Nat. Sci.: Mater, Int., 2011, 21, p 433–446. S. Guo and C.T. Liu, Phase Stability in High Entropy Alloys: Formation of Solid-Solution Phase or Amorphous Phase, Prog. Nat. Sci.: Mater, Int., 2011, 21, p 433–446.
28.
go back to reference X. Yang and Y. Zhang, Prediction of High-Entropy Stabilized Solid-Solution in Multicomponent Alloys, Mater. Chem. Phys., 2012, 132, p 233–238.CrossRef X. Yang and Y. Zhang, Prediction of High-Entropy Stabilized Solid-Solution in Multicomponent Alloys, Mater. Chem. Phys., 2012, 132, p 233–238.CrossRef
29.
go back to reference B. Chanda and J. Das, Composition Dependence on the Evolution of Nanoeutectic in CoCrFeNiNbx (0.45 ≤ x ≤ 0.65) High Entropy Alloys, Adv. Eng. Mater., 2018, 20, p 1700908.CrossRef B. Chanda and J. Das, Composition Dependence on the Evolution of Nanoeutectic in CoCrFeNiNbx (0.45 ≤ x ≤ 0.65) High Entropy Alloys, Adv. Eng. Mater., 2018, 20, p 1700908.CrossRef
30.
go back to reference F.R. de Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, and A.K. Niessen Eds., Cohesion in Metals: Transition Metal Alloys, North Holland Physics, Amsterdam, 1988 F.R. de Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, and A.K. Niessen Eds., Cohesion in Metals: Transition Metal Alloys, North Holland Physics, Amsterdam, 1988
31.
go back to reference M.H. Tsai, K.Y. Tsai, C.W. Tsai, C. Lee, C.C. Juan and J.W. Yeh, Criterion for Sigma Phase Formation in Cr- and V-Containing High-Entropy Alloys, Mater. Res. Lett., 2013, 1, p 207–212.CrossRef M.H. Tsai, K.Y. Tsai, C.W. Tsai, C. Lee, C.C. Juan and J.W. Yeh, Criterion for Sigma Phase Formation in Cr- and V-Containing High-Entropy Alloys, Mater. Res. Lett., 2013, 1, p 207–212.CrossRef
32.
go back to reference K.U. Kainer, Metal Matrix Composites, Betz-Druck GmbH, Darmstadt, 2006 K.U. Kainer, Metal Matrix Composites, Betz-Druck GmbH, Darmstadt, 2006
33.
go back to reference W.Y. Huo, H. Zhou, F. Fang, X.F. Zhou, Z.H. Xie and J.Q. Jiang, Microstructure and Properties of Novel CoCrFeNiTax Eutectic High-Entropy Alloys, J. Alloys Compd., 2018, 735, p 897–904.CrossRef W.Y. Huo, H. Zhou, F. Fang, X.F. Zhou, Z.H. Xie and J.Q. Jiang, Microstructure and Properties of Novel CoCrFeNiTax Eutectic High-Entropy Alloys, J. Alloys Compd., 2018, 735, p 897–904.CrossRef
Metadata
Title
Effect of V Content on Phase Formation and Mechanical Properties of the CoFeNiMnVx High-Entropy Alloys
Authors
Man Zhu
Mao Zhang
Lijuan Yao
ZiQi Jie
Yongqin Liu
Kun Li
Zengyun Jian
Publication date
15-11-2021
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 4/2022
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-021-06428-2

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