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Journal of Materials Engineering and Performance

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21-12-2016

Electrochemical Behavior Assessment of Micro- and Nano-Grained Commercial Pure Titanium in H₂SO₄ Solutions

Authors: Arash Fattah-alhosseini, Ali Reza Ansari, Yousef Mazaheri, Mohsen Karimi

Published in: Journal of Materials Engineering and Performance | Issue 2/2017

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Abstract

In this study, the electrochemical behavior of commercial pure titanium with both coarse-grained (annealed sample with the average grain size of about 45 µm) and nano-grained microstructure was compared by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and Mott-Schottky analysis. Nano-grained Ti, which typically has a grain size of about 90 nm, is successfully made by six-cycle accumulative roll-bonding process at room temperature. Potentiodynamic polarization plots and impedance measurements revealed that as a result of grain refinement, the passive behavior of the nano-grained sample was improved compared to that of annealed pure Ti in H₂SO₄ solutions. Mott-Schottky analysis indicated that the passive films behaved as n-type semiconductors in H₂SO₄ solutions and grain refinement did not change the semiconductor type of passive films. Also, Mott-Schottky analysis showed that the donor densities decreased as the grain size of the samples reduced. Finally, all electrochemical tests showed that the electrochemical behavior of the nano-grained sample was improved compared to that of annealed pure Ti, mainly due to the formation of thicker and less defective oxide film.

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Title: Electrochemical Behavior Assessment of Micro- and Nano-Grained Commercial Pure Titanium in H2SO4 Solutions
Authors: Arash Fattah-alhosseini
Ali Reza Ansari
Yousef Mazaheri
Mohsen Karimi
Publication date: 21-12-2016
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 2/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-016-2489-2

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