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Polymer Bulletin

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13-02-2020 | Original Paper

Effects of the polymer composite composition and amine-based additives on the performance of a polymer composite CO₂ separation membrane

Authors: Fuminori Ito, Yuriko Nishiyama, Shuhong Duan, Hidetaka Yamada

Published in: Polymer Bulletin | Issue 1/2021

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Abstract

In this study, a CO₂ separation membrane was prepared by blending polyvinyl alcohol (PVA) and a water-absorbing agent. The effects of the blend composition and the addition of amine-based additives on the separation performance were examined. Membrane preparation by blending PVA and two types of water-absorbing agents promoted the permeation of CO₂ and He, while selectivity of CO₂ relative to He was slightly decreased. The addition of amine-based additives to the membrane improved the pressure resistance when pressurized from 0.1 to 0.7 MPa at 60 °C, and therefore also improved the separation performance. Changing the combination of PVA and the two types of water-absorbing agents during the preparation of the membrane materials led to a further enhancement of the separation performance. Thus, in this study, a CO₂ separation membrane with a high separation performance and a pressure resistance of up to 0.7 MPa at 60 °C under humidification was prepared.

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Title: Effects of the polymer composite composition and amine-based additives on the performance of a polymer composite CO2 separation membrane
Authors: Fuminori Ito
Yuriko Nishiyama
Shuhong Duan
Hidetaka Yamada
Publication date: 13-02-2020
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2021
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-020-03122-6

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