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Surface Engineering and Applied Electrochemistry

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01-03-2020

Electrochemical Studies of Inhibition of Zinc Corrosion in Hydrochloric Acid by Phosphonium Salts

Authors: T. J. Harvey, F. C. Walsh, A. H. Nahlé

Published in: Surface Engineering and Applied Electrochemistry | Issue 2/2020

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Abstract

The performance of five synthesised phosphonium salts, 4-tolyltriphenyl-phosphonium chloride (TTPPC), 4-phenoltriphenylphosphonium chloride (PTPPC), 4-anilinetriphenylphosphonium bromide (ATPPB), 4-benzyl alcoholtriphenylphosphonium chloride (BATPPC), 4-chlorophenyltriphenylphosphonium bromide (CPTPPB) and two commercially available phosphonium salts, tetraphenylphosphonium bromide (TPPB), and methyltriphenylphosphonium bromide (MTPPB) for the inhibition of zinc corrosion in 1 M HCl at 22°C has been quantified using electrochemical techniques. The inhibitor concentration ranged from 1 × 10^–3 to 1 × 10^–7 mol dm^–3. The degree of corrosion inhibition for zinc in 1 M HCl at 22°C was found to be in the order: CPTPPB > TTPPC > TPPB > PTPPC > BATPPC > MTPPB > ATPPB.

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Title: Electrochemical Studies of Inhibition of Zinc Corrosion in Hydrochloric Acid by Phosphonium Salts
Authors: T. J. Harvey
F. C. Walsh
A. H. Nahlé
Publication date: 01-03-2020
Publisher: Pleiades Publishing
Published in: Surface Engineering and Applied Electrochemistry / Issue 2/2020
Print ISSN: 1068-3755
Electronic ISSN: 1934-8002
DOI: https://doi.org/10.3103/S106837552002009X

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